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Acta Cryst. (2006). E62, m870-m872  [ doi:10.1107/S1600536806010415 ]

A new polymorph of (dimethyl 5,6,7,8,15,16-hexahydro-6,7-dioxo-5,8,14,17-tetraazadibenzo[a,g]cyclotetradecine-13,18-dicarboxylato-[kappa]4N)nickel(II)

C.-Q. Li, L.-N. Zhu, X.-Z. Li and R. Li

Abstract: A new polymorph of the title complex, [Ni(C22H18N4O6)], has been synthesized and structurally characterized. Ni(II) is coordinated by the four nitrogen donors of the macrocyclic ligand with a distorted square-planar geometry. C-H...O hydrogen bonds and [pi]...[pi] stacking interactions link the complex molecules, forming an infinite three-dimensional supramolecular network.

Online 29 March 2006


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