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The title compound, C10H24N2O2, was synthesized by N-alkyl­ation of 1,2-dichloro­ethane with (S)-2-amino-1-butanol. In the crystal structure, O—H...N and N—H...O link the mol­ecules into sheets in the bc plane.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806015352/sj2043sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536806015352/sj2043Isup2.hkl
Contains datablock I

CCDC reference: 610889

Key indicators

  • Single-crystal X-ray study
  • T = 294 K
  • Mean [sigma](C-C) = 0.004 Å
  • R factor = 0.041
  • wR factor = 0.102
  • Data-to-parameter ratio = 9.3

checkCIF/PLATON results

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Alert level C PLAT066_ALERT_1_C Predicted and Reported Transmissions Identical . ? PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 2.70 Ratio PLAT222_ALERT_3_C Large Non-Solvent H Ueq(max)/Ueq(min) ... 3.58 Ratio
Alert level G REFLT03_ALERT_4_G Please check that the estimate of the number of Friedel pairs is correct. If it is not, please give the correct count in the _publ_section_exptl_refinement section of the submitted CIF. From the CIF: _diffrn_reflns_theta_max 26.33 From the CIF: _reflns_number_total 1318 Count of symmetry unique reflns 1336 Completeness (_total/calc) 98.65% TEST3: Check Friedels for noncentro structure Estimate of Friedel pairs measured 0 Fraction of Friedel pairs measured 0.000 Are heavy atom types Z>Si present no
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 3 ALERT level C = Check and explain 1 ALERT level G = General alerts; check 1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 1 ALERT type 2 Indicator that the structure model may be wrong or deficient 1 ALERT type 3 Indicator that the structure quality may be low 1 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: SMART (Bruker, 1997); cell refinement: SAINT (Bruker, 1997); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1997); software used to prepare material for publication: SHELXTL.

