Acta Cryst. (2006). E62, m1365-m1367  [ doi:10.1107/S1600536806018563 ]

Poly[bis(-pentafluorobenzenethiolato)lead(II)]

H. Fleischer, C. Heller and D. Schollmeyer

Abstract: The title compound, [Pb(SC₆F₅)₂]_n, exhibits a layered structure containing two differently hexacoordinated Pb^II atoms. One is situated on a centre of inversion and is coordinated by six S atoms, its valence lone pair of electrons being consequently stereochemically inactive. The other Pb atom is pyramidally coordinated by three S atoms and forms three contacts to adjacent F atoms, the stereochemically active lone pair pointing towards the F₃ plane.

Online 24 May 2006

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