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Acta Cryst. (2006). E62, m1362-m1364  [ doi:10.1107/S1600536806018654 ]

catena-Poly[bis[[4-(1H-1,3,7,8-tetraazacyclopenta[l]phenanthren-2-yl)phenol-[kappa]2N7,N8]cadmium(II)]-di-[mu]3-benzene-1,3-dicarboxylato-[kappa]4O:O':O'',O''']

G.-B. Che, C.-B. Liu, Y.-C. Cui and C.-B. Li

Abstract: In the title compound, [Cd2(C8H4O4)2(C19H12N4O)2]n, each Cd atom is six-coordinated by two N atoms from the substituted phenanthroline ligand and four O atoms from three different benzene-1,3-dicarboxylate (m-BDC) ligands. Pairs of Cd atoms with two carboxylate bridges form a dimeric unit with twofold rotation symmetry, and these dimeric units are further bridged by m-BDC ligands to form a double-chain structure. Furthermore, neighbouring double-chain polymers are interdigitated, leading to a two-dimensional supramolecular structure.

Online 24 May 2006


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