Acta Cryst. (2006). E62, m1229-m1231  [ doi:10.1107/S1600536806015868 ]

meso-Tetrakis(ethylenediamine)-1⁴N,N';3⁴N,N'-di--sulfidoacetato-1:2³O,S:S;2:3³S:S,O-dicobalt(III)silver(I) triperchlorate

N. Yoshinari, A. Igashira-Kamiyama and T. Konno

Abstract: In the crystal structure of the title compound, [AgCo₂(C₂H₄O₂S)₂(C₂H₈N₂)₄](ClO₄)₃, the Ag^I atom is located on an inversion center and is linearly coordinated by two sulfide S atoms from - and -[Co^III(C₂H₄O₂S)(C₂H₈N₂)₂]⁺ octahedral units, forming a meso configurational S-bridged Co^III-Ag^I-Co^III trinuclear structure.

Online 10 May 2006

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