Chloro­(dimethyl­formamide-κO)­(hydridotri­pyrazolyl­borato)­(tripyrrol-1-ylphosphine-κP)ruthenium(II)

The title compound, [Ru(C₉H₁₀BN₆)Cl(C₃H₇NO)(C₁₂H₁₂N₃P)], has the Ru atom in octa­hedral coordination. The Ru—P bond length of 2.2022 (5) Å is some 0.107 Å shorter than that in the corresponding triphenyl­phosphine complex; this difference is attributable to the electronic donor–acceptor properties of the phosphine ligand.

Key indicators

• Single-crystal X-ray study
• T = 298 K
• Mean [sigma](C-C) = 0.003 Å
• R factor = 0.025
• wR factor = 0.058
• Data-to-parameter ratio = 23.3

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT222_ALERT_3_C Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       3.17 Ratio

Author Response: Coordinated dimethylformamide is librating with the terminal atoms and causes this problem.

PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X)  Ru     -   Cl      ..       9.58 su

Author Response: Outer atoms moving about the metal centre, room temperature measurement.

PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X)  Ru     -   O       ..       6.57 su

Author Response: Outer atoms moving about the metal centre, room temperature measurement.

PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X)  Ru     -   N2      ..       5.24 su

Author Response: Outer atoms moving about the metal centre, room temperature measurement.

PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X)  Ru     -   N4      ..       6.68 su

Author Response: Outer atoms moving about the metal centre, room temperature measurement.

PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        N10

Author Response: Terminal methyl C atoms are librating and causing this problem, see previous alerts.

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   6 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   5 ALERT type 2 Indicator that the structure model may be wrong or deficient
   1 ALERT type 3 Indicator that the structure quality may be low
   0 ALERT type 4 Improvement, methodology, query or suggestion

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Computing details

Data collection: SMART (Bruker, 2003); cell refinement: SAINT (Bruker, 2003); data reduction: SAINT, SADABS and XPREP in SHELXTL (Bruker, 2003); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

Chloro(dimethylformamide-κO)(hydridotripyrazolylborato)(tripyrrol-1- ylphosphine-κP)ruthenium(II)

Crystal data

[Ru(C9H10BN6)Cl(C3H7NO)(C12H12N3P)]	F(000) = 1328
Mr = 651.87	Dx = 1.504 Mg m^−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 819 reflections
a = 10.046 (2) Å	θ = 2.5–29.6°
b = 22.749 (4) Å	µ = 0.73 mm^−1
c = 12.683 (2) Å	T = 298 K
β = 96.78 (1)°	Prism, yellow
V = 2878.3 (9) Å^3	0.59 × 0.38 × 0.31 mm
Z = 4

Data collection

Bruker SMART CCD diffractometer	8277 independent reflections
Radiation source: fine-focus sealed tube	7117 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.021
ω scans	θmax = 30.1°, θmin = 1.9°
Absorption correction: multi-scan (SADABS; Bruker, 2003)	h = −14→8
Tmin = 0.641, Tmax = 0.797	k = −29→32
23769 measured reflections	l = −17→17

Refinement

Refinement on F^2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F^2 > 2σ(F^2)] = 0.025	H-atom parameters constrained
wR(F^2) = 0.058	w = 1/[σ^2(Fo^2) + (0.023P)^2 + 0.8425P] where P = (Fo^2 + 2Fc^2)/3
S = 1.06	(Δ/σ)max = 0.001
8277 reflections	Δρmax = 0.35 e Å^−3
355 parameters	Δρmin = −0.45 e Å^−3
0 restraints	Extinction correction: SHELXL97, Fc^*=kFc[1+0.001xFc^2λ^3/sin(2θ)]^-1/4
Primary atom site location: structure-invariant direct methods	Extinction coefficient: 0.00085 (15)

