(2-Methyl­dithio­benzoato-κS)(triphenyl­phosphine-κO)gold(I)

The asymmetric unit of the title compound, o-CH₃(C₆H₄)C(S)S–Au–P(C₆H₅)₃ or [Au(C₈H₇S₂)(C₁₈H₁₅P)], consists of two quasi-linear gold complexes. The S—Au—P bond angles [173.83 (2), 175.03 (2)°], S—Au bond lengths [2.3240 (6), 2.3329 (6) Å] and Au—P bond lengths [2.2568 (6), 2.2632 (6) Å] are consistent with previously reported values. The major difference in the two mol­ecules is that the o-methyl­phenyl rings are twisted with respect to the dithio­carboxyl planes by 73.0 (3)° and 46.6 (3)°, as measured by S—C—C—C torsion angles.

Key indicators

• Single-crystal X-ray study
• T = 100 K
• Mean [sigma](C-C) = 0.004 Å
• R factor = 0.029
• wR factor = 0.063
• Data-to-parameter ratio = 34.4

checkCIF/PLATON results

No syntax errors found



Alert level C
ABSTM02_ALERT_3_C  The ratio of expected to reported Tmax/Tmin(RR) is > 1.10
            Tmin and Tmax reported:      0.198     0.256
            Tmin and Tmax expected:      0.162     0.254
            RR =      1.218
            Please check that your absorption correction is appropriate.
PLAT060_ALERT_3_C Ratio Tmax/Tmin (Exp-to-Rep) (too) Large .......       1.23
PLAT432_ALERT_2_C Short Inter X...Y Contact  S1     ..  C43     ..       3.27 Ang.

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   3 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   1 ALERT type 2 Indicator that the structure model may be wrong or deficient
   2 ALERT type 3 Indicator that the structure quality may be low
   0 ALERT type 4 Improvement, methodology, query or suggestion

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Computing details

Data collection: COLLECT (Nonius, 2000); cell refinement: HKL SCALEPACK (Otwinowski & Minor 1997); data reduction: HKL DENZO (Otwinowski & Minor 1997) and SCALEPACK; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997); software used to prepare material for publication: SHELXL97.

2-Methyldithiobenzoato-S(triphenylphosphine)gold(I)

Crystal data

[Au(C18H15P)(C8H7S2)]	F(000) = 2432
Mr = 626.49	Dx = 1.86 Mg m^−3
Monoclinic, P21/c	Melting point: 172-173 °C K
Hall symbol: -P 2ybc	Mo Kα radiation, λ = 0.71073 Å
a = 19.525 (2) Å	Cell parameters from 17051 reflections
b = 12.3297 (10) Å	θ = 2.5–35°
c = 18.625 (1) Å	µ = 6.84 mm^−1
β = 93.486 (3)°	T = 100 K
V = 4475.4 (6) Å^3	Fragment, purple
Z = 8	0.28 × 0.24 × 0.20 mm

Data collection

KappaCCD (with Oxford Cryostream) diffractometer	15875 reflections with I > 2σ(I)
ω scans with κ offsets	Rint = 0.024
Absorption correction: multi-scan HKL Scalepack (Otwinowski & Minor 1997)	θmax = 35.0°, θmin = 2.7°
Tmin = 0.198, Tmax = 0.256	h = −30→31
83707 measured reflections	k = −18→19
18706 independent reflections	l = −30→30

