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Acta Cryst. (2006). E62, m954-m956 [ doi:10.1107/S1600536806011573 ]
![[mu]](/logos/entities/mu_rmgif.gif)
-Chloro--diphenylphosphido--hydrido-bis[(![[eta]](/logos/entities/eta_rmgif.gif)
6-hexamethylbenzene)ruthenium(II)] tetrafluoroborateAbstract: The new triple-bridged dinuclear cation [(6-C6Me6)2Ru2(2-Cl)(2-H)(2-PPh2)]+ was formed in chloroform from the precursor [(6-C6Me6)2Ru2(2-H)2(2-PPh2)]+ and characterized as the tetrafluoroborate salt [(6-C12H18)2Ru2(2-Cl)(2-H){2-P(C6H5)2}]BF4. The single-crystal X-ray structure analysis confirms the formation of the meso form. Despite the presence of two stereogenic centres, the complex is not chiral.
Online 5 April 2006
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