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Acta Cryst. (2006). E62, m1081-m1082  [ doi:10.1107/S1600536806013547 ]

[mu]-Oxalato-bis[(N,N'-dimethylformamide)(1,10-phenanthroline)copper(II)] bis(perchlorate)

H.-D. Wang, Y.-L. Zhou, H.-Y. He, X.-H. Tu and L.-G. Zhu

Abstract: The title centrosymmetric binuclear complex, [Cu2(C2O4)(C12H8N2)2(C3H7NO)2](ClO4)2, was synthesized by the reaction of 1,10-phenanthroline, 2,5-dihydroxy-1,4-dithiane and Cu(ClO4)2·6H2O. In the asymmetric unit, the CuII atom is in a distorted square-pyramidal coordination geometry. The closest Cu...O distance involving the perchlorate anion is 2.745 (2) Å.

Online 21 April 2006


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