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.029	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.063	H-atom parameters constrained
S = 1.02	w = 1/[σ^2(Fo^2) + (0.0199P)^2 + 8.6263P] where P = (Fo^2 + 2Fc^2)/3
18706 reflections	(Δ/σ)max = 0.006
543 parameters	Δρmax = 3.06 e Å^−3
0 restraints	Δρmin = −1.63 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Au1	0.792055 (5)	0.594127 (7)	0.408406 (5)	0.01431 (2)
P1	0.87498 (3)	0.55923 (5)	0.33233 (3)	0.01303 (10)
S1	0.71920 (4)	0.38569 (5)	0.48316 (4)	0.02729 (15)
S2	0.71390 (3)	0.62860 (5)	0.49487 (3)	0.01688 (11)
C1	0.95875 (12)	0.58058 (19)	0.37755 (13)	0.0155 (4)
C2	0.96865 (14)	0.6735 (2)	0.42011 (14)	0.0199 (5)
H2	0.9319	0.723	0.4248	0.024*
C3	1.03193 (14)	0.6937 (2)	0.45553 (14)	0.0239 (5)
H3	1.0383	0.757	0.4843	0.029*
C4	1.08608 (15)	0.6219 (2)	0.44920 (15)	0.0245 (5)
H4	1.1295	0.6364	0.473	0.029*
C5	1.07629 (14)	0.5288 (2)	0.40783 (15)	0.0234 (5)
H5	1.113	0.4789	0.4041	0.028*
C6	1.01320 (13)	0.5083 (2)	0.37188 (14)	0.0198 (5)
H6	1.0071	0.4449	0.3433	0.024*
C7	0.87210 (12)	0.63753 (18)	0.25005 (12)	0.0140 (4)
C8	0.93231 (13)	0.6612 (2)	0.21539 (14)	0.0180 (4)
H8	0.9759	0.6422	0.2372	0.022*
C9	0.92733 (14)	0.7128 (2)	0.14887 (14)	0.0213 (5)
H9	0.9678	0.7288	0.1251	0.026*
C10	0.86404 (14)	0.7409 (2)	0.11700 (14)	0.0223 (5)
H10	0.8613	0.7755	0.0713	0.027*
C11	0.80426 (14)	0.7187 (2)	0.15159 (14)	0.0201 (5)
H11	0.7608	0.7385	0.1298	0.024*
C12	0.80864 (13)	0.6674 (2)	0.21824 (13)	0.0172 (4)
H12	0.768	0.6526	0.2421	0.021*
C13	0.87585 (12)	0.41900 (18)	0.30192 (13)	0.0135 (4)
C14	0.87777 (13)	0.39219 (19)	0.22940 (13)	0.0161 (4)
H14	0.8771	0.4476	0.194	0.019*
C15	0.88072 (13)	0.2833 (2)	0.20911 (15)	0.0202 (5)
H15	0.8819	0.265	0.1597	0.024*
C16	0.88192 (13)	0.2022 (2)	0.26013 (16)	0.0229 (5)
H16	0.8848	0.1284	0.2459	0.028*
C17	0.87893 (13)	0.2288 (2)	0.33280 (16)	0.0222 (5)
H17	0.8796	0.173	0.368	0.027*
C18	0.87504 (13)	0.3366 (2)	0.35349 (14)	0.0188 (4)
H18	0.8718	0.3544	0.4028	0.023*
C19	0.69225 (12)	0.49918 (18)	0.51872 (12)	0.0139 (4)
C20	0.64336 (12)	0.49493 (17)	0.57715 (12)	0.0130 (4)
C21	0.57500 (12)	0.52393 (19)	0.56155 (13)	0.0163 (4)
H21	0.5608	0.5481	0.5146	0.02*
C22	0.52754 (13)	0.5179 (2)	0.61400 (14)	0.0184 (4)
H22	0.4809	0.5368	0.603	0.022*
C23	0.54916 (13)	0.4837 (2)	0.68284 (13)	0.0184 (4)
H23	0.5171	0.4784	0.7191	0.022*
