(4-Amino­benzoato)tris­(2-methyl-2-phenyl­propyl)tin(IV)

Ding, Y.-J.; Zhao, X.; Sun, Y.-X.; Tian, L.-J.

doi:10.1107/S1600536806024044

(4-Aminobenzoato)tris(2-methyl-2-phenylpropyl)tin(IV)

Y.-J. Ding, X. Zhao, Y.-X. Sun and L.-J. Tian

The title compound, [Sn(C₁₀H₁₃)₃(C₇H₆NO₂)], crystallizes with two independent molecules in the asymmetric unit. The Sn atom is four-coordinate and has a distorted SnC₃O tetrahedral geometry. N—H

O hydrogen bonds help to establish the crystal packing.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806024044/hb2093sup1.cif Contains datablocks global, I
	Structure factor file (CIF format) https://doi.org/10.1107/S1600536806024044/hb2093Isup2.hkl Contains datablock I

CCDC reference: 613705

checkCIF report

Key indicators

Single-crystal X-ray study
T = 295 K
Mean (C-C) = 0.010 Å
R factor = 0.047
wR factor = 0.105
Data-to-parameter ratio = 19.2

checkCIF/PLATON results

No syntax errors found



Alert level B
PLAT241_ALERT_2_B Check High      Ueq as Compared to Neighbors for        C9'

Alert level C
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       2.79 Ratio
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       2.55 Ratio
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for         C9
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C17
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C19
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C37
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for       C34'
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for       C37'
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for         C5
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C12
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C15
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C20
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C25
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C32
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C35
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C5'
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for       C12'
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for       C15'
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for       C31'
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for       C32'
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for       C35'
PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ...         10
PLAT420_ALERT_2_C D-H Without Acceptor       N1     -   H1D    ...          ?
PLAT420_ALERT_2_C D-H Without Acceptor       N1'    -   H1D'   ...          ?
PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........          4

Alert level G
REFLT03_ALERT_4_G Please check that the estimate of the number of Friedel pairs is
            correct. If it is not, please give the correct count in the
            _publ_section_exptl_refinement section of the submitted CIF.
           From the CIF: _diffrn_reflns_theta_max           26.50
           From the CIF: _reflns_number_total              14187
           Count of symmetry unique reflns         7819
           Completeness (_total/calc)            181.44%
           TEST3: Check Friedels for noncentro structure
           Estimate of Friedel pairs measured      6368
           Fraction of Friedel pairs measured     0.814
           Are heavy atom types Z>Si present        yes

   0 ALERT level A = In general: serious problem
   1 ALERT level B = Potentially serious problem
  25 ALERT level C = Check and explain
   1 ALERT level G = General alerts; check

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
  24 ALERT type 2 Indicator that the structure model may be wrong or deficient
   1 ALERT type 3 Indicator that the structure quality may be low
   2 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: SMART (Bruker, 2002); cell refinement: SAINT (Bruker, 2002); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 (Farrugia, 1997); software used to prepare material for publication: SHELXL97.

(4-Aminobenzoato)tris(2-methyl-2-phenylpropyl)tin(IV) top

Crystal data top

[Sn(C₁₀H₁₃)₃(C₇H₆NO₂)]	F(000) = 2720
M_r = 654.43	D_x = 1.270 Mg m⁻³
Orthorhombic, P2₁2₁2₁	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: P 2ac 2ab	Cell parameters from 9977 reflections
a = 13.165 (1) Å	θ = 2.2–25.2°
b = 13.4984 (10) Å	µ = 0.78 mm⁻¹
c = 38.507 (3) Å	T = 295 K
V = 6842.9 (9) Å³	Block, colorless
Z = 8	0.38 × 0.35 × 0.30 mm

Data collection top

Bruker SMART APEX area-detector diffractometer	14187 independent reflections
Radiation source: fine-focus sealed tube	12378 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.032
φ and ω scans	θ_max = 26.5°, θ_min = 1.1°
Absorption correction: multi-scan (SADABS; Bruker, 2002)	h = −16→16
T_min = 0.757, T_max = 0.800	k = −16→16
55565 measured reflections	l = −48→48