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Ru	0.197717 (11)	0.180074 (5)	0.342503 (9)	0.02535 (4)
Cl	−0.02355 (4)	0.193084 (19)	0.39655 (4)	0.04310 (9)
N1	0.43521 (13)	0.22490 (6)	0.24723 (10)	0.0359 (3)
N2	0.39483 (12)	0.18227 (5)	0.31132 (10)	0.0313 (2)
C1	0.50270 (16)	0.14952 (8)	0.34273 (14)	0.0410 (4)
H1	0.5036	0.1172	0.3878	0.049*
C2	0.61323 (18)	0.17065 (9)	0.29842 (18)	0.0524 (5)
H2	0.7001	0.1558	0.3073	0.063*
C3	0.56671 (17)	0.21812 (9)	0.23886 (15)	0.0480 (4)
H3	0.6175	0.2418	0.1992	0.058*
N3	0.28494 (14)	0.30411 (6)	0.29964 (11)	0.0366 (3)
N4	0.22236 (13)	0.27209 (5)	0.36985 (10)	0.0323 (3)
C4	0.19130 (19)	0.30905 (7)	0.44375 (15)	0.0432 (4)
H4	0.1472	0.2986	0.5015	0.052*
C5	0.2338 (2)	0.36564 (8)	0.42306 (17)	0.0559 (5)
H5	0.2248	0.3994	0.4629	0.067*
C6	0.2920 (2)	0.36070 (8)	0.33119 (17)	0.0509 (4)
H6	0.3300	0.3913	0.2963	0.061*
N5	0.21546 (14)	0.24260 (6)	0.14015 (10)	0.0377 (3)
N6	0.13779 (12)	0.20346 (6)	0.18697 (10)	0.0324 (3)
C7	0.03901 (18)	0.18808 (8)	0.11270 (14)	0.0434 (4)
H7	−0.0297	0.1621	0.1231	0.052*
C8	0.0531 (2)	0.21622 (10)	0.01773 (15)	0.0557 (5)
H8	−0.0022	0.2128	−0.0462	0.067*
C9	0.1656 (2)	0.25013 (9)	0.03806 (14)	0.0504 (4)
H9	0.2015	0.2743	−0.0106	0.061*
B	0.33621 (19)	0.27295 (8)	0.20413 (15)	0.0382 (4)
H	0.3840	0.3044	0.1545	0.046*
P	0.17964 (4)	0.085885 (16)	0.30334 (3)	0.02963 (8)
N7	0.29614 (14)	0.05922 (6)	0.22569 (11)	0.0388 (3)
C10	0.33105 (19)	0.08761 (9)	0.13656 (15)	0.0478 (4)
H10	0.2976	0.1235	0.1101	0.057*
C11	0.4233 (2)	0.05361 (11)	0.09426 (18)	0.0622 (6)
H11	0.4635	0.0621	0.0336	0.075*
C12	0.4465 (2)	0.00375 (10)	0.1583 (2)	0.0642 (6)
H12	0.5053	−0.0267	0.1478	0.077*
C13	0.36861 (19)	0.00744 (8)	0.23832 (17)	0.0494 (4)
H13	0.3646	−0.0200	0.2922	0.059*
N8	0.03855 (13)	0.05892 (6)	0.22971 (11)	0.0374 (3)
C14	0.0303 (2)	0.01708 (8)	0.14938 (14)	0.0485 (4)
H14	0.1023	0.0004	0.1204	0.058*
C15	−0.1014 (2)	0.00486 (10)	0.12071 (16)	0.0619 (6)
H15	−0.1353	−0.0215	0.0682	0.074*