C24	0.61727 (13)	0.45746 (19)	0.69863 (13)	0.0167 (4)
H24	0.6314	0.436	0.7462	0.02*
C25	0.66583 (12)	0.46161 (18)	0.64673 (13)	0.0150 (4)
C26	0.73910 (13)	0.4301 (2)	0.66484 (15)	0.0220 (5)
H26A	0.7466	0.4219	0.7171	0.033*
H26B	0.7696	0.4866	0.648	0.033*
H26C	0.7489	0.3613	0.6413	0.033*
Au2	0.266900 (5)	0.606902 (7)	0.895154 (5)	0.01484 (2)
P2	0.35764 (3)	0.59915 (5)	0.82527 (3)	0.01240 (10)
S3	0.26172 (4)	0.40386 (5)	1.00547 (4)	0.02242 (13)
S4	0.18105 (3)	0.60646 (5)	0.97697 (4)	0.01933 (12)
C27	0.36862 (12)	0.46344 (18)	0.78991 (13)	0.0138 (4)
C28	0.37388 (13)	0.37748 (19)	0.83929 (14)	0.0176 (4)
H28	0.3718	0.3916	0.8893	0.021*
C29	0.38220 (13)	0.2715 (2)	0.81527 (15)	0.0196 (5)
H29	0.386	0.2133	0.8487	0.024*
C30	0.38486 (13)	0.2514 (2)	0.74186 (15)	0.0207 (5)
H30	0.391	0.1794	0.7253	0.025*
C31	0.37868 (14)	0.3358 (2)	0.69279 (14)	0.0201 (5)
H31	0.3802	0.3214	0.6428	0.024*
C32	0.37014 (12)	0.44207 (19)	0.71668 (13)	0.0159 (4)
H32	0.3654	0.4997	0.6829	0.019*
C33	0.43472 (12)	0.62760 (18)	0.88155 (12)	0.0143 (4)
C34	0.49607 (13)	0.5702 (2)	0.87692 (14)	0.0192 (5)
H34	0.4984	0.5116	0.844	0.023*
C35	0.55362 (14)	0.5988 (2)	0.92046 (16)	0.0232 (5)
H35	0.5952	0.5596	0.9172	0.028*
C36	0.55067 (14)	0.6847 (2)	0.96878 (14)	0.0223 (5)
H36	0.5901	0.7049	0.9981	0.027*
C37	0.48915 (15)	0.7404 (2)	0.97365 (15)	0.0235 (5)
H37	0.4867	0.7985	1.007	0.028*
C38	0.43166 (13)	0.7128 (2)	0.93085 (14)	0.0190 (4)
H38	0.39	0.7516	0.9348	0.023*
C39	0.36075 (12)	0.68782 (18)	0.74778 (12)	0.0137 (4)
C40	0.42364 (13)	0.71596 (19)	0.72060 (14)	0.0175 (4)
H40	0.4654	0.6927	0.7446	0.021*
C41	0.42485 (13)	0.7780 (2)	0.65831 (14)	0.0193 (5)
H41	0.4675	0.7967	0.6396	0.023*
C42	0.36411 (14)	0.8125 (2)	0.62343 (13)	0.0204 (5)
H42	0.3651	0.8547	0.5808	0.024*
C43	0.30148 (14)	0.7856 (2)	0.65073 (13)	0.0188 (4)
H43	0.2599	0.8101	0.627	0.023*
C44	0.29965 (12)	0.72296 (19)	0.71262 (13)	0.0161 (4)
H44	0.2569	0.7041	0.7309	0.019*
C45	0.19841 (12)	0.48608 (18)	1.02271 (12)	0.0140 (4)
C46	0.14940 (12)	0.46024 (18)	1.07902 (13)	0.0140 (4)
C47	0.07898 (13)	0.4759 (2)	1.06215 (14)	0.0178 (4)
H47	0.0641	0.5012	1.0156	0.021*
C48	0.03068 (14)	0.4551 (2)	1.11200 (15)	0.0218 (5)
H48	−0.0168	0.4647	1.0994	0.026*
C49	0.05246 (14)	0.4201 (2)	1.18042 (14)	0.0210 (5)
H49	0.0199	0.4063	1.2152	0.025*
C50	0.12191 (13)	0.40535 (19)	1.19793 (13)	0.0175 (4)
H50	0.1361	0.3822	1.2452	0.021*