Refinement top

Refinement on F²	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F² > 2σ(F²)] = 0.047	H-atom parameters constrained
wR(F²) = 0.105	w = 1/[σ²(F_o²) + (0.0374P)² + 4.2443P] where P = (F_o² + 2F_c²)/3
S = 1.16	(Δ/σ)_max = 0.001
14187 reflections	Δρ_max = 0.79 e Å⁻³
739 parameters	Δρ_min = −0.80 e Å⁻³
0 restraints	Absolute structure: Flack (1983), 6368 Friedel pairs
Primary atom site location: structure-invariant direct methods	Absolute structure parameter: 0.02 (2)

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Sn1	−0.03450 (3)	0.18043 (3)	0.118563 (8)	0.05751 (9)
O1	−0.1784 (2)	0.2143 (3)	0.10111 (8)	0.0682 (10)
O2	−0.1304 (3)	0.2062 (5)	0.04652 (10)	0.116 (2)
N1	−0.5997 (3)	0.3096 (5)	0.02870 (12)	0.0964 (16)
H1C	−0.6155	0.3119	0.0070	0.116*
H1D	−0.6451	0.3212	0.0442	0.116*
C1	−0.0249 (4)	0.0225 (4)	0.11045 (13)	0.0650 (13)
H1A	−0.0050	−0.0069	0.1324	0.078*
H1B	−0.0931	−0.0008	0.1055	0.078*
C2	0.0452 (4)	−0.0211 (4)	0.08239 (13)	0.0645 (13)
C3	−0.0015 (4)	−0.0011 (5)	0.04662 (14)	0.0856 (19)
H3A	−0.0699	−0.0258	0.0461	0.128*
H3B	0.0380	−0.0338	0.0291	0.128*
H3C	−0.0019	0.0690	0.0423	0.128*
C4	0.0464 (5)	−0.1346 (4)	0.08779 (18)	0.0904 (19)
H4A	−0.0216	−0.1598	0.0862	0.136*
H4B	0.0738	−0.1495	0.1103	0.136*
H4C	0.0877	−0.1649	0.0702	0.136*
C5	0.1532 (4)	0.0161 (4)	0.08485 (14)	0.0653 (13)
C6	0.1974 (4)	0.0290 (5)	0.11713 (18)	0.0812 (16)
H6	0.1597	0.0160	0.1370	0.097*
C7	0.2963 (6)	0.0607 (6)	0.1202 (2)	0.105 (2)
H7	0.3248	0.0694	0.1421	0.126*
C8	0.3526 (6)	0.0795 (7)	0.0913 (3)	0.115 (3)
H8	0.4200	0.0992	0.0934	0.137*
C9	0.3110 (6)	0.0695 (8)	0.0599 (3)	0.130 (3)
H9	0.3493	0.0828	0.0401	0.156*
C10	0.2097 (5)	0.0390 (7)	0.05670 (19)	0.106 (2)
H10	0.1808	0.0345	0.0347	0.127*
C11	0.0742 (5)	0.2700 (4)	0.09207 (15)	0.0742 (15)
H11A	0.1409	0.2430	0.0971	0.089*
H11B	0.0627	0.2617	0.0674	0.089*
C12	0.0785 (5)	0.3821 (4)	0.09939 (17)	0.0803 (17)
C13	−0.0228 (7)	0.4288 (6)	0.0880 (3)	0.128 (3)
H13A	−0.0351	0.4137	0.0640	0.193*
H13B	−0.0195	0.4993	0.0910	0.193*
H13C	−0.0770	0.4025	0.1019	0.193*
C14	0.1629 (7)	0.4295 (6)	0.0767 (2)	0.122 (3)
H14A	0.1485	0.4176	0.0526	0.182*
H14B	0.2273	0.4007	0.0826	0.182*
H14C	0.1651	0.4996	0.0809	0.182*
