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Acta Cryst. (2006). E62, i131-i132 [ doi:10.1107/S1600536806016242 ]
Abstract: The structure of the title compound, NbSeCl3, was determined by single-crystal X-ray diffraction. The structure consists of NbSeCl3 chains centred on the Nb atoms. These chains, with a zigzag development along the c direction, show a regular alternation of short and long Nb-Nb distances. NbSeCl3 is isostructural with NbSeBr3; it may be described as 2(Nb4+) (Se22-) 6(Cl-), with the presence of both (Nb-Nb)8+ and (Se-Se)2- dimers.
Online 10 May 2006
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