(S,S)-2,2'-(1,2-Ethanediyldiimino)dibutan-1-ol top
Crystal data top
C10H24N2O2F(000) = 228
Mr = 204.31Dx = 1.107 Mg m3
Monoclinic, P21Mo Kα radiation, λ = 0.71073 Å
Hall symbol: P 2ybCell parameters from 1264 reflections
a = 7.157 (3) Åθ = 2.9–25.3°
b = 8.440 (4) ŵ = 0.08 mm1
c = 10.193 (5) ÅT = 294 K
β = 95.631 (8)°Block, colourless
V = 612.7 (5) Å30.22 × 0.20 × 0.10 mm
Z = 2
Data collection top
Bruker SMART-1000 CCD area-detector
diffractometer
1318 independent reflections
Radiation source: fine-focus sealed tube1049 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.026
φ and ω scansθmax = 26.3°, θmin = 2.0°
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)
h = 88
Tmin = 0.983, Tmax = 0.992k = 106
3317 measured reflectionsl = 1212
Refinement top
Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.041H atoms treated by a mixture of independent and constrained refinement
wR(F2) = 0.102 w = 1/[σ2(Fo2) + (0.0537P)2 + 0.0476P]
where P = (Fo2 + 2Fc2)/3
S = 1.07(Δ/σ)max = 0.001
1318 reflectionsΔρmax = 0.50 e Å3
141 parametersΔρmin = 0.42 e Å3
1 restraintAbsolute structure: Friedel pairs merged
Primary atom site location: structure-invariant direct methods
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
O10.8028 (3)0.2364 (3)0.3341 (2)0.0496 (6)
H10.855 (5)0.333 (6)0.361 (3)0.074*
O20.3356 (3)0.0029 (3)0.60362 (19)0.0421 (5)
H2B0.376 (4)0.111 (5)0.600 (3)0.063*
N10.4292 (3)0.1791 (3)0.3932 (2)0.0303 (5)
H1C0.519 (4)0.155 (4)0.451 (2)0.036*
N20.0506 (3)0.0460 (3)0.5967 (2)0.0316 (5)
H2A0.036 (4)0.036 (4)0.527 (3)0.038*
C10.6465 (3)0.2648 (3)0.2403 (3)0.0373 (7)
H1A0.68380.25110.15200.045*
H1B0.60380.37310.24860.045*
C20.4875 (3)0.1515 (3)0.2613 (2)0.0319 (6)
H20.38120.18100.19810.038*
C30.5370 (4)0.0212 (4)0.2317 (3)0.0422 (7)
H3A0.66020.04520.27560.051*
H3B0.44710.09070.26790.051*
C40.5373 (6)0.0550 (5)0.0864 (3)0.0697 (11)
H4A0.41970.02260.04100.105*
H4B0.55480.16650.07350.105*
H4C0.63770.00240.05230.105*
C50.2657 (3)0.0865 (3)0.4261 (3)0.0356 (6)
H5A0.30010.02430.43650.043*
H5B0.16550.09480.35520.043*
C60.1989 (4)0.1480 (3)0.5521 (3)0.0348 (6)
H6A0.30380.15230.61990.042*
H6B0.15080.25480.53810.042*
C70.2165 (4)0.0134 (4)0.7218 (2)0.0394 (7)
H7A0.17300.09040.75200.047*
H7B0.28660.05930.78910.047*
C80.0488 (4)0.1174 (3)0.7026 (2)0.0342 (6)
H80.09350.22300.67460.041*
C90.0776 (4)0.1323 (4)0.8306 (3)0.0482 (8)
H9A0.10170.02710.86670.058*
H9B0.19700.17640.81120.058*
C100.0003 (5)0.2337 (6)0.9340 (3)0.0861 (15)
H10A0.04050.33360.89600.129*
H10B0.09510.25131.00550.129*
H10C0.10540.18090.96650.129*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
O10.0365 (11)0.0385 (12)0.0726 (14)0.0050 (10)0.0011 (10)0.0063 (11)
O20.0349 (10)0.0395 (12)0.0505 (11)0.0049 (9)0.0031 (8)0.0096 (10)
N10.0256 (10)0.0333 (13)0.0319 (11)0.0017 (10)0.0018 (9)0.0011 (10)
N20.0311 (11)0.0287 (12)0.0356 (12)0.0048 (10)0.0056 (9)0.0016 (10)