C15	0.1031 (5)	0.4027 (4)	0.13701 (18)	0.0817 (17)
C16	0.0421 (7)	0.4599 (5)	0.1585 (2)	0.113 (3)
H16	−0.0156	0.4893	0.1491	0.136*
C17	0.0631 (12)	0.4750 (7)	0.1927 (3)	0.156 (5)
H17	0.0193	0.5111	0.2068	0.187*
C18	0.1518 (14)	0.4346 (9)	0.2057 (3)	0.159 (7)
H18	0.1691	0.4469	0.2287	0.190*
C19	0.2140 (11)	0.3781 (9)	0.1864 (3)	0.154 (5)
H19	0.2721	0.3497	0.1958	0.185*
C20	0.1884 (6)	0.3639 (6)	0.1518 (2)	0.101 (2)
H20	0.2316	0.3259	0.1381	0.121*
C21	−0.0700 (4)	0.2260 (4)	0.17058 (12)	0.0648 (13)
H21A	−0.0170	0.2713	0.1780	0.078*
H21B	−0.1326	0.2638	0.1696	0.078*
C22	−0.0826 (5)	0.1473 (4)	0.19945 (12)	0.0657 (13)
C23	−0.1734 (5)	0.0817 (6)	0.19081 (18)	0.098 (2)
H23A	−0.2328	0.1222	0.1880	0.148*
H23B	−0.1843	0.0354	0.2093	0.148*
H23C	−0.1603	0.0464	0.1697	0.148*
C24	−0.1047 (6)	0.2034 (5)	0.23380 (14)	0.093 (2)
H24A	−0.1669	0.2400	0.2315	0.139*
H24B	−0.0500	0.2483	0.2386	0.139*
H24C	−0.1109	0.1567	0.2525	0.139*
C25	0.0161 (5)	0.0909 (4)	0.20420 (11)	0.0656 (14)
C26	0.0223 (7)	−0.0115 (5)	0.20748 (16)	0.091 (2)
H26	−0.0373	−0.0485	0.2065	0.109*
C27	0.1132 (9)	−0.0604 (6)	0.2121 (2)	0.111 (3)
H27	0.1133	−0.1290	0.2140	0.133*
C28	0.2021 (8)	−0.0108 (8)	0.21379 (19)	0.116 (3)
H28	0.2634	−0.0442	0.2165	0.139*
C29	0.1990 (7)	0.0913 (7)	0.2113 (2)	0.115 (3)
H29	0.2588	0.1277	0.2131	0.138*
C30	0.1093 (6)	0.1388 (5)	0.20644 (16)	0.0883 (19)
H30	0.1102	0.2075	0.2045	0.106*
C31	−0.1969 (4)	0.2200 (4)	0.06823 (13)	0.0689 (15)
C32	−0.3022 (4)	0.2438 (4)	0.05806 (12)	0.0573 (12)
C33	−0.3762 (4)	0.2594 (4)	0.08242 (12)	0.0606 (13)
H33	−0.3598	0.2544	0.1058	0.073*
C34	−0.4736 (4)	0.2820 (5)	0.07306 (13)	0.0776 (17)
H34	−0.5216	0.2938	0.0903	0.093*
C35	−0.5023 (4)	0.2877 (4)	0.03844 (13)	0.0675 (15)
C36	−0.4291 (4)	0.2691 (6)	0.01446 (13)	0.095 (2)
H36	−0.4460	0.2702	−0.0090	0.114*
C37	−0.3320 (5)	0.2491 (6)	0.02383 (14)	0.105 (3)
H37	−0.2838	0.2385	0.0065	0.126*
Sn1'	0.58820 (3)	0.81177 (2)	0.132280 (7)	0.05580 (9)
O1'	0.5565 (3)	0.9516 (2)	0.15099 (8)	0.0713 (10)
O2'	0.5469 (5)	0.9041 (3)	0.20527 (10)	0.116 (2)
N1'	0.4759 (6)	1.3696 (4)	0.22024 (14)	0.116 (2)
H1C'	0.4660	1.3846	0.2417	0.139*
H1D'	0.4755	1.4154	0.2047	0.139*
C1'	0.7491 (4)	0.8037 (4)	0.14042 (13)	0.0691 (14)
