A 2:1 cocrystal of 2,3-bis(4-bromophenyl)quinoxaline and 1,2-bis(4-bromophenyl)ethane-1,2-diol
Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806013729/ci2056sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536806013729/ci2056Isup2.hkl |
CCDC reference: 608402
Key indicators
- Single-crystal X-ray study
- T = 193 K
- Mean (C-C) = 0.005 Å
- R factor = 0.038
- wR factor = 0.097
- Data-to-parameter ratio = 14.3
checkCIF/PLATON results
No syntax errors found
Alert level C ABSTM02_ALERT_3_C The ratio of expected to reported Tmax/Tmin(RR) is > 1.10 Tmin and Tmax reported: 0.306 0.553 Tmin and Tmax expected: 0.239 0.511 RR = 1.184 Please check that your absorption correction is appropriate. PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ? PLAT060_ALERT_3_C Ratio Tmax/Tmin (Exp-to-Rep) (too) Large ....... 1.20 PLAT062_ALERT_4_C Rescale T(min) & T(max) by ..................... 0.92 PLAT431_ALERT_2_C Short Inter HL..A Contact Br1 .. Br3 .. 3.51 Ang.
Alert level G ABSTM02_ALERT_3_G When printed, the submitted absorption T values will be replaced by the scaled T values. Since the ratio of scaled T's is identical to the ratio of reported T values, the scaling does not imply a change to the absorption corrections used in the study. Ratio of Tmax expected/reported 0.924 Tmax scaled 0.511 Tmin scaled 0.283
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 5 ALERT level C = Check and explain 1 ALERT level G = General alerts; check 1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 1 ALERT type 2 Indicator that the structure model may be wrong or deficient 3 ALERT type 3 Indicator that the structure quality may be low 1 ALERT type 4 Improvement, methodology, query or suggestion
Data collection: CrystalClear (Rigaku, 2000); cell refinement: CrystalClear; data reduction: CrystalStructure (Rigaku/MSC, 2003); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1999); software used to prepare material for publication: SHELXTL.
C20H12Br2N2·0.5C14H12Br2O2 | Z = 2 |
Mr = 626.13 | F(000) = 614 |
Triclinic, P1 | Dx = 1.767 Mg m−3 |
Hall symbol: -P 1 | Mo Kα radiation, λ = 0.71070 Å |
a = 7.8746 (7) Å | Cell parameters from 4575 reflections |
b = 11.9601 (9) Å | θ = 3.1–25.3° |
c = 14.446 (2) Å | µ = 5.17 mm−1 |
α = 66.121 (11)° | T = 193 K |
β = 83.931 (17)° | Block, yellow |
γ = 71.126 (15)° | 0.30 × 0.24 × 0.13 mm |
V = 1176.7 (3) Å3 |
Rigaku Mercury diffractometer | 4295 independent reflections |