C16	−0.1771 (2)	0.03880 (11)	0.18390 (18)	0.0630 (6)
H16	−0.2700	0.0389	0.1811	0.076*
C17	−0.09054 (18)	0.07145 (9)	0.24993 (17)	0.0519 (5)
H17	−0.1142	0.0979	0.3005	0.062*
N9	0.19585 (15)	0.03329 (6)	0.40131 (11)	0.0393 (3)
C18	0.1278 (2)	−0.02017 (9)	0.40201 (17)	0.0555 (5)
H18	0.0549	−0.0315	0.3542	0.067*
C19	0.1860 (3)	−0.05284 (10)	0.4844 (2)	0.0720 (7)
H19	0.1604	−0.0904	0.5027	0.086*
C20	0.2926 (3)	−0.01965 (10)	0.53732 (18)	0.0643 (6)
H20	0.3490	−0.0313	0.5971	0.077*
C21	0.2981 (2)	0.03241 (8)	0.48528 (15)	0.0480 (4)
H21	0.3599	0.0623	0.5029	0.058*
O	0.27747 (12)	0.17020 (5)	0.50403 (9)	0.0383 (2)
C22	0.22069 (19)	0.15521 (8)	0.58024 (14)	0.0423 (4)
H22	0.1308	0.1446	0.5680	0.051*
N10	0.28033 (19)	0.15337 (7)	0.67866 (12)	0.0516 (4)
C23	0.4197 (3)	0.16935 (15)	0.7036 (2)	0.0976 (11)
H23A	0.4304	0.1931	0.7666	0.146*
H23B	0.4484	0.1912	0.6455	0.146*
H23C	0.4730	0.1344	0.7151	0.146*
C24	0.2099 (3)	0.13201 (15)	0.7654 (2)	0.0953 (10)
H24A	0.2279	0.1577	0.8255	0.143*
H24B	0.2403	0.0930	0.7848	0.143*
H24C	0.1153	0.1313	0.7429	0.143*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Ru	0.02500 (5)	0.02579 (6)	0.02518 (6)	0.00209 (4)	0.00266 (4)	−0.00086 (4)
Cl	0.03064 (18)	0.0484 (2)	0.0521 (2)	0.00268 (15)	0.01228 (16)	−0.00479 (18)
N1	0.0320 (6)	0.0406 (7)	0.0360 (7)	−0.0056 (5)	0.0070 (5)	−0.0021 (5)
N2	0.0271 (6)	0.0332 (6)	0.0331 (6)	0.0014 (5)	0.0021 (5)	−0.0032 (5)
C1	0.0309 (8)	0.0432 (9)	0.0476 (9)	0.0083 (6)	−0.0005 (7)	−0.0066 (7)
C2	0.0275 (8)	0.0630 (12)	0.0669 (12)	0.0056 (7)	0.0062 (8)	−0.0175 (10)
C3	0.0350 (8)	0.0598 (11)	0.0517 (10)	−0.0098 (8)	0.0153 (7)	−0.0136 (9)
N3	0.0411 (7)	0.0280 (6)	0.0399 (7)	−0.0017 (5)	0.0015 (6)	0.0030 (5)
N4	0.0354 (6)	0.0292 (6)	0.0314 (6)	0.0032 (5)	0.0002 (5)	0.0003 (5)
C4	0.0502 (10)	0.0373 (9)	0.0415 (9)	0.0074 (7)	0.0034 (7)	−0.0064 (7)
C5	0.0733 (14)	0.0308 (9)	0.0624 (12)	0.0055 (8)	0.0036 (10)	−0.0115 (8)
C6	0.0614 (12)	0.0276 (8)	0.0622 (12)	−0.0018 (7)	0.0015 (9)	0.0018 (8)
