Acta Cryst. (2006). E62, m827-m829  [ doi:10.1107/S1600536806008488 ]

Di--acetone-²O:O-bis[(acetone-O)aqualithium(I)] di--acetone-²O:O-bis[diaqualithium(I)] tetrakis{[phthalocyaninato(2-)-⁴N,N',N'',N''']lithiate(I)}

D. A. Grossie, W. A. Feld, L. Scanlon, G. Sandi and Z. Wawrzak

Abstract: The crystals of the title compound, [Li₂(C₃H₆O)₄(H₂O)₂][Li₂(C₃H₆O)₂(H₂O)₄] [Li(C₃₂H₁₆N₈)]₄, were obtained by a recrystallization of dilithium phthalocyanine from an acetone/water/toluene solution. The title structure consists of two independent Li-phthalocyanine complexes along with acetone-bridged lithium dimers. The lithium dimers are located on inversion centers. The crystal structure is stabilized by a network of hydrogen bonds.

Online 22 March 2006

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