Radiation source: fine-focus sealed tube | 3425 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.037 |
Detector resolution: 7.31 pixels mm-1 | θmax = 25.3°, θmin = 3.1° |
ω scans | h = −8→9 |
Absorption correction: multi-scan (Jacobson, 1998) | k = −14→14 |
Tmin = 0.306, Tmax = 0.553 | l = −17→16 |
11766 measured reflections |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.038 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.097 | H-atom parameters constrained |
S = 1.03 | w = 1/[σ2(Fo2) + (0.0531P)2] where P = (Fo2 + 2Fc2)/3 |
4295 reflections | (Δ/σ)max = 0.001 |
300 parameters | Δρmax = 1.04 e Å−3 |
0 restraints | Δρmin = −0.65 e Å−3 |
Experimental. Spectroscopic analysis: IR (KBr, cm-1): 3090, 1664, 1586, 1568, 1482, 1398, 1312, 1209, 1173, 1112, 1070, 1008, 880, 833, 760, 748, 725, 681; 1H NMR (DMSO-d6, δ, p.p.m.): 4.55 (2H, s, CH), 5.43 (2H, s, OH), 7.18 (4H, d, J = 8.0 Hz, ArH), 7.45 (12H, t, J = 8.0 Hz, ArH), 7.62 (8H, d, J = 8.0 Hz, ArH), 7.91–7.93 (4H, dd, J = 3.6 Hz, J = 3.6 Hz, ArH), 8.17–8.19 (4H, dd, J = 3.6 Hz, J = 3.6 Hz, ArH). |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
Br1 | 0.18716 (5) | 0.26657 (4) | 0.10396 (3) | 0.04213 (14) | |
Br2 | 0.29452 (6) | −0.10449 (4) | 0.60234 (3) | 0.05527 (16) | |
Br3 | 0.76080 (4) | 0.44789 (4) | 0.14796 (3) | 0.03974 (14) | |
O1 | 0.9723 (4) | 0.1028 (3) | −0.1319 (2) | 0.0433 (7) | |
H1 | 1.0028 | 0.1697 | −0.1611 | 0.065* | |
N1 | −0.1047 (3) | 0.6848 (3) | 0.25153 (19) | 0.0237 (6) | |
N2 | −0.2433 (4) | 0.5171 (3) | 0.4153 (2) | 0.0248 (6) | |
C1 | 0.9635 (4) | 0.0733 (3) | −0.0280 (3) | 0.0291 (8) | |
H1A | 1.0429 | 0.1127 | −0.0103 | 0.035* | |
C2 | 0.7746 (4) | 0.1253 (3) | 0.0039 (3) | 0.0267 (8) | |
C3 | 0.7420 (4) | 0.1597 (3) | 0.0862 (3) | 0.0288 (8) | |
H3 | 0.8403 | 0.1533 | 0.1229 | 0.035* | |
C4 | 0.5689 (5) | 0.2031 (3) | 0.1160 (3) | 0.0309 (8) | |
H4 | 0.5481 | 0.2266 | 0.1726 | 0.037* | |
C5 | 0.4266 (4) | 0.2116 (3) | 0.0623 (3) | 0.0286 (8) | |
C6 | 0.4543 (5) | 0.1804 (4) | −0.0205 (3) | 0.0346 (9) | |
H6 | 0.3552 | 0.1885 | −0.0576 | 0.042* | |
C7 | 0.6283 (5) | 0.1367 (4) | −0.0497 (3) | 0.0342 (9) | |
H7 | 0.6483 | 0.1143 | −0.1068 | 0.041* | |
C8 | −0.2719 (4) | 0.7286 (3) | 0.2861 (2) | 0.0247 (7) | |
C9 | −0.3407 (4) | 0.6444 (3) | 0.3694 (2) | 0.0238 (7) | |
C10 | −0.0837 (4) | 0.4758 (3) | 0.3806 (2) | 0.0222 (7) | |