H1A'	0.7796	0.7839	0.1186	0.083*
H1B'	0.7727	0.8704	0.1452	0.083*
C2'	0.7936 (5)	0.7351 (4)	0.16913 (13)	0.0642 (14)
C3'	0.7646 (6)	0.7753 (4)	0.20478 (15)	0.090 (2)
H3D	0.7883	0.8423	0.2070	0.135*
H3E	0.7953	0.7351	0.2225	0.135*
H3F	0.6921	0.7738	0.2073	0.135*
C4'	0.9098 (5)	0.7361 (5)	0.16515 (18)	0.0918 (19)
H4D	0.9345	0.8024	0.1683	0.138*
H4E	0.9278	0.7130	0.1424	0.138*
H4F	0.9397	0.6936	0.1823	0.138*
C5'	0.7587 (4)	0.6285 (4)	0.16404 (14)	0.0609 (13)
C6'	0.7424 (5)	0.5884 (4)	0.13192 (17)	0.0782 (16)
H6'	0.7484	0.6286	0.1124	0.094*
C7'	0.7171 (5)	0.4899 (5)	0.1276 (2)	0.094 (2)
H7'	0.7070	0.4644	0.1054	0.113*
C8'	0.7071 (7)	0.4309 (6)	0.1555 (3)	0.121 (3)
H8'	0.6908	0.3643	0.1527	0.145*
C9'	0.7207 (9)	0.4686 (6)	0.1877 (3)	0.143 (4)
H9'	0.7125	0.4279	0.2070	0.171*
C10'	0.7467 (7)	0.5667 (5)	0.19225 (19)	0.104 (3)
H10'	0.7563	0.5915	0.2146	0.125*
C11'	0.4967 (4)	0.7038 (4)	0.15861 (14)	0.0694 (14)
H11C	0.5272	0.6394	0.1546	0.083*
H11D	0.5016	0.7169	0.1833	0.083*
C12'	0.3835 (4)	0.6957 (5)	0.14951 (15)	0.0758 (15)
C13'	0.3368 (6)	0.6134 (6)	0.1723 (2)	0.114 (3)
H13D	0.3693	0.5514	0.1672	0.171*
H13E	0.2654	0.6082	0.1674	0.171*
H13F	0.3465	0.6294	0.1963	0.171*
C14'	0.3326 (6)	0.7936 (6)	0.1581 (2)	0.118 (3)
H14D	0.3425	0.8085	0.1822	0.178*
H14E	0.2612	0.7890	0.1533	0.178*
H14F	0.3620	0.8452	0.1442	0.178*
C15'	0.3701 (4)	0.6649 (4)	0.11120 (15)	0.0697 (14)
C16'	0.4194 (6)	0.5848 (5)	0.09853 (18)	0.0903 (19)
H16'	0.4623	0.5484	0.1129	0.108*
C17'	0.4060 (8)	0.5570 (7)	0.0642 (3)	0.121 (3)
H17'	0.4384	0.5005	0.0560	0.146*
C18'	0.3479 (9)	0.6094 (10)	0.0426 (3)	0.143 (5)
H18'	0.3417	0.5901	0.0195	0.172*
C19'	0.2983 (7)	0.6898 (11)	0.0541 (2)	0.135 (4)
H19'	0.2570	0.7259	0.0392	0.162*
C20'	0.3094 (5)	0.7189 (6)	0.0887 (2)	0.103 (2)
H20'	0.2757	0.7750	0.0968	0.123*
C21'	0.5406 (4)	0.8486 (4)	0.08068 (12)	0.0648 (13)
H21C	0.4961	0.7961	0.0727	0.078*
H21D	0.4999	0.9083	0.0822	0.078*
C22'	0.6214 (4)	0.8655 (5)	0.05225 (13)	0.0686 (14)
C23'	0.6852 (5)	0.9560 (5)	0.06229 (18)	0.098 (2)
H23D	0.6413	1.0119	0.0658	0.146*
H23E	0.7325	0.9704	0.0440	0.146*
H23F	0.7216	0.9423	0.0833	0.146*
C24'	0.5642 (5)	0.8919 (6)	0.01800 (15)	0.101 (2)