C10.0387 (15)0.0332 (16)0.0416 (15)0.0007 (13)0.0120 (12)0.0038 (12)
C20.0333 (13)0.0322 (15)0.0305 (13)0.0050 (12)0.0040 (11)0.0025 (11)
C30.0461 (15)0.0341 (16)0.0472 (16)0.0037 (14)0.0087 (13)0.0033 (14)
C40.095 (3)0.058 (2)0.056 (2)0.019 (2)0.0038 (19)0.0184 (17)
C50.0331 (13)0.0349 (15)0.0393 (14)0.0063 (13)0.0062 (11)0.0039 (12)
C60.0341 (13)0.0305 (14)0.0407 (14)0.0052 (12)0.0081 (12)0.0011 (12)
C70.0369 (14)0.0418 (17)0.0403 (14)0.0066 (13)0.0080 (11)0.0022 (13)
C80.0347 (14)0.0293 (15)0.0395 (14)0.0025 (12)0.0091 (12)0.0013 (12)
C90.0426 (16)0.058 (2)0.0442 (16)0.0096 (16)0.0061 (13)0.0104 (15)
C100.075 (2)0.116 (4)0.070 (2)0.012 (3)0.019 (2)0.045 (3)
Geometric parameters (Å, º) top
O1—C11.419 (3)C4—H4B0.9600
O1—H10.93 (5)C4—H4C0.9600
O2—C71.412 (3)C5—C61.506 (4)
O2—H2B0.96 (4)C5—H5A0.9700
N1—C21.464 (3)C5—H5B0.9700
N1—C51.473 (3)C6—H6A0.9700
N1—H1C0.85 (3)C6—H6B0.9700
N2—C61.473 (3)C7—C81.515 (4)
N2—C81.478 (3)C7—H7A0.9700
N2—H2A0.90 (3)C7—H7B0.9700
C1—C21.518 (4)C8—C91.519 (4)
C1—H1A0.9700C8—H80.9800
C1—H1B0.9700C9—C101.507 (4)
C2—C31.536 (4)C9—H9A0.9700
C2—H20.9800C9—H9B0.9700
C3—C41.508 (4)C10—H10A0.9600
C3—H3A0.9700C10—H10B0.9600
C3—H3B0.9700C10—H10C0.9600
C4—H4A0.9600
C1—O1—H1109 (2)C6—C5—H5A109.7
C7—O2—H2B106.2 (19)N1—C5—H5B109.7
C2—N1—C5115.4 (2)C6—C5—H5B109.7
C2—N1—H1C109.3 (17)H5A—C5—H5B108.2
C5—N1—H1C106.3 (19)N2—C6—C5111.1 (2)
C6—N2—C8113.6 (2)N2—C6—H6A109.4
C6—N2—H2A105.9 (17)C5—C6—H6A109.4
C8—N2—H2A105.8 (16)N2—C6—H6B109.4
O1—C1—C2110.6 (2)C5—C6—H6B109.4
O1—C1—H1A109.5H6A—C6—H6B108.0
C2—C1—H1A109.5O2—C7—C8111.5 (2)
O1—C1—H1B109.5O2—C7—H7A109.3
C2—C1—H1B109.5C8—C7—H7A109.3
H1A—C1—H1B108.1O2—C7—H7B109.3
N1—C2—C1108.3 (2)C8—C7—H7B109.3
N1—C2—C3115.1 (2)H7A—C7—H7B108.0
C1—C2—C3112.3 (2)N2—C8—C7107.6 (2)
N1—C2—H2106.9N2—C8—C9111.8 (2)
C1—C2—H2106.9C7—C8—C9110.5 (2)
C3—C2—H2106.9N2—C8—H8109.0
C4—C3—C2113.3 (3)C7—C8—H8109.0
C4—C3—H3A108.9C9—C8—H8109.0
C2—C3—H3A108.9C10—C9—C8114.7 (3)
C4—C3—H3B108.9C10—C9—H9A108.6
C2—C3—H3B108.9C8—C9—H9A108.6
H3A—C3—H3B107.7C10—C9—H9B108.6
C3—C4—H4A109.5C8—C9—H9B108.6
C3—C4—H4B109.5H9A—C9—H9B107.6
H4A—C4—H4B109.5C9—C10—H10A109.5
C3—C4—H4C109.5C9—C10—H10B109.5
H4A—C4—H4C109.5H10A—C10—H10B109.5
H4B—C4—H4C109.5C9—C10—H10C109.5
N1—C5—C6109.7 (2)H10A—C10—H10C109.5
N1—C5—H5A109.7H10B—C10—H10C109.5
C5—N1—C2—C1175.7 (2)N1—C5—C6—N2173.0 (2)
C5—N1—C2—C357.8 (3)C6—N2—C8—C7170.5 (2)
O1—C1—C2—N161.4 (3)C6—N2—C8—C968.0 (3)
O1—C1—C2—C366.7 (3)O2—C7—C8—N257.3 (3)
N1—C2—C3—C4162.1 (3)O2—C7—C8—C9179.7 (2)
C1—C2—C3—C473.4 (3)N2—C8—C9—C10167.9 (3)
C2—N1—C5—C6169.3 (2)C7—C8—C9—C1072.2 (4)
C8—N2—C6—C5167.6 (2)
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O1—H1···N2i0.93 (5)1.95 (5)2.877 (3)174 (3)
O2—H2B···N1ii0.96 (4)1.82 (4)2.767 (3)174 (3)
N1—H1C···O2iii0.85 (3)2.23 (3)3.014 (3)153 (3)
Symmetry codes: (i) x+1, y+1/2, z+1; (ii) x, y1/2, z+1; (iii) x+1, y, z.
 

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