N5	0.0414 (7)	0.0416 (7)	0.0292 (6)	−0.0022 (6)	0.0006 (5)	0.0048 (5)
N6	0.0310 (6)	0.0359 (6)	0.0293 (6)	0.0010 (5)	−0.0006 (5)	0.0013 (5)
C7	0.0380 (8)	0.0500 (10)	0.0393 (9)	−0.0012 (7)	−0.0071 (7)	−0.0009 (7)
C8	0.0562 (11)	0.0721 (14)	0.0343 (9)	0.0002 (10)	−0.0132 (8)	0.0031 (9)
C9	0.0583 (11)	0.0611 (12)	0.0301 (8)	−0.0005 (9)	−0.0022 (7)	0.0098 (8)
B	0.0414 (9)	0.0380 (9)	0.0352 (9)	−0.0063 (7)	0.0048 (7)	0.0048 (7)
P	0.03114 (18)	0.02716 (17)	0.03127 (18)	0.00067 (13)	0.00660 (14)	−0.00224 (14)
N7	0.0398 (7)	0.0348 (7)	0.0437 (7)	−0.0001 (5)	0.0132 (6)	−0.0091 (6)
C10	0.0525 (10)	0.0518 (11)	0.0420 (9)	−0.0041 (8)	0.0179 (8)	−0.0100 (8)
C11	0.0576 (12)	0.0772 (15)	0.0569 (12)	−0.0100 (11)	0.0281 (10)	−0.0274 (11)
C12	0.0519 (12)	0.0609 (13)	0.0832 (16)	0.0074 (10)	0.0215 (11)	−0.0298 (12)
C13	0.0459 (10)	0.0385 (9)	0.0649 (12)	0.0062 (7)	0.0117 (9)	−0.0131 (8)
N8	0.0361 (7)	0.0362 (7)	0.0402 (7)	−0.0057 (5)	0.0060 (5)	−0.0060 (5)
C14	0.0608 (11)	0.0470 (10)	0.0387 (9)	−0.0136 (8)	0.0092 (8)	−0.0103 (7)
C15	0.0719 (14)	0.0689 (14)	0.0435 (10)	−0.0328 (11)	0.0005 (10)	−0.0083 (9)
C16	0.0441 (11)	0.0794 (16)	0.0645 (13)	−0.0236 (10)	0.0024 (9)	−0.0031 (11)
C17	0.0371 (9)	0.0590 (12)	0.0602 (12)	−0.0072 (8)	0.0089 (8)	−0.0120 (9)
N9	0.0465 (8)	0.0311 (7)	0.0409 (7)	0.0026 (5)	0.0081 (6)	0.0032 (5)
C18	0.0686 (13)	0.0414 (10)	0.0584 (12)	−0.0104 (9)	0.0151 (10)	0.0063 (9)
C19	0.104 (2)	0.0421 (11)	0.0713 (15)	−0.0031 (12)	0.0176 (14)	0.0195 (10)
C20	0.0854 (16)	0.0516 (12)	0.0554 (12)	0.0193 (11)	0.0066 (11)	0.0170 (10)
C21	0.0581 (11)	0.0409 (9)	0.0436 (9)	0.0098 (8)	0.0007 (8)	0.0036 (7)
O	0.0447 (6)	0.0405 (6)	0.0291 (5)	0.0001 (5)	0.0015 (5)	0.0018 (4)
C22	0.0478 (9)	0.0418 (9)	0.0377 (8)	0.0054 (7)	0.0069 (7)	0.0033 (7)
N10	0.0762 (12)	0.0471 (9)	0.0312 (7)	0.0046 (8)	0.0047 (7)	0.0063 (6)
C23	0.107 (2)	0.118 (3)	0.0580 (15)	−0.0503 (19)	−0.0292 (15)	0.0248 (15)
C24	0.115 (2)	0.121 (3)	0.0543 (14)	0.0221 (19)	0.0312 (15)	0.0356 (16)