H24D	0.5253	0.9513	0.0214	0.151*
H24E	0.5194	0.8386	0.0118	0.151*
H24F	0.6126	0.9021	−0.0003	0.151*
C25'	0.6821 (4)	0.7732 (5)	0.04630 (12)	0.0702 (16)
C26'	0.6341 (5)	0.6836 (6)	0.03994 (16)	0.097 (2)
H26'	0.5635	0.6813	0.0396	0.116*
C27'	0.6893 (9)	0.5964 (8)	0.0340 (2)	0.127 (3)
H27'	0.6552	0.5372	0.0299	0.152*
C28'	0.7917 (10)	0.5982 (10)	0.0341 (2)	0.141 (4)
H28'	0.8285	0.5406	0.0298	0.169*
C29'	0.8400 (7)	0.6841 (10)	0.04045 (19)	0.128 (3)
H29'	0.9106	0.6847	0.0410	0.153*
C30'	0.7887 (5)	0.7698 (7)	0.04604 (15)	0.090 (2)
H30'	0.8251	0.8278	0.0498	0.109*
C31'	0.5445 (5)	0.9693 (4)	0.18354 (13)	0.0647 (13)
C32'	0.5258 (4)	1.0747 (3)	0.19276 (12)	0.0558 (11)
C33'	0.5252 (5)	1.1472 (4)	0.16801 (13)	0.0697 (14)
H33'	0.5379	1.1310	0.1450	0.084*
C34'	0.5060 (6)	1.2442 (4)	0.17693 (14)	0.086 (2)
H34'	0.5024	1.2917	0.1595	0.103*
C35'	0.4921 (5)	1.2729 (4)	0.21085 (14)	0.0702 (16)
C36'	0.4926 (6)	1.2003 (4)	0.23536 (13)	0.087 (2)
H36'	0.4816	1.2166	0.2585	0.105*
C37'	0.5092 (6)	1.1039 (4)	0.22629 (13)	0.093 (2)
H37'	0.5091	1.0561	0.2437	0.112*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Sn1	0.05504 (17)	0.0731 (2)	0.04441 (15)	0.00272 (18)	−0.00284 (14)	0.00597 (16)
O1	0.0534 (19)	0.103 (3)	0.0477 (18)	0.0108 (18)	−0.0099 (15)	0.0081 (17)
O2	0.067 (2)	0.229 (6)	0.052 (2)	0.035 (3)	0.0016 (19)	−0.005 (3)
N1	0.056 (3)	0.166 (5)	0.067 (3)	0.014 (4)	−0.007 (2)	−0.016 (4)
C1	0.063 (3)	0.072 (3)	0.059 (3)	−0.003 (3)	0.002 (3)	−0.004 (2)
C2	0.056 (3)	0.081 (4)	0.057 (3)	0.006 (3)	−0.004 (2)	−0.012 (2)
C3	0.062 (3)	0.137 (6)	0.058 (3)	−0.009 (3)	−0.009 (3)	−0.014 (3)
C4	0.085 (4)	0.081 (4)	0.104 (5)	−0.008 (3)	−0.002 (4)	−0.024 (3)
C5	0.057 (3)	0.073 (3)	0.066 (3)	0.004 (3)	−0.001 (3)	−0.009 (3)
C6	0.065 (3)	0.094 (4)	0.085 (4)	−0.009 (3)	−0.014 (3)	0.005 (3)
C7	0.080 (5)	0.114 (5)	0.121 (6)	−0.006 (4)	−0.038 (5)	0.012 (5)
C8	0.065 (4)	0.125 (7)	0.153 (8)	−0.003 (4)	−0.008 (5)	−0.003 (6)
C9	0.085 (6)	0.172 (9)	0.134 (8)	−0.016 (6)	0.047 (6)	−0.018 (7)
C10	0.082 (5)	0.158 (7)	0.078 (4)	−0.019 (5)	0.011 (4)	−0.016 (5)
C11	0.069 (4)	0.094 (4)	0.060 (3)	0.001 (3)	0.013 (3)	0.006 (3)
C12	0.088 (4)	0.074 (4)	0.079 (4)	0.004 (3)	0.012 (4)	0.023 (3)
