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Acta Cryst. (2006). E62, m1542-m1544  [ doi:10.1107/S1600536806021490 ]

[4-(Ferrocene-1-carboxamido)pyridine](tetraphenylporphyrinato)zinc(II) toluene sesquisolvate

P. D. W. Boyd and A. Hosseini

Abstract: The title compound is a five-coordinate square-pyramidal zinc-porphyrin complex, [(C44H28N4)Zn(C10H9N2O)Fe(C5H5)]·1.5C7H8, with a 4-(ferrocene-1-carboxamido)pyridine apical ligand. The complexes assemble in the crystal structure by head-to-tail stacking of the 4-(ferrocene-1-carboxamido)pyridine groups, which interact through [pi]-[pi] stacking of the pyridine and cyclopentadienyl rings.

Online 14 June 2006


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