Geometric parameters (Å, º)

Ru—N2	2.0652 (13)	N7—C13	1.384 (2)
Ru—N4	2.1315 (13)	C10—C11	1.364 (3)
Ru—N6	2.0631 (13)	C10—H10	0.9300
Ru—O	2.1217 (12)	C11—C12	1.399 (4)
Ru—P	2.2022 (5)	C11—H11	0.9300
Ru—Cl	2.4204 (6)	C12—C13	1.355 (3)
P—N7	1.7261 (14)	C12—H12	0.9300
P—N8	1.7161 (14)	C13—H13	0.9300
P—N9	1.7188 (14)	N8—C17	1.381 (2)
N1—C3	1.347 (2)	N8—C14	1.390 (2)
N1—N2	1.3578 (18)	C14—C15	1.359 (3)
N1—B	1.534 (2)	C14—H14	0.9300
N2—C1	1.336 (2)	C15—C16	1.400 (3)
C1—C2	1.388 (3)	C15—H15	0.9300
C1—H1	0.9300	C16—C17	1.355 (3)
C2—C3	1.368 (3)	C16—H16	0.9300
C2—H2	0.9300	C17—H17	0.9300
C3—H3	0.9300	N9—C21	1.390 (2)
N3—C6	1.347 (2)	N9—C18	1.396 (2)
N3—N4	1.3604 (18)	C18—C19	1.357 (3)
N3—B	1.544 (2)	C18—H18	0.9300
N4—C4	1.324 (2)	C19—C20	1.414 (4)
C4—C5	1.391 (3)	C19—H19	0.9300
C4—H4	0.9300	C20—C21	1.360 (3)
C5—C6	1.368 (3)	C20—H20	0.9300
C5—H5	0.9300	C21—H21	0.9300
C6—H6	0.9300	O—C22	1.227 (2)
N5—C9	1.343 (2)	C22—N10	1.320 (2)
N5—N6	1.3652 (18)	C22—H22	0.9300
N5—B	1.541 (2)	N10—C23	1.445 (3)
N6—C7	1.332 (2)	N10—C24	1.459 (3)
C7—C8	1.386 (3)	C23—H23A	0.9600
C7—H7	0.9300	C23—H23B	0.9600
C8—C9	1.368 (3)	C23—H23C	0.9600
C8—H8	0.9300	C24—H24A	0.9600
C9—H9	0.9300	C24—H24B	0.9600
B—H	1.1000	C24—H24C	0.9600
N7—C10	1.383 (2)
O—Ru—P	97.27 (3)	N9—P—N7	98.92 (7)
O—Ru—Cl	89.67 (4)	N8—P—Ru	120.75 (5)
P—Ru—Cl	97.40 (2)	N9—P—Ru	121.06 (5)
O—Ru—N6	170.00 (5)	N7—P—Ru	115.29 (5)
P—Ru—N4	175.69 (4)	C10—N7—C13	108.14 (15)
Cl—Ru—N2	169.96 (4)	C10—N7—P	123.84 (13)
N6—Ru—N2	89.36 (5)	C13—N7—P	128.01 (13)
N2—Ru—O	85.76 (5)	C11—C10—N7	107.8 (2)
N6—Ru—N4	85.27 (5)	C11—C10—H10	126.1
N2—Ru—N4	84.94 (5)	N7—C10—H10	126.1
O—Ru—N4	85.61 (5)	C10—C11—C12	107.81 (19)
N6—Ru—P	91.62 (4)	C10—C11—H11	126.1
N2—Ru—P	92.05 (4)	C12—C11—H11	126.1
N6—Ru—Cl	93.74 (4)	C13—C12—C11	108.24 (18)
N4—Ru—Cl	85.80 (4)	C13—C12—H12	125.9
C3—N1—N2	109.30 (14)	C11—C12—H12	125.9
C3—N1—B	130.85 (15)	C12—C13—N7	107.96 (19)
N2—N1—B	119.69 (12)	C12—C13—H13	126.0
C1—N2—N1	106.71 (13)	N7—C13—H13	126.0
C1—N2—Ru	133.75 (12)	C17—N8—C14	107.56 (15)
N1—N2—Ru	119.53 (9)	C17—N8—P	123.96 (12)
N2—C1—C2	110.21 (17)	C14—N8—P	128.14 (13)
N2—C1—H1	124.9	C15—C14—N8	107.94 (18)
C2—C1—H1	124.9	C15—C14—H14	126.0
C3—C2—C1	105.03 (15)	N8—C14—H14	126.0
C3—C2—H2	127.5	C14—C15—C16	108.15 (18)