C13	0.124 (7)	0.101 (6)	0.161 (8)	0.015 (5)	−0.009 (6)	0.037 (5)
C14	0.145 (7)	0.127 (6)	0.093 (5)	−0.049 (6)	0.030 (5)	0.025 (5)
C15	0.086 (4)	0.063 (3)	0.095 (5)	−0.020 (3)	0.015 (4)	0.010 (3)
C16	0.147 (7)	0.073 (4)	0.120 (6)	−0.015 (5)	0.024 (6)	−0.006 (4)
C17	0.262 (17)	0.089 (7)	0.118 (9)	−0.041 (8)	0.044 (9)	−0.028 (6)
C18	0.29 (2)	0.103 (8)	0.087 (7)	−0.087 (11)	−0.033 (9)	0.006 (6)
C19	0.207 (13)	0.129 (8)	0.128 (9)	−0.085 (9)	−0.052 (9)	0.027 (7)
C20	0.103 (5)	0.101 (5)	0.098 (5)	−0.037 (4)	−0.011 (4)	0.010 (4)
C21	0.078 (4)	0.068 (3)	0.048 (3)	0.006 (3)	−0.002 (2)	0.003 (2)
C22	0.087 (4)	0.066 (3)	0.044 (2)	−0.008 (3)	0.003 (3)	0.000 (2)
C23	0.101 (5)	0.108 (5)	0.087 (5)	−0.034 (4)	0.026 (4)	−0.011 (4)
C24	0.141 (6)	0.087 (4)	0.050 (3)	0.008 (4)	0.016 (3)	−0.005 (3)
C25	0.101 (4)	0.063 (3)	0.033 (2)	−0.005 (3)	−0.008 (2)	−0.001 (2)
C26	0.136 (6)	0.069 (4)	0.067 (4)	−0.003 (4)	0.025 (4)	0.008 (3)
C27	0.166 (9)	0.077 (5)	0.089 (5)	0.039 (6)	0.020 (6)	0.016 (4)
C28	0.133 (8)	0.147 (8)	0.068 (4)	0.047 (7)	−0.026 (5)	−0.006 (5)
C29	0.120 (7)	0.120 (7)	0.104 (6)	0.019 (5)	−0.045 (5)	−0.030 (5)
C30	0.103 (5)	0.080 (4)	0.081 (4)	−0.002 (4)	−0.034 (4)	−0.014 (3)
C31	0.059 (3)	0.101 (4)	0.047 (3)	0.014 (3)	−0.004 (2)	0.008 (3)
C32	0.051 (3)	0.079 (3)	0.042 (2)	0.003 (2)	−0.003 (2)	0.004 (2)
C33	0.057 (3)	0.086 (3)	0.039 (2)	−0.010 (3)	−0.004 (2)	0.000 (2)
C34	0.055 (3)	0.129 (5)	0.048 (3)	0.001 (3)	0.005 (2)	−0.008 (3)
C35	0.055 (3)	0.100 (4)	0.048 (3)	−0.002 (3)	−0.003 (2)	−0.007 (3)
C36	0.070 (4)	0.178 (7)	0.038 (3)	0.032 (4)	−0.003 (2)	0.003 (3)
C37	0.072 (4)	0.201 (8)	0.042 (3)	0.040 (4)	0.007 (3)	0.012 (4)
Sn1'	0.0747 (2)	0.05122 (16)	0.04146 (15)	−0.00148 (18)	0.00253 (15)	−0.00411 (14)
O1'	0.105 (3)	0.0568 (19)	0.0519 (19)	0.0076 (19)	0.0134 (19)	−0.0108 (15)
O2'	0.233 (7)	0.060 (2)	0.054 (2)	0.018 (3)	0.009 (3)	0.0060 (18)
N1'	0.220 (8)	0.058 (3)	0.069 (3)	0.015 (4)	0.012 (4)	−0.008 (2)
C1'	0.090 (4)	0.062 (3)	0.056 (3)	−0.005 (3)	−0.001 (2)	−0.006 (3)
C2'	0.078 (4)	0.063 (3)	0.052 (3)	−0.008 (3)	−0.018 (3)	0.000 (2)
C3'	0.137 (6)	0.072 (4)	0.061 (3)	0.002 (4)	−0.021 (4)	−0.007 (3)
C4'	0.087 (4)	0.088 (4)	0.101 (5)	−0.014 (4)	−0.024 (4)	0.010 (3)
