Acta Cryst. (2006). E62, m1326-m1328  [ doi:10.1107/S1600536806017934 ]

Bis(diethylenetriamine)cobalt(II) tetrathiomolybdate(VI) oxotrithiamolybdate(VI)

M. Poisot, C. Näther and W. Bensch

Abstract: In the crystal structure of the title compound, [Co(C₄H₁₃N₃)₂]₂[MoS₄][MoS₃O], discrete [MoS₄]^2- and [MoS₃O]^2- anions, as well as [Co(C₄H₁₃N₃)₂]²⁺ cations are found. Both anions occupy the same crystallographic position and are therefore disordered. The Co atom is octahedrally coordinated by six N atoms of the diethylenetriamine ligand whereas the Mo atom shows a distorted tetrahedral geometry.

Online 17 May 2006

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