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Acta Cryst. (2006). E62, m1428-m1430  [ doi:10.1107/S1600536806018903 ]

trans-Iodo(p-iodophenyl)bis(triphenylphosphine)palladium(II)

A. Gniewek, J. J. Ziólkowski and T. Lis

Abstract: The title compound, trans-[Pd(C6H4I)I(C18H15P)2], has been crystallized from dichloromethane. The crystal structure of this complex reveals a slightly distorted square-planar coordination geometry of the Pd atom, which lies on a twofold rotation axis. The P atoms in the triphenylphosphine ligands lie slightly out of the planes of the phenyl rings. The crystal structure is stabilized by short intermolecular I...I contacts, weak C-H...[pi](arene) hydrogen bonds and [pi]-[pi] stacking interactions.

Online 31 May 2006


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