C51	0.17176 (12)	0.42329 (18)	1.14861 (13)	0.0148 (4)
C52	0.24519 (13)	0.4020 (2)	1.17264 (15)	0.0210 (5)
H52A	0.2604	0.3344	1.1508	0.032*
H52B	0.2494	0.3953	1.2252	0.032*
H52C	0.2738	0.4622	1.1576	0.032*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Au1	0.01267 (4)	0.01743 (4)	0.01320 (4)	−0.00139 (3)	0.00389 (3)	0.00006 (3)
P1	0.0112 (3)	0.0163 (2)	0.0118 (2)	−0.00156 (19)	0.0018 (2)	−0.0005 (2)
S1	0.0345 (4)	0.0175 (3)	0.0319 (4)	−0.0033 (2)	0.0188 (3)	−0.0079 (2)
S2	0.0184 (3)	0.0151 (2)	0.0180 (3)	0.0003 (2)	0.0084 (2)	0.0006 (2)
C1	0.0146 (10)	0.0198 (10)	0.0121 (9)	−0.0035 (8)	−0.0004 (8)	0.0028 (8)
C2	0.0192 (12)	0.0235 (11)	0.0171 (11)	−0.0042 (9)	0.0013 (9)	−0.0013 (9)
C3	0.0222 (13)	0.0314 (13)	0.0179 (11)	−0.0092 (10)	−0.0018 (10)	−0.0024 (10)
C4	0.0185 (12)	0.0372 (14)	0.0174 (11)	−0.0106 (11)	−0.0037 (9)	0.0057 (10)
C5	0.0152 (11)	0.0322 (13)	0.0225 (12)	−0.0010 (10)	−0.0018 (9)	0.0042 (10)
C6	0.0157 (11)	0.0230 (11)	0.0204 (11)	−0.0016 (9)	0.0004 (9)	0.0003 (9)
C7	0.0143 (10)	0.0138 (9)	0.0141 (10)	−0.0011 (7)	0.0026 (8)	0.0004 (8)
C8	0.0131 (10)	0.0213 (10)	0.0197 (11)	−0.0014 (8)	0.0020 (9)	0.0032 (9)
C9	0.0180 (12)	0.0261 (12)	0.0202 (11)	−0.0034 (9)	0.0046 (9)	0.0035 (10)
C10	0.0241 (13)	0.0261 (12)	0.0167 (11)	−0.0035 (10)	0.0014 (10)	0.0049 (9)
C11	0.0182 (11)	0.0246 (11)	0.0172 (11)	−0.0012 (9)	−0.0023 (9)	0.0019 (9)
C12	0.0156 (11)	0.0199 (10)	0.0158 (10)	−0.0022 (8)	−0.0006 (8)	0.0005 (8)
C13	0.0092 (9)	0.0168 (9)	0.0145 (10)	−0.0009 (7)	−0.0001 (7)	0.0000 (8)
C14	0.0148 (10)	0.0176 (10)	0.0164 (10)	−0.0017 (8)	0.0037 (8)	−0.0023 (8)
C15	0.0161 (11)	0.0220 (11)	0.0229 (12)	−0.0004 (9)	0.0034 (9)	−0.0070 (9)
C16	0.0128 (11)	0.0166 (10)	0.0392 (15)	0.0009 (8)	0.0002 (10)	−0.0038 (10)
C17	0.0154 (11)	0.0199 (11)	0.0308 (14)	−0.0001 (8)	−0.0019 (10)	0.0077 (10)
C18	0.0179 (11)	0.0222 (11)	0.0161 (10)	−0.0016 (9)	−0.0007 (9)	0.0040 (9)
C19	0.0130 (10)	0.0166 (9)	0.0124 (9)	−0.0018 (8)	0.0029 (8)	−0.0012 (8)
C20	0.0131 (9)	0.0130 (8)	0.0133 (9)	−0.0012 (7)	0.0037 (8)	−0.0009 (7)
C21	0.0149 (10)	0.0187 (10)	0.0152 (10)	0.0008 (8)	0.0009 (8)	−0.0004 (8)
C22	0.0120 (10)	0.0226 (11)	0.0208 (11)	0.0003 (8)	0.0036 (9)	−0.0024 (9)
C23	0.0173 (11)	0.0216 (10)	0.0171 (11)	−0.0017 (8)	0.0070 (9)	0.0004 (9)
C24	0.0173 (11)	0.0185 (10)	0.0143 (10)	−0.0011 (8)	0.0023 (8)	0.0024 (8)
