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Acta Cryst. (2006). E62, m939-m941  [ doi:10.1107/S1600536806011111 ]

Tetrakis(benzyldiphenylphosphine-[kappa]P)tetra-[mu]2-sulfido-dicopper(I)molybdenum(VI) tetrahydrate

Y.-Y. Niu, Y.-Q. Shu, R. Yang and S. W. Ng

Abstract: In the crystal structure of the title heterothiolate cluster, [MoCu2S4(C19H17P)4]·4H2O, the Mo atom lies on a postion of crystallographic site symmetry \overline{4}, coordinated by four S atoms in a tetrahedral environment; each pair of S atoms bis-chelates two Cu atoms which are, in addition, coordinated by two phosphine ligands each. The tetrahedrally coordinated Cu atoms lie on positions of site symmetry 2.

Online 5 April 2006


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