Acta Cryst. (2006). E62, m957-m958  [ doi:10.1107/S1600536806011470 ]

Phenyltris(pyrimidine-2-thiolato)tin(IV)

Y.-X. Li, R.-F. Zhang and C.-L. Ma

Abstract: The seven-coordinate Sn atom in the monomeric title compound, [Sn(C₆H₅)(C₄H₃N₂S)₃], has distorted pentagonal-bipyramidal geometry. The axial C-Sn-S angle is 154.10 (7)°. Thiolate S and phenyl C atoms define the axial positions. Two S atoms and three N atoms define the pentagonal equatorial plane.

Online 5 April 2006

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