C25	0.0140 (10)	0.0155 (9)	0.0158 (10)	−0.0011 (7)	0.0026 (8)	−0.0012 (8)
C26	0.0128 (11)	0.0310 (13)	0.0219 (12)	0.0033 (9)	−0.0001 (9)	0.0027 (10)
Au2	0.01186 (4)	0.01782 (4)	0.01527 (4)	0.00124 (3)	0.00427 (3)	0.00212 (3)
P2	0.0101 (2)	0.0145 (2)	0.0128 (2)	−0.00008 (18)	0.0023 (2)	−0.00023 (19)
S3	0.0224 (3)	0.0227 (3)	0.0229 (3)	0.0085 (2)	0.0076 (2)	0.0013 (2)
S4	0.0172 (3)	0.0204 (3)	0.0214 (3)	0.0062 (2)	0.0093 (2)	0.0071 (2)
C27	0.0111 (9)	0.0135 (9)	0.0168 (10)	−0.0002 (7)	0.0022 (8)	−0.0008 (8)
C28	0.0190 (11)	0.0166 (9)	0.0171 (11)	0.0002 (8)	−0.0002 (9)	0.0005 (8)
C29	0.0180 (11)	0.0162 (10)	0.0246 (12)	0.0013 (8)	−0.0004 (9)	0.0030 (9)
C30	0.0162 (11)	0.0167 (10)	0.0292 (13)	−0.0005 (8)	0.0002 (10)	−0.0041 (9)
C31	0.0193 (12)	0.0215 (11)	0.0195 (11)	−0.0006 (9)	0.0006 (9)	−0.0058 (9)
C32	0.0133 (10)	0.0182 (10)	0.0162 (10)	−0.0021 (8)	0.0010 (8)	−0.0002 (8)
C33	0.0146 (10)	0.0160 (9)	0.0125 (9)	−0.0012 (8)	0.0012 (8)	0.0001 (8)
C34	0.0153 (11)	0.0229 (11)	0.0193 (11)	0.0003 (9)	0.0005 (9)	−0.0036 (9)
C35	0.0146 (11)	0.0292 (13)	0.0250 (13)	0.0022 (9)	−0.0048 (10)	0.0012 (10)
C36	0.0200 (12)	0.0266 (12)	0.0195 (11)	−0.0089 (10)	−0.0055 (9)	0.0044 (10)
C37	0.0300 (14)	0.0207 (11)	0.0197 (12)	−0.0058 (10)	0.0002 (10)	−0.0041 (9)
C38	0.0186 (11)	0.0188 (10)	0.0195 (11)	−0.0016 (8)	−0.0001 (9)	−0.0011 (9)
C39	0.0135 (10)	0.0139 (9)	0.0140 (9)	−0.0001 (7)	0.0027 (8)	−0.0002 (7)
C40	0.0156 (11)	0.0177 (10)	0.0196 (11)	0.0004 (8)	0.0051 (9)	−0.0003 (8)
C41	0.0195 (12)	0.0203 (10)	0.0190 (11)	−0.0029 (9)	0.0080 (9)	−0.0008 (9)
C42	0.0277 (13)	0.0207 (11)	0.0129 (10)	−0.0031 (9)	0.0028 (9)	0.0029 (8)
C43	0.0200 (11)	0.0218 (11)	0.0142 (10)	−0.0004 (9)	−0.0024 (9)	0.0021 (9)
C44	0.0137 (10)	0.0185 (10)	0.0160 (10)	−0.0010 (8)	0.0010 (8)	−0.0001 (8)
C45	0.0135 (10)	0.0162 (9)	0.0123 (9)	0.0007 (7)	−0.0003 (8)	−0.0021 (8)
C46	0.0137 (10)	0.0136 (9)	0.0149 (10)	−0.0004 (7)	0.0015 (8)	−0.0008 (7)
C47	0.0135 (10)	0.0225 (11)	0.0173 (11)	0.0008 (8)	−0.0010 (8)	0.0040 (9)
C48	0.0140 (11)	0.0305 (13)	0.0212 (12)	−0.0003 (9)	0.0028 (9)	0.0032 (10)
C49	0.0174 (11)	0.0272 (12)	0.0191 (11)	−0.0018 (9)	0.0062 (9)	0.0026 (10)
C50	0.0194 (11)	0.0183 (10)	0.0146 (10)	0.0012 (8)	0.0002 (9)	0.0022 (8)
C51	0.0150 (10)	0.0139 (9)	0.0152 (10)	0.0011 (7)	−0.0007 (8)	−0.0005 (8)
C52	0.0150 (11)	0.0262 (12)	0.0214 (12)	0.0032 (9)	−0.0027 (9)	−0.0001 (10)

