Acta Cryst. (2006). E62, m1356-m1358  [ doi:10.1107/S1600536806018277 ]

Chloro(dimethylformamide-O)(hydridotripyrazolylborato)(tripyrrol-1-ylphosphine-P)ruthenium(II)

C. Slugovc, K. Kirchner and K. Mereiter

Abstract: The title compound, [Ru(C₉H₁₀BN₆)Cl(C₃H₇NO)(C₁₂H₁₂N₃P)], has the Ru atom in octahedral coordination. The Ru-P bond length of 2.2022 (5) Å is some 0.107 Å shorter than that in the corresponding triphenylphosphine complex; this difference is attributable to the electronic donor-acceptor properties of the phosphine ligand.

Online 24 May 2006

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