Acta Cryst. (2006). E62, m1285-m1286  [ doi:10.1107/S160053680601676X ]

A novel organometallic macrocycle containing a tetrahedral Mo₂Fe(₃-S) cluster core

D.-S. Guo, Y.-H. Gao, X.-L. Zhang and J.-P. Ma

Abstract: The title compound, [₂-⁵,⁵-1,1'-(propane-1,3-diyldicarbonyl)dicyclopentadienyl]-₃-thio-heptacarbonylirondimolybdenum(2Fe-Mo, Mo-Mo), [Mo₂Fe(C₅H₆O₂)S(CO)₇], consists of a tetrahedral Mo₂Fe(₃-S) cluster core and a 1,1'-(propane-1,3-diyldicarbonyl)dicyclopentadienyl ligand. The cyclopentadienyl rings, coordinated to two Mo atoms, make a dihedral angle of 66.57 (10)°.

Online 12 May 2006

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