Geometric parameters (Å, º)

Au1—P1	2.2568 (6)	Au2—P2	2.2632 (6)
Au1—S2	2.3240 (6)	Au2—S4	2.3329 (6)
P1—C7	1.809 (2)	P2—C39	1.815 (2)
P1—C1	1.813 (3)	P2—C33	1.815 (3)
P1—C13	1.820 (2)	P2—C27	1.816 (2)
S1—C19	1.648 (2)	S3—C45	1.645 (2)
S2—C19	1.716 (2)	S4—C45	1.734 (2)
C1—C6	1.396 (4)	C27—C32	1.391 (3)
C1—C2	1.400 (3)	C27—C28	1.403 (3)
C2—C3	1.387 (4)	C28—C29	1.394 (3)
C2—H2	0.95	C28—H28	0.95
C3—C4	1.390 (4)	C29—C30	1.394 (4)
C3—H3	0.95	C29—H29	0.95
C4—C5	1.389 (4)	C30—C31	1.386 (4)
C4—H4	0.95	C30—H30	0.95
C5—C6	1.389 (4)	C31—C32	1.397 (3)
C5—H5	0.95	C31—H31	0.95
C6—H6	0.95	C32—H32	0.95
C7—C12	1.390 (3)	C33—C34	1.399 (3)
C7—C8	1.406 (3)	C33—C38	1.399 (3)
C8—C9	1.390 (4)	C34—C35	1.391 (4)
C8—H8	0.95	C34—H34	0.95
C9—C10	1.382 (4)	C35—C36	1.393 (4)
C9—H9	0.95	C35—H35	0.95
C10—C11	1.394 (4)	C36—C37	1.392 (4)
C10—H10	0.95	C36—H36	0.95
C11—C12	1.391 (3)	C37—C38	1.380 (4)
C11—H11	0.95	C37—H37	0.95
C12—H12	0.95	C38—H38	0.95
C13—C14	1.393 (3)	C39—C44	1.395 (3)
C13—C18	1.399 (3)	C39—C40	1.400 (3)
C14—C15	1.397 (3)	C40—C41	1.391 (3)
C14—H14	0.95	C40—H40	0.95
C15—C16	1.379 (4)	C41—C42	1.384 (4)
C15—H15	0.95	C41—H41	0.95
C16—C17	1.397 (4)	C42—C43	1.393 (4)
C16—H16	0.95	C42—H42	0.95
C17—C18	1.387 (4)	C43—C44	1.390 (3)
C17—H17	0.95	C43—H43	0.95
C18—H18	0.95	C44—H44	0.95
C19—C20	1.492 (3)	C45—C46	1.496 (3)
C20—C21	1.395 (3)	C46—C47	1.405 (3)
C20—C25	1.404 (3)	C46—C51	1.417 (3)
C21—C22	1.389 (3)	C47—C48	1.387 (3)
C21—H21	0.95	C47—H47	0.95
C22—C23	1.391 (4)	C48—C49	1.387 (4)
C22—H22	0.95	C48—H48	0.95
C23—C24	1.383 (4)	C49—C50	1.387 (4)
C23—H23	0.95	C49—H49	0.95
C24—C25	1.396 (3)	C50—C51	1.396 (3)
C24—H24	0.95	C50—H50	0.95
C25—C26	1.501 (4)	C51—C52	1.499 (4)
C26—H26A	0.98	C52—H52A	0.98
C26—H26B	0.98	C52—H52B	0.98
C26—H26C	0.98	C52—H52C	0.98
P1—Au1—S2	175.03 (2)	P2—Au2—S4	173.83 (2)
C7—P1—C1	107.26 (11)	C39—P2—C33	106.03 (11)
C7—P1—C13	104.10 (11)	C39—P2—C27	104.85 (10)
C1—P1—C13	104.91 (11)	C33—P2—C27	105.99 (11)
C7—P1—Au1	116.33 (8)	C39—P2—Au2	119.82 (8)
C1—P1—Au1	110.01 (8)	C33—P2—Au2	108.08 (8)
C13—P1—Au1	113.41 (7)	C27—P2—Au2	111.19 (7)
C19—S2—Au1	101.06 (8)	C45—S4—Au2	101.31 (8)
C6—C1—C2	119.0 (2)	C32—C27—C28	119.6 (2)
C6—C1—P1	122.83 (19)	C32—C27—P2	122.70 (18)
C2—C1—P1	118.13 (19)	C28—C27—P2	117.64 (18)
C3—C2—C1	120.3 (3)	C29—C28—C27	120.2 (2)
C3—C2—H2	119.9	C29—C28—H28	119.9
C1—C2—H2	119.9	C27—C28—H28	119.9
C2—C3—C4	120.4 (3)	C30—C29—C28	119.6 (2)
C2—C3—H3	119.8	C30—C29—H29	120.2
C4—C3—H3	119.8	C28—C29—H29	120.2
C5—C4—C3	119.6 (3)	C31—C30—C29	120.5 (2)
C5—C4—H4	120.2	C31—C30—H30	119.8
C3—C4—H4	120.2	C29—C30—H30	119.8
C4—C5—C6	120.4 (3)	C30—C31—C32	120.1 (2)
C4—C5—H5	119.8	C30—C31—H31	119.9
C6—C5—H5	119.8	C32—C31—H31	119.9
C5—C6—C1	120.3 (2)	C27—C32—C31	120.0 (2)
C5—C6—H6	119.8	C27—C32—H32	120
