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Acta Cryst. (2006). E62, m1255-m1257  [ doi:10.1107/S1600536806016898 ]

1,4-Diazoniabicyclo[2.2.2]octane tetraaquatetrachlorolanthanate(III) chloride

L. K. Ritchie and W. T. A. Harrison

Abstract: The title compound, (C6H14N2)[LaCl4(H2O)4]Cl, is built up from organic cations, [La(H2O)4Cl4]- complex anions and uncoordinated chloride ions. The previously unseen rare-earth-containing complex ion is irregular in shape. A network of O-H...Cl and N-H...Cl hydrogen bonds helps to establish the structure. Prominent among these are two well defined trifurcated N-H...(Cl,Cl,Cl) interactions. The La atom, one Cl atom, two N atoms and two C atoms possess site symmetry m.

Online 10 May 2006


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