C11 | −0.0101 (4) | 0.5630 (3) | 0.2980 (2) | 0.0223 (7) | |
C12 | −0.3723 (4) | 0.8593 (3) | 0.2414 (3) | 0.0294 (8) | |
H12 | −0.3269 | 0.9166 | 0.1852 | 0.035* | |
C13 | −0.5339 (5) | 0.9035 (4) | 0.2785 (3) | 0.0318 (8) | |
H13 | −0.6003 | 0.9922 | 0.2491 | 0.038* | |
C14 | −0.6048 (5) | 0.8182 (4) | 0.3611 (3) | 0.0331 (9) | |
H14 | −0.7196 | 0.8501 | 0.3853 | 0.040* | |
C15 | −0.5104 (4) | 0.6916 (4) | 0.4059 (3) | 0.0297 (8) | |
H15 | −0.5584 | 0.6353 | 0.4614 | 0.036* | |
C16 | 0.0113 (4) | 0.3359 (3) | 0.4319 (2) | 0.0236 (7) | |
C17 | −0.0023 (5) | 0.2748 (3) | 0.5371 (3) | 0.0286 (8) | |
H17 | −0.0701 | 0.3236 | 0.5742 | 0.034* | |
C18 | 0.0816 (5) | 0.1449 (4) | 0.5874 (3) | 0.0313 (8) | |
H18 | 0.0721 | 0.1043 | 0.6586 | 0.038* | |
C19 | 0.1792 (5) | 0.0746 (3) | 0.5335 (3) | 0.0310 (8) | |
C20 | 0.1925 (5) | 0.1316 (4) | 0.4302 (3) | 0.0365 (9) | |
H20 | 0.2587 | 0.0816 | 0.3937 | 0.044* | |
C21 | 0.1090 (5) | 0.2618 (4) | 0.3798 (3) | 0.0308 (8) | |
H21 | 0.1188 | 0.3010 | 0.3085 | 0.037* | |
C22 | 0.1752 (4) | 0.5256 (3) | 0.2629 (2) | 0.0239 (7) | |
C23 | 0.3219 (4) | 0.4640 (3) | 0.3316 (3) | 0.0289 (8) | |
H23 | 0.3017 | 0.4388 | 0.4022 | 0.035* | |
C24 | 0.4950 (4) | 0.4397 (3) | 0.2982 (3) | 0.0297 (8) | |
H24 | 0.5942 | 0.3983 | 0.3450 | 0.036* | |
C25 | 0.5221 (4) | 0.4769 (3) | 0.1946 (3) | 0.0263 (8) | |
C26 | 0.3806 (4) | 0.5352 (3) | 0.1257 (3) | 0.0289 (8) | |
H26 | 0.4016 | 0.5578 | 0.0554 | 0.035* | |
C27 | 0.2074 (4) | 0.5606 (3) | 0.1600 (3) | 0.0272 (8) | |
H27 | 0.1090 | 0.6025 | 0.1127 | 0.033* |
U11 | U22 | U33 | U12 | U13 | U23 | |
Br1 | 0.0269 (2) | 0.0437 (3) | 0.0498 (3) | −0.00520 (17) | 0.01442 (16) | −0.0200 (2) |
Br2 | 0.0688 (3) | 0.0267 (2) | 0.0500 (3) | 0.0033 (2) | −0.0137 (2) | −0.0053 (2) |
Br3 | 0.0226 (2) | 0.0444 (3) | 0.0464 (3) | −0.00633 (17) | 0.00955 (16) | −0.0173 (2) |
O1 | 0.0452 (16) | 0.0379 (17) | 0.0396 (16) | −0.0137 (13) | 0.0143 (12) | −0.0106 (13) |
N1 | 0.0217 (14) | 0.0240 (16) | 0.0223 (15) | −0.0076 (12) | 0.0051 (11) | −0.0067 (12) |
N2 | 0.0275 (15) | 0.0230 (16) | 0.0219 (14) | −0.0078 (12) | 0.0044 (12) | −0.0077 (12) |
C1 | 0.0267 (18) | 0.027 (2) | 0.032 (2) | −0.0104 (15) | 0.0086 (15) | −0.0098 (16) |
C2 | 0.0235 (17) | 0.0199 (18) | 0.0309 (19) | −0.0057 (14) | 0.0058 (14) | −0.0062 (15) |
C3 | 0.0231 (18) | 0.026 (2) | 0.033 (2) | −0.0078 (14) | 0.0024 (14) | −0.0085 (16) |
C4 | 0.035 (2) | 0.026 (2) | 0.031 (2) | −0.0092 (16) | 0.0072 (15) | −0.0131 (16) |