C1—C6—H6	119.8	C31—C32—H32	120
C12—C7—C8	119.9 (2)	C34—C33—C38	119.4 (2)
C12—C7—P1	118.90 (17)	C34—C33—P2	123.35 (18)
C8—C7—P1	121.07 (19)	C38—C33—P2	117.20 (18)
C9—C8—C7	119.3 (2)	C35—C34—C33	120.0 (2)
C9—C8—H8	120.4	C35—C34—H34	120
C7—C8—H8	120.4	C33—C34—H34	120
C10—C9—C8	120.6 (2)	C34—C35—C36	120.4 (2)
C10—C9—H9	119.7	C34—C35—H35	119.8
C8—C9—H9	119.7	C36—C35—H35	119.8
C9—C10—C11	120.3 (2)	C37—C36—C35	119.2 (2)
C9—C10—H10	119.9	C37—C36—H36	120.4
C11—C10—H10	119.9	C35—C36—H36	120.4
C12—C11—C10	119.6 (2)	C38—C37—C36	121.0 (2)
C12—C11—H11	120.2	C38—C37—H37	119.5
C10—C11—H11	120.2	C36—C37—H37	119.5
C7—C12—C11	120.4 (2)	C37—C38—C33	120.0 (2)
C7—C12—H12	119.8	C37—C38—H38	120
C11—C12—H12	119.8	C33—C38—H38	120
C14—C13—C18	119.7 (2)	C44—C39—C40	119.8 (2)
C14—C13—P1	121.91 (18)	C44—C39—P2	119.45 (17)
C18—C13—P1	118.41 (18)	C40—C39—P2	120.63 (19)
C13—C14—C15	119.6 (2)	C41—C40—C39	119.8 (2)
C13—C14—H14	120.2	C41—C40—H40	120.1
C15—C14—H14	120.2	C39—C40—H40	120.1
C16—C15—C14	120.7 (2)	C42—C41—C40	120.2 (2)
C16—C15—H15	119.7	C42—C41—H41	119.9
C14—C15—H15	119.7	C40—C41—H41	119.9
C15—C16—C17	119.9 (2)	C41—C42—C43	120.1 (2)
C15—C16—H16	120.1	C41—C42—H42	120
C17—C16—H16	120.1	C43—C42—H42	120
C18—C17—C16	120.0 (2)	C44—C43—C42	120.2 (2)
C18—C17—H17	120	C44—C43—H43	119.9
C16—C17—H17	120	C42—C43—H43	119.9
C17—C18—C13	120.1 (2)	C43—C44—C39	119.8 (2)
C17—C18—H18	119.9	C43—C44—H44	120.1
C13—C18—H18	119.9	C39—C44—H44	120.1
C20—C19—S1	119.84 (17)	C46—C45—S3	121.71 (17)
C20—C19—S2	113.59 (16)	C46—C45—S4	114.35 (16)
S1—C19—S2	126.57 (13)	S3—C45—S4	123.93 (14)
C21—C20—C25	120.6 (2)	C47—C46—C51	119.4 (2)
C21—C20—C19	119.1 (2)	C47—C46—C45	118.2 (2)
C25—C20—C19	120.4 (2)	C51—C46—C45	122.3 (2)
C22—C21—C20	120.7 (2)	C48—C47—C46	121.4 (2)
C22—C21—H21	119.7	C48—C47—H47	119.3
C20—C21—H21	119.7	C46—C47—H47	119.3
C21—C22—C23	119.1 (2)	C47—C48—C49	119.3 (2)
C21—C22—H22	120.4	C47—C48—H48	120.3
C23—C22—H22	120.4	C49—C48—H48	120.3
C24—C23—C22	120.1 (2)	C50—C49—C48	119.8 (2)
C24—C23—H23	120	C50—C49—H49	120.1
C22—C23—H23	120	C48—C49—H49	120.1
C23—C24—C25	122.0 (2)	C49—C50—C51	122.4 (2)
C23—C24—H24	119	C49—C50—H50	118.8
C25—C24—H24	119	C51—C50—H50	118.8
C24—C25—C20	117.6 (2)	C50—C51—C46	117.7 (2)
C24—C25—C26	120.9 (2)	C50—C51—C52	117.9 (2)
C20—C25—C26	121.6 (2)	C46—C51—C52	124.4 (2)
C25—C26—H26A	109.5	C51—C52—H52A	109.5
C25—C26—H26B	109.5	C51—C52—H52B	109.5
H26A—C26—H26B	109.5	H52A—C52—H52B	109.5
C25—C26—H26C	109.5	C51—C52—H52C	109.5
H26A—C26—H26C	109.5	H52A—C52—H52C	109.5
H26B—C26—H26C	109.5	H52B—C52—H52C	109.5
C7—P1—C1—C6	−97.2 (2)	C39—P2—C27—C32	−6.7 (2)
C13—P1—C1—C6	13.1 (2)	C33—P2—C27—C32	−118.6 (2)
Au1—P1—C1—C6	135.42 (19)	Au2—P2—C27—C32	124.17 (18)
C7—P1—C1—C2	83.1 (2)	C39—P2—C27—C28	175.00 (19)
