Acta Cryst. (2006). E62, m1309-m1311  [ doi:10.1107/S1600536806015637 ]

A new polymorph of trans-carbonylchlorobis[tris(4-fluorophenyl)phosphine]rhodium(I)

R. Meijboom, A. Muller and A. Roodt

Abstract: In the title compound, trans-[RhCl{P(4-FC₆H₄)₃}₂(CO)], where 4-FC₆H₄ is 4-fluorophenyl, the Rh-P bond distances are 2.3118 (5), 2.3220 (5), 2.3136 (5) and 2.3233 (5) Å, and the Rh-Cl bond distances are 2.3689 (5) and 2.3694 (5) Å. The effective cone angles (_E) for the phosphine ligands were calculated to be 155 and 156°.

Online 17 May 2006

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