C1—C2—H2	127.5	C14—C15—H15	125.9
N1—C3—C2	108.74 (16)	C16—C15—H15	125.9
N1—C3—H3	125.6	C17—C16—C15	107.68 (19)
C2—C3—H3	125.6	C17—C16—H16	126.2
C6—N3—N4	109.22 (14)	C15—C16—H16	126.2
C6—N3—B	131.39 (15)	C16—C17—N8	108.67 (18)
N4—N3—B	119.37 (13)	C16—C17—H17	125.7
C4—N4—N3	106.81 (14)	N8—C17—H17	125.7
C4—N4—Ru	134.95 (12)	C21—N9—C18	107.52 (15)
N3—N4—Ru	118.24 (9)	C21—N9—P	124.22 (13)
N4—C4—C5	110.55 (17)	C18—N9—P	127.33 (14)
N4—C4—H4	124.7	C19—C18—N9	108.4 (2)
C5—C4—H4	124.7	C19—C18—H18	125.8
C6—C5—C4	104.83 (16)	N9—C18—H18	125.8
C6—C5—H5	127.6	C18—C19—C20	107.86 (19)
C4—C5—H5	127.6	C18—C19—H19	126.1
N3—C6—C5	108.59 (16)	C20—C19—H19	126.1
N3—C6—H6	125.7	C21—C20—C19	107.9 (2)
C5—C6—H6	125.7	C21—C20—H20	126.1
C9—N5—N6	109.60 (14)	C19—C20—H20	126.1
C9—N5—B	129.15 (15)	C20—C21—N9	108.39 (19)
N6—N5—B	121.20 (12)	C20—C21—H21	125.8
C7—N6—N5	106.26 (13)	N9—C21—H21	125.8
C7—N6—Ru	135.85 (12)	C22—O—Ru	129.21 (12)
N5—N6—Ru	117.83 (9)	O—C22—N10	123.53 (18)
N6—C7—C8	110.46 (17)	O—C22—H22	118.2
N6—C7—H7	124.8	N10—C22—H22	118.2
C8—C7—H7	124.8	C22—N10—C23	121.24 (18)
C9—C8—C7	105.28 (16)	C22—N10—C24	121.1 (2)
C9—C8—H8	127.4	C23—N10—C24	117.5 (2)
C7—C8—H8	127.4	N10—C23—H23A	109.5
N5—C9—C8	108.39 (17)	N10—C23—H23B	109.5
N5—C9—H9	125.8	H23A—C23—H23B	109.5
C8—C9—H9	125.8	N10—C23—H23C	109.5
N1—B—N5	107.77 (14)	H23A—C23—H23C	109.5
N1—B—N3	108.06 (13)	H23B—C23—H23C	109.5
N5—B—N3	107.71 (14)	N10—C24—H24A	109.5
N1—B—H	111.1	N10—C24—H24B	109.5
N5—B—H	111.1	H24A—C24—H24B	109.5
N3—B—H	111.1	N10—C24—H24C	109.5
N8—P—N9	98.41 (7)	H24A—C24—H24C	109.5
N8—P—N7	97.82 (7)	H24B—C24—H24C	109.5
C3—N1—N2—C1	0.38 (17)	N6—N5—B—N3	−55.61 (19)
B—N1—N2—C1	−175.53 (14)	C6—N3—B—N1	120.40 (19)
C3—N1—N2—Ru	179.49 (11)	N4—N3—B—N1	−58.21 (18)
B—N1—N2—Ru	3.58 (18)	C6—N3—B—N5	−123.43 (19)
N6—Ru—N2—C1	−142.27 (15)	N4—N3—B—N5	57.97 (18)
O—Ru—N2—C1	46.46 (15)	N6—Ru—P—N8	−48.28 (7)
N4—Ru—N2—C1	132.42 (15)	N2—Ru—P—N8	−137.70 (7)
P—Ru—N2—C1	−50.68 (15)	O—Ru—P—N8	136.31 (6)
Cl—Ru—N2—C1	109.6 (2)	Cl—Ru—P—N8	45.70 (6)
N6—Ru—N2—N1	38.91 (11)	N6—Ru—P—N9	−172.14 (7)
O—Ru—N2—N1	−132.36 (11)	N2—Ru—P—N9	98.44 (7)
N4—Ru—N2—N1	−46.40 (11)	O—Ru—P—N9	12.45 (7)
P—Ru—N2—N1	130.51 (10)	Cl—Ru—P—N9	−78.16 (6)
Cl—Ru—N2—N1	−69.2 (3)	N6—Ru—P—N7	68.86 (7)
N1—N2—C1—C2	−0.40 (19)	N2—Ru—P—N7	−20.56 (7)