C5 | 0.0211 (17) | 0.0237 (19) | 0.035 (2) | −0.0044 (14) | 0.0076 (14) | −0.0088 (16) |
C6 | 0.0251 (19) | 0.044 (2) | 0.038 (2) | −0.0088 (16) | 0.0030 (15) | −0.0206 (19) |
C7 | 0.034 (2) | 0.040 (2) | 0.033 (2) | −0.0119 (17) | 0.0071 (16) | −0.0200 (18) |
C8 | 0.0250 (17) | 0.0275 (19) | 0.0214 (17) | −0.0090 (14) | 0.0039 (13) | −0.0095 (15) |
C9 | 0.0240 (17) | 0.0266 (19) | 0.0225 (17) | −0.0119 (14) | 0.0036 (13) | −0.0089 (15) |
C10 | 0.0270 (17) | 0.0215 (18) | 0.0181 (16) | −0.0084 (14) | 0.0018 (13) | −0.0073 (14) |
C11 | 0.0239 (17) | 0.0223 (18) | 0.0205 (17) | −0.0064 (14) | 0.0024 (13) | −0.0093 (14) |
C12 | 0.0295 (19) | 0.026 (2) | 0.0269 (19) | −0.0099 (15) | 0.0081 (15) | −0.0051 (16) |
C13 | 0.0302 (19) | 0.024 (2) | 0.034 (2) | −0.0030 (15) | 0.0018 (15) | −0.0079 (16) |
C14 | 0.0233 (18) | 0.034 (2) | 0.036 (2) | −0.0051 (16) | 0.0108 (15) | −0.0129 (18) |
C15 | 0.0271 (18) | 0.032 (2) | 0.0261 (18) | −0.0101 (16) | 0.0070 (14) | −0.0089 (16) |
C16 | 0.0209 (16) | 0.0248 (19) | 0.0263 (18) | −0.0083 (14) | 0.0019 (13) | −0.0107 (15) |
C17 | 0.0339 (19) | 0.028 (2) | 0.0245 (18) | −0.0108 (16) | 0.0045 (15) | −0.0105 (16) |
C18 | 0.0331 (19) | 0.030 (2) | 0.0258 (18) | −0.0117 (16) | −0.0029 (15) | −0.0034 (16) |
C19 | 0.0306 (19) | 0.0214 (19) | 0.034 (2) | −0.0044 (15) | −0.0068 (16) | −0.0056 (16) |
C20 | 0.039 (2) | 0.031 (2) | 0.038 (2) | −0.0034 (17) | 0.0049 (17) | −0.0191 (18) |
C21 | 0.037 (2) | 0.028 (2) | 0.0262 (18) | −0.0105 (16) | 0.0046 (15) | −0.0100 (16) |
C22 | 0.0237 (17) | 0.0200 (18) | 0.0256 (18) | −0.0066 (14) | 0.0059 (14) | −0.0080 (15) |
C23 | 0.0256 (18) | 0.031 (2) | 0.0281 (19) | −0.0099 (15) | 0.0028 (14) | −0.0093 (16) |
C24 | 0.0239 (18) | 0.028 (2) | 0.035 (2) | −0.0084 (15) | −0.0032 (15) | −0.0082 (16) |
C25 | 0.0237 (18) | 0.0234 (19) | 0.033 (2) | −0.0082 (14) | 0.0086 (15) | −0.0137 (16) |
C26 | 0.0264 (19) | 0.026 (2) | 0.0253 (18) | −0.0040 (15) | 0.0041 (15) | −0.0056 (15) |
C27 | 0.0237 (18) | 0.027 (2) | 0.0240 (18) | −0.0040 (14) | 0.0019 (14) | −0.0067 (15) |
Br1—C5 | 1.904 (3) | C12—C13 | 1.355 (5) |
Br2—C19 | 1.900 (4) | C12—H12 | 0.95 |
Br3—C25 | 1.899 (3) | C13—C14 | 1.421 (5) |
O1—C1 | 1.395 (4) | C13—H13 | 0.95 |
O1—H1 | 0.84 | C14—C15 | 1.358 (5) |
N1—C11 | 1.318 (4) | C14—H14 | 0.95 |
N1—C8 | 1.373 (4) | C15—H15 | 0.95 |
N2—C10 | 1.319 (4) | C16—C21 | 1.386 (5) |
