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Acta Cryst. (2006). E62, m1370-m1372  [ doi:10.1107/S1600536806018733 ]

catena-Poly[[(pyrazino[2,3-f][1,10]phenanthroline)copper(I)]-[mu]2-chloro]

G.-B. Che, Z.-L. Xu and C.-B. Liu

Abstract: In the title compound, [CuCl(C14H8N4)]n, the central CuI ion displays a distorted tetrahedral geometry, coordinated by two Cl- ions and two N atoms from a bidentate pyrazino[2,3-f][1,10]phenanthroline (PyPhen) ligand. Each Cl- ion bridges two CuI atoms, forming a zigzag chain structure. Cu and Cl have site symmetry 2; the complete PyPhen molecule is generated by twofold symmetry.

Online 24 May 2006


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