Acta Cryst. (2006). E62, m1428-m1430 [ doi:10.1107/S1600536806018903 ]
Abstract: The title compound, trans-[Pd(C6H4I)I(C18H15P)2], has been crystallized from dichloromethane. The crystal structure of this complex reveals a slightly distorted square-planar coordination geometry of the Pd atom, which lies on a twofold rotation axis. The P atoms in the triphenylphosphine ligands lie slightly out of the planes of the phenyl rings. The crystal structure is stabilized by short intermolecular II contacts, weak C-H(arene) hydrogen bonds and - stacking interactions.
Online 31 May 2006
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