C5'	0.060 (3)	0.062 (3)	0.061 (3)	0.002 (2)	−0.014 (2)	−0.003 (2)
C6'	0.095 (4)	0.070 (3)	0.070 (3)	−0.003 (3)	0.006 (3)	−0.016 (3)
C7'	0.104 (5)	0.075 (4)	0.101 (5)	0.005 (4)	−0.006 (4)	−0.030 (4)
C8'	0.149 (8)	0.063 (4)	0.151 (8)	−0.004 (5)	−0.028 (7)	−0.008 (5)
C9'	0.237 (12)	0.070 (5)	0.121 (7)	−0.026 (6)	−0.038 (8)	0.023 (5)
C10'	0.168 (8)	0.066 (4)	0.079 (4)	−0.014 (4)	−0.031 (5)	0.007 (3)
C11'	0.086 (4)	0.063 (3)	0.059 (3)	−0.014 (3)	0.005 (2)	0.012 (2)
C12'	0.073 (3)	0.074 (3)	0.080 (4)	−0.004 (3)	0.018 (3)	0.006 (3)
C13'	0.113 (6)	0.131 (6)	0.098 (5)	−0.054 (5)	0.019 (5)	0.018 (5)
C14'	0.080 (4)	0.123 (6)	0.152 (7)	0.013 (5)	0.028 (5)	−0.037 (6)
C15'	0.065 (3)	0.067 (4)	0.077 (4)	−0.014 (3)	0.003 (3)	0.011 (3)
C16'	0.101 (5)	0.080 (4)	0.090 (5)	−0.017 (4)	0.006 (4)	−0.006 (3)
C17'	0.128 (7)	0.125 (7)	0.111 (6)	−0.030 (6)	0.013 (6)	−0.041 (5)
C18'	0.130 (9)	0.215 (14)	0.085 (6)	−0.076 (9)	−0.002 (6)	−0.021 (7)
C19'	0.099 (6)	0.219 (12)	0.086 (6)	−0.037 (8)	−0.022 (5)	0.043 (7)
C20'	0.073 (4)	0.133 (7)	0.103 (5)	−0.002 (4)	0.002 (4)	0.020 (5)
C21'	0.069 (3)	0.077 (3)	0.049 (3)	−0.007 (3)	−0.005 (2)	0.000 (2)
C22'	0.063 (3)	0.099 (4)	0.044 (3)	−0.010 (3)	−0.004 (2)	0.007 (3)
C23'	0.101 (5)	0.101 (5)	0.090 (5)	−0.032 (4)	−0.006 (4)	0.023 (4)
C24'	0.090 (5)	0.158 (7)	0.054 (3)	0.000 (4)	−0.004 (3)	0.022 (4)
C25'	0.063 (3)	0.119 (5)	0.028 (2)	−0.006 (3)	0.006 (2)	−0.010 (2)
C26'	0.089 (4)	0.122 (6)	0.079 (4)	0.000 (5)	−0.011 (3)	−0.031 (5)
C27'	0.157 (9)	0.139 (8)	0.084 (5)	0.024 (7)	−0.017 (6)	−0.049 (5)
C28'	0.166 (10)	0.182 (11)	0.074 (5)	0.063 (9)	−0.018 (6)	−0.055 (6)
C29'	0.104 (6)	0.204 (10)	0.076 (5)	0.032 (8)	0.021 (4)	−0.026 (7)
C30'	0.066 (4)	0.150 (7)	0.055 (3)	−0.008 (4)	0.008 (3)	−0.006 (4)
C31'	0.088 (4)	0.056 (3)	0.050 (3)	−0.001 (3)	0.002 (3)	−0.006 (2)
C32'	0.070 (3)	0.052 (3)	0.046 (2)	0.000 (2)	−0.003 (2)	0.000 (2)
C33'	0.103 (4)	0.065 (3)	0.041 (2)	−0.010 (3)	0.010 (3)	−0.003 (2)
C34'	0.153 (7)	0.053 (3)	0.051 (3)	−0.008 (3)	0.011 (3)	0.006 (2)
C35'	0.105 (5)	0.057 (3)	0.049 (3)	0.008 (3)	−0.003 (3)	−0.007 (2)
C36'	0.156 (6)	0.066 (3)	0.040 (2)	0.016 (4)	0.005 (3)	−0.006 (2)
C37'	0.179 (8)	0.062 (3)	0.038 (3)	0.012 (4)	0.005 (3)	0.005 (2)

