Acta Cryst. (2006). E62, m1489-m1491  [ doi:10.1107/S1600536806020332 ]

cis-(2,2'-Bipyridyl)dichloromanganese(II)-thiourea (1/1)

S. R. Choudhury, A. Dutta, S. Mukhopadhyay, L.-P. Lu and M.-L. Zhu

Abstract: In the title compound, [MnCl₂(C₁₀H₈N₂)₂]·SC(NH₂)₂, the Mn^II atom is coordinated by four N atoms from two 2,2'-bipyridyl ligands and two Cl^- anions, resulting in a distorted cis-MnCl₂N₄ octahedral geometry. The complexes and thiourea molecules are connected by N-HCl and N-HS hydrogen bonds, leading to one-dimensional tapes which are further organized into a three-dimensional structure through -, C-H and C-HCl interactions.

Online 9 June 2006

Copyright © International Union of Crystallography
IUCr Webmaster