N2—C9 | 1.372 (4) | C16—C17 | 1.405 (5) |
C1—C2 | 1.517 (5) | C17—C18 | 1.379 (5) |
C1—C1i | 1.536 (7) | C17—H17 | 0.95 |
C1—H1A | 1.00 | C18—C19 | 1.374 (5) |
C2—C3 | 1.381 (5) | C18—H18 | 0.95 |
C2—C7 | 1.395 (5) | C19—C20 | 1.376 (5) |
C3—C4 | 1.383 (5) | C20—C21 | 1.381 (5) |
C3—H3 | 0.95 | C20—H20 | 0.95 |
C4—C5 | 1.383 (5) | C21—H21 | 0.95 |
C4—H4 | 0.95 | C22—C27 | 1.391 (5) |
C5—C6 | 1.369 (5) | C22—C23 | 1.401 (5) |
C6—C7 | 1.386 (5) | C23—C24 | 1.376 (5) |
C6—H6 | 0.95 | C23—H23 | 0.95 |
C7—H7 | 0.95 | C24—C25 | 1.392 (5) |
C8—C12 | 1.406 (5) | C24—H24 | 0.95 |
C8—C9 | 1.410 (5) | C25—C26 | 1.374 (5) |
C9—C15 | 1.409 (5) | C26—C27 | 1.382 (5) |
C10—C11 | 1.444 (4) | C26—H26 | 0.95 |
C10—C16 | 1.487 (5) | C27—H27 | 0.95 |
C11—C22 | 1.480 (5) | ||
C1—O1—H1 | 109.5 | C14—C13—H13 | 119.7 |
C11—N1—C8 | 118.6 (3) | C15—C14—C13 | 120.8 (3) |
C10—N2—C9 | 118.6 (3) | C15—C14—H14 | 119.6 |
O1—C1—C2 | 112.4 (3) | C13—C14—H14 | 119.6 |
O1—C1—C1i | 108.3 (4) | C14—C15—C9 | 119.5 (3) |
C2—C1—C1i | 111.1 (3) | C14—C15—H15 | 120.3 |
O1—C1—H1A | 108.4 | C9—C15—H15 | 120.3 |
C2—C1—H1A | 108.4 | C21—C16—C17 | 118.2 (3) |
C1i—C1—H1A | 108.4 | C21—C16—C10 | 122.8 (3) |
C3—C2—C7 | 118.5 (3) | C17—C16—C10 | 119.0 (3) |
C3—C2—C1 | 122.1 (3) | C18—C17—C16 | 120.9 (3) |
C7—C2—C1 | 119.4 (3) | C18—C17—H17 | 119.6 |
C2—C3—C4 | 121.2 (3) | C16—C17—H17 | 119.6 |
C2—C3—H3 | 119.4 | C19—C18—C17 | 119.4 (3) |
C4—C3—H3 | 119.4 | C19—C18—H18 | 120.3 |
C3—C4—C5 | 119.0 (3) | C17—C18—H18 | 120.3 |
C3—C4—H4 | 120.5 | C18—C19—C20 | 121.0 (3) |
C5—C4—H4 | 120.5 | C18—C19—Br2 | 119.5 (3) |
C6—C5—C4 | 121.2 (3) | C20—C19—Br2 | 119.4 (3) |
C6—C5—Br1 | 118.9 (3) | C19—C20—C21 | 119.7 (4) |
C4—C5—Br1 | 120.0 (3) | C19—C20—H20 | 120.2 |
C5—C6—C7 | 119.3 (3) | C21—C20—H20 | 120.2 |
C5—C6—H6 | 120.3 | C20—C21—C16 | 120.8 (3) |
C7—C6—H6 | 120.3 | C20—C21—H21 | 119.6 |
C6—C7—C2 | 120.7 (3) | C16—C21—H21 | 119.6 |
C6—C7—H7 | 119.6 | C27—C22—C23 | 118.8 (3) |
C2—C7—H7 | 119.6 | C27—C22—C11 | 120.3 (3) |
N1—C8—C12 | 120.0 (3) | C23—C22—C11 | 120.7 (3) |
N1—C8—C9 | 120.4 (3) | C24—C23—C22 | 120.8 (3) |
C12—C8—C9 | 119.5 (3) | C24—C23—H23 | 119.6 |
N2—C9—C15 | 119.8 (3) | C22—C23—H23 | 119.6 |
N2—C9—C8 | 120.4 (3) | C23—C24—C25 | 118.8 (3) |
C15—C9—C8 | 119.8 (3) | C23—C24—H24 | 120.6 |
N2—C10—C11 | 121.0 (3) | C25—C24—H24 | 120.6 |
N2—C10—C16 | 115.5 (3) | C26—C25—C24 | 121.6 (3) |
C11—C10—C16 | 123.5 (3) | C26—C25—Br3 | 119.5 (3) |
