Acta Cryst. (2006). E62, m1431-m1433  [ doi:10.1107/S1600536806019349 ]

[1,2-Bis(diphenylphosphino)ethane]bis(N,N-dimethyldithiocarbamato)iron(III) tetrafluoroborate

P. D. W. Boyd and C. E. F. Rickard

Abstract: The title compound, [Fe(C₃H₆NS₂)₂(C₂₆H₂₄P₂)]BF₄, contains a six-coordinate iron(III) cationic complex, with two bidentate dimethyldithiocarbamate and one 1,2-bis(diphenylphosphino)ethane ligands, and a disordered tetrafluoroborate anion. The cation possesses a crystallographic twofold rotation axis. The cations assemble in the crystal structure in two-dimensional layers via complementary C-H(phenyl) interactions with channels occupied by tetrafluorborate anions.

Online 31 May 2006

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