Acta Cryst. (2006). E62, m1106-m1108  [ doi:10.1107/S1600536806014188 ]

[N,N'-Bis(diphenylphosphino)pyridine-2,6-diamine-³P,N¹,P']chloropalladium(II) chloride monohydrate 1,2-dichloroethane solvate

J. Wiedermann, D. Benito-Garagorri, K. Kirchner and K. Mereiter

Abstract: The title compound, [PdCl(C₂₉H₂₅N₃P₂)]Cl·H₂O·C₂H₄Cl₂, contains a cationic pincer-type PNP complex with Pd in a square-planar coordination. The complexes form dimers which are - stacked via their pyridine rings and linked into chains via hydrogen bonds via four-membered rings of two chloride anions and two water molecules. Pairs of 1,2-dichloroethane molecules are entrapped in pockets of the structure and show weak interactions with palladium.

Online 26 April 2006

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