Ru—N2—C1—C2	−179.33 (12)	O—Ru—P—N7	−106.55 (7)
N2—C1—C2—C3	0.3 (2)	Cl—Ru—P—N7	162.84 (6)
N2—N1—C3—C2	−0.2 (2)	N8—P—N7—C10	84.37 (15)
B—N1—C3—C2	175.08 (17)	N9—P—N7—C10	−175.78 (14)
C1—C2—C3—N1	0.0 (2)	Ru—P—N7—C10	−45.10 (16)
C6—N3—N4—C4	0.07 (19)	N8—P—N7—C13	−94.73 (16)
B—N3—N4—C4	178.96 (14)	N9—P—N7—C13	5.11 (17)
C6—N3—N4—Ru	−179.31 (11)	Ru—P—N7—C13	135.79 (14)
B—N3—N4—Ru	−0.43 (18)	C13—N7—C10—C11	0.4 (2)
N6—Ru—N4—C4	135.72 (16)	P—N7—C10—C11	−178.87 (14)
N2—Ru—N4—C4	−134.50 (16)	N7—C10—C11—C12	−0.4 (2)
O—Ru—N4—C4	−48.38 (16)	C10—C11—C12—C13	0.3 (3)
Cl—Ru—N4—C4	41.62 (16)	C11—C12—C13—N7	0.0 (2)
N6—Ru—N4—N3	−45.11 (11)	C10—N7—C13—C12	−0.2 (2)
N2—Ru—N4—N3	44.67 (11)	P—N7—C13—C12	178.99 (14)
O—Ru—N4—N3	130.79 (11)	N9—P—N8—C17	85.71 (16)
Cl—Ru—N4—N3	−139.22 (11)	N7—P—N8—C17	−174.01 (16)
N3—N4—C4—C5	−0.3 (2)	Ru—P—N8—C17	−48.31 (17)
Ru—N4—C4—C5	178.91 (13)	N9—P—N8—C14	−86.70 (16)
N4—C4—C5—C6	0.4 (2)	N7—P—N8—C14	13.58 (17)
N4—N3—C6—C5	0.2 (2)	Ru—P—N8—C14	139.28 (14)
B—N3—C6—C5	−178.50 (18)	C17—N8—C14—C15	0.6 (2)
C4—C5—C6—N3	−0.4 (2)	P—N8—C14—C15	173.95 (14)
C9—N5—N6—C7	−1.02 (19)	N8—C14—C15—C16	−0.5 (3)
B—N5—N6—C7	176.52 (15)	C14—C15—C16—C17	0.3 (3)
C9—N5—N6—Ru	176.66 (12)	C15—C16—C17—N8	0.1 (3)
B—N5—N6—Ru	−5.80 (19)	C14—N8—C17—C16	−0.4 (2)
N2—Ru—N6—C7	139.57 (17)	P—N8—C17—C16	−174.14 (15)
N4—Ru—N6—C7	−135.46 (17)	N8—P—N9—C21	179.13 (14)
P—Ru—N6—C7	47.54 (17)	N7—P—N9—C21	79.79 (15)
Cl—Ru—N6—C7	−49.99 (17)	Ru—P—N9—C21	−47.04 (16)
N2—Ru—N6—N5	−37.23 (11)	N8—P—N9—C18	11.59 (17)
N4—Ru—N6—N5	47.74 (11)	N7—P—N9—C18	−87.75 (17)
P—Ru—N6—N5	−129.26 (11)	Ru—P—N9—C18	145.42 (14)
Cl—Ru—N6—N5	133.21 (11)	C21—N9—C18—C19	0.3 (2)
N5—N6—C7—C8	0.9 (2)	P—N9—C18—C19	169.54 (16)
Ru—N6—C7—C8	−176.16 (14)	N9—C18—C19—C20	0.2 (3)
N6—C7—C8—C9	−0.4 (2)	C18—C19—C20—C21	−0.7 (3)
N6—N5—C9—C8	0.8 (2)	C19—C20—C21—N9	0.9 (2)
B—N5—C9—C8	−176.52 (18)	C18—N9—C21—C20	−0.8 (2)
C7—C8—C9—N5	−0.2 (2)	P—N9—C21—C20	−170.40 (14)
C3—N1—B—N5	126.27 (17)	N2—Ru—O—C22	−165.96 (15)
N2—N1—B—N5	−58.83 (18)	N4—Ru—O—C22	108.80 (15)
C3—N1—B—N3	−117.59 (18)	P—Ru—O—C22	−74.43 (14)
N2—N1—B—N3	57.30 (18)	Cl—Ru—O—C22	22.99 (14)
C9—N5—B—N1	−122.24 (19)	Ru—O—C22—N10	−176.64 (13)
N6—N5—B—N1	60.75 (19)	O—C22—N10—C23	0.1 (3)
C9—N5—B—N3	121.40 (19)	O—C22—N10—C24	−176.5 (2)