N1—C11—C10 | 120.9 (3) | C24—C25—Br3 | 118.9 (2) |
N1—C11—C22 | 115.6 (3) | C25—C26—C27 | 119.1 (3) |
C10—C11—C22 | 123.5 (3) | C25—C26—H26 | 120.4 |
C13—C12—C8 | 119.9 (3) | C27—C26—H26 | 120.4 |
C13—C12—H12 | 120.0 | C26—C27—C22 | 120.9 (3) |
C8—C12—H12 | 120.0 | C26—C27—H27 | 119.6 |
C12—C13—C14 | 120.5 (3) | C22—C27—H27 | 119.6 |
C12—C13—H13 | 119.7 | ||
O1—C1—C2—C3 | −150.7 (3) | C12—C13—C14—C15 | 1.5 (6) |
C1i—C1—C2—C3 | 87.9 (5) | C13—C14—C15—C9 | −0.4 (6) |
O1—C1—C2—C7 | 30.7 (5) | N2—C9—C15—C14 | 179.0 (3) |
C1i—C1—C2—C7 | −90.8 (5) | C8—C9—C15—C14 | −0.9 (5) |
C7—C2—C3—C4 | 0.7 (5) | N2—C10—C16—C21 | 139.9 (3) |
C1—C2—C3—C4 | −177.9 (3) | C11—C10—C16—C21 | −39.8 (5) |
C2—C3—C4—C5 | 0.2 (5) | N2—C10—C16—C17 | −38.1 (4) |
C3—C4—C5—C6 | −1.3 (5) | C11—C10—C16—C17 | 142.1 (3) |
C3—C4—C5—Br1 | 178.3 (3) | C21—C16—C17—C18 | 0.9 (5) |
C4—C5—C6—C7 | 1.4 (6) | C10—C16—C17—C18 | 179.1 (3) |
Br1—C5—C6—C7 | −178.2 (3) | C16—C17—C18—C19 | −0.2 (5) |
C5—C6—C7—C2 | −0.4 (6) | C17—C18—C19—C20 | −0.8 (5) |
C3—C2—C7—C6 | −0.6 (5) | C17—C18—C19—Br2 | −179.8 (2) |
C1—C2—C7—C6 | 178.1 (3) | C18—C19—C20—C21 | 1.0 (6) |
C11—N1—C8—C12 | 176.8 (3) | Br2—C19—C20—C21 | −179.9 (3) |
C11—N1—C8—C9 | −0.2 (5) | C19—C20—C21—C16 | −0.3 (5) |
C10—N2—C9—C15 | −179.0 (3) | C17—C16—C21—C20 | −0.7 (5) |
C10—N2—C9—C8 | 0.8 (5) | C10—C16—C21—C20 | −178.8 (3) |
N1—C8—C9—N2 | −1.7 (5) | N1—C11—C22—C27 | −48.6 (5) |
C12—C8—C9—N2 | −178.8 (3) | C10—C11—C22—C27 | 134.3 (4) |
N1—C8—C9—C15 | 178.2 (3) | N1—C11—C22—C23 | 126.1 (4) |
C12—C8—C9—C15 | 1.1 (5) | C10—C11—C22—C23 | −51.0 (5) |
C9—N2—C10—C11 | 1.7 (5) | C27—C22—C23—C24 | 0.7 (6) |
C9—N2—C10—C16 | −178.0 (3) | C11—C22—C23—C24 | −174.1 (3) |
C8—N1—C11—C10 | 2.8 (5) | C22—C23—C24—C25 | −0.3 (6) |
C8—N1—C11—C22 | −174.4 (3) | C23—C24—C25—C26 | −1.0 (6) |
N2—C10—C11—N1 | −3.7 (5) | C23—C24—C25—Br3 | 178.2 (3) |
C16—C10—C11—N1 | 176.1 (3) | C24—C25—C26—C27 | 1.7 (6) |
N2—C10—C11—C22 | 173.3 (3) | Br3—C25—C26—C27 | −177.4 (3) |
C16—C10—C11—C22 | −6.9 (5) | C25—C26—C27—C22 | −1.3 (6) |
N1—C8—C12—C13 | −177.1 (3) | C23—C22—C27—C26 | 0.1 (5) |
C9—C8—C12—C13 | 0.0 (5) | C11—C22—C27—C26 | 174.9 (3) |
C8—C12—C13—C14 | −1.3 (6) |
Symmetry code: (i) −x+2, −y, −z. |
D—H···A | D—H | H···A | D···A | D—H···A |
O1—H1···N1ii | 0.84 | 2.05 | 2.882 (4) | 168 |
C12—H12···Cgiii | 0.95 | 2.84 | 3.666 (4) | 146 |
Symmetry codes: (ii) −x+1, −y+1, −z; (iii) x−1, y+1, z. |