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Acta Cryst. (2006). E62, m1250-m1251 [ doi:10.1107/S1600536806016680 ]
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4-acetylacetonato-di-3-acetylacetonato-pyridinetrisodium(I)]Abstract: In the title compound, [Na3(C5H7O2)3(C5H5N)]n, the two O atoms of one acetylacetonate (acac) ligand bridge four Na atoms in a 3 fashion, whereas the two other independent acac ligands bridge three Na atoms each, in a 2-fashion. All three Na atoms are in distorted square-pyramidal edge-sharing coordination polyhedra. The resulting assemblage is a polymeric chain directed along the c axis. This is the first example of Na-3-O(acac) bonds to be reported.
Online 10 May 2006
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