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Acta Cryst. (2006). E62, m1252-m1254  [ doi:10.1107/S1600536806016540 ]

cis-Dichlorobis(triphenylphosphine-[kappa]P)platinum(II)

H.-K. Fun, S. Chantrapromma, Y.-C. Liu, Z.-F. Chen and H. Liang

Abstract: The geometry of the Pt atom in the title compound, [PtCl2(C18H15P)2], is square planar. There are two crystallographically independent molecules, A and B, in the asymmetric unit. The average Pt-P bond distances are 2.2614 (9) (in A) and 2.2659 (10) Å (in B), with Pt-Cl distances of 2.3463 (8) (in A) and 2.3496 (10) Å (in B). The molecular structure is stabilized by intermolecular C-H...Cl hydrogen bonds and C-H...[pi] interactions.

Online 10 May 2006


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