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Acta Cryst. (2006). E62, m1600-m1602 [ doi:10.1107/S1600536806022884 ]
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4-benzene-1,4-dicarboxylato-di-2-benzene-1,4-dicarboxylato-bis(N,N'-dimethylformamide)digadolinium(III)]Abstract: In the title compound, [Gd2(C8H4O4)3(C3H7NO)2(H2O)2]n, the central GdIII atom is nine-coordinated by seven O atoms from benzene-1,4-dicarboxylate (1,4-BDC) ligands, one dimethylformamide and one water molecule in a distorted tricapped trigonal-prism coordination. The 1,4-BDC ligands link the GdIII atoms, forming a three-dimensional structure. All aromatic rings are located on centres of inversion. The water molecule forms hydrogen bonds to carboxylate groups.
Online 21 June 2006
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