C13—P1—C1—C2	−166.59 (18)	C33—P2—C27—C28	63.1 (2)
Au1—P1—C1—C2	−44.3 (2)	Au2—P2—C27—C28	−54.1 (2)
C6—C1—C2—C3	0.6 (4)	C32—C27—C28—C29	1.5 (4)
P1—C1—C2—C3	−179.7 (2)	P2—C27—C28—C29	179.8 (2)
C1—C2—C3—C4	−0.1 (4)	C27—C28—C29—C30	−0.4 (4)
C2—C3—C4—C5	−0.8 (4)	C28—C29—C30—C31	−0.6 (4)
C3—C4—C5—C6	1.2 (4)	C29—C30—C31—C32	0.4 (4)
C4—C5—C6—C1	−0.6 (4)	C28—C27—C32—C31	−1.7 (4)
C2—C1—C6—C5	−0.2 (4)	P2—C27—C32—C31	−179.93 (19)
P1—C1—C6—C5	−179.93 (19)	C30—C31—C32—C27	0.7 (4)
C1—P1—C7—C12	−157.40 (19)	C39—P2—C33—C34	−92.4 (2)
C13—P1—C7—C12	91.8 (2)	C27—P2—C33—C34	18.7 (2)
Au1—P1—C7—C12	−33.8 (2)	Au2—P2—C33—C34	137.94 (19)
C1—P1—C7—C8	27.4 (2)	C39—P2—C33—C38	86.5 (2)
C13—P1—C7—C8	−83.4 (2)	C27—P2—C33—C38	−162.39 (18)
Au1—P1—C7—C8	151.03 (17)	Au2—P2—C33—C38	−43.1 (2)
C12—C7—C8—C9	−1.1 (4)	C38—C33—C34—C35	−0.8 (4)
P1—C7—C8—C9	174.02 (19)	P2—C33—C34—C35	178.1 (2)
C7—C8—C9—C10	0.2 (4)	C33—C34—C35—C36	−0.1 (4)
C8—C9—C10—C11	0.6 (4)	C34—C35—C36—C37	0.9 (4)
C9—C10—C11—C12	−0.4 (4)	C35—C36—C37—C38	−0.8 (4)
C8—C7—C12—C11	1.3 (4)	C36—C37—C38—C33	−0.1 (4)
P1—C7—C12—C11	−173.97 (19)	C34—C33—C38—C37	0.9 (4)
C10—C11—C12—C7	−0.5 (4)	P2—C33—C38—C37	−178.1 (2)
C7—P1—C13—C14	3.2 (2)	C33—P2—C39—C44	−150.84 (19)
C1—P1—C13—C14	−109.4 (2)	C27—P2—C39—C44	97.3 (2)
Au1—P1—C13—C14	130.55 (18)	Au2—P2—C39—C44	−28.4 (2)
C7—P1—C13—C18	−177.28 (19)	C33—P2—C39—C40	32.9 (2)
C1—P1—C13—C18	70.2 (2)	C27—P2—C39—C40	−79.0 (2)
Au1—P1—C13—C18	−49.9 (2)	Au2—P2—C39—C40	155.36 (16)
C18—C13—C14—C15	−1.7 (4)	C44—C39—C40—C41	−0.6 (3)
P1—C13—C14—C15	177.83 (19)	P2—C39—C40—C41	175.66 (18)
C13—C14—C15—C16	−0.2 (4)	C39—C40—C41—C42	0.4 (4)
C14—C15—C16—C17	1.1 (4)	C40—C41—C42—C43	0.2 (4)
C15—C16—C17—C18	−0.2 (4)	C41—C42—C43—C44	−0.7 (4)
C16—C17—C18—C13	−1.6 (4)	C42—C43—C44—C39	0.6 (4)
C14—C13—C18—C17	2.6 (4)	C40—C39—C44—C43	0.1 (3)
P1—C13—C18—C17	−177.0 (2)	P2—C39—C44—C43	−176.20 (18)
Au1—S2—C19—C20	177.73 (16)	Au2—S4—C45—C46	−178.23 (16)
Au1—S2—C19—S1	−3.05 (19)	Au2—S4—C45—S3	0.20 (17)
S1—C19—C20—C21	−106.6 (2)	S3—C45—C46—C47	−134.9 (2)
S2—C19—C20—C21	72.6 (3)	S4—C45—C46—C47	43.6 (3)
S1—C19—C20—C25	73.0 (3)	S3—C45—C46—C51	46.6 (3)
S2—C19—C20—C25	−107.7 (2)	S4—C45—C46—C51	−134.9 (2)
C25—C20—C21—C22	−1.6 (4)	C51—C46—C47—C48	−0.5 (4)
C19—C20—C21—C22	178.0 (2)	C45—C46—C47—C48	−179.1 (2)
C20—C21—C22—C23	0.8 (4)	C46—C47—C48—C49	1.2 (4)
C21—C22—C23—C24	0.7 (4)	C47—C48—C49—C50	−0.6 (4)
C22—C23—C24—C25	−1.5 (4)	C48—C49—C50—C51	−0.7 (4)
C23—C24—C25—C20	0.7 (4)	C49—C50—C51—C46	1.4 (4)
C23—C24—C25—C26	−178.5 (2)	C49—C50—C51—C52	−178.4 (2)
C21—C20—C25—C24	0.8 (3)	C47—C46—C51—C50	−0.8 (3)
C19—C20—C25—C24	−178.8 (2)	C45—C46—C51—C50	177.7 (2)
C21—C20—C25—C26	−180.0 (2)	C47—C46—C51—C52	179.0 (2)
C19—C20—C25—C26	0.4 (3)	C45—C46—C51—C52	−2.5 (4)