Geometric parameters (Å, º) top

Sn1—O1	2.061 (3)	Sn1'—O1'	2.063 (3)
Sn1—C11	2.133 (6)	Sn1'—C21'	2.142 (5)
Sn1—C21	2.147 (5)	Sn1'—C1'	2.144 (6)
Sn1—C1	2.158 (5)	Sn1'—C11'	2.146 (5)
C31—O1	1.292 (6)	C31'—O1'	1.286 (6)
C31—O2	1.225 (6)	C31'—O2'	1.215 (6)
N1—C35	1.368 (7)	N1'—C35'	1.372 (7)
N1—H1C	0.8600	N1'—H1C'	0.8600
N1—H1D	0.8600	N1'—H1D'	0.8600
C1—C2	1.538 (7)	C1'—C2'	1.557 (7)
C1—H1A	0.9700	C1'—H1A'	0.9700
C1—H1B	0.9700	C1'—H1B'	0.9700
C2—C5	1.511 (8)	C2'—C5'	1.522 (7)
C2—C3	1.533 (7)	C2'—C3'	1.525 (8)
C2—C4	1.545 (8)	C2'—C4'	1.538 (9)
C3—H3A	0.9600	C3'—H3D	0.9600
C3—H3B	0.9600	C3'—H3E	0.9600
C3—H3C	0.9600	C3'—H3F	0.9600
C4—H4A	0.9600	C4'—H4D	0.9600
C4—H4B	0.9600	C4'—H4E	0.9600
C4—H4C	0.9600	C4'—H4F	0.9600
C5—C10	1.350 (9)	C5'—C6'	1.367 (8)
C5—C6	1.384 (8)	C5'—C10'	1.379 (8)
C6—C7	1.375 (9)	C6'—C7'	1.380 (8)
C6—H6	0.9300	C6'—H6'	0.9300
C7—C8	1.361 (11)	C7'—C8'	1.346 (11)
C7—H7	0.9300	C7'—H7'	0.9300
C8—C9	1.333 (12)	C8'—C9'	1.353 (12)
C8—H8	0.9300	C8'—H8'	0.9300
C9—C10	1.401 (11)	C9'—C10'	1.380 (10)
C9—H9	0.9300	C9'—H9'	0.9300
C10—H10	0.9300	C10'—H10'	0.9300
C11—C12	1.540 (8)	C11'—C12'	1.535 (8)
C11—H11A	0.9700	C11'—H11C	0.9700
C11—H11B	0.9700	C11'—H11D	0.9700
C12—C15	1.510 (9)	C12'—C14'	1.518 (9)
C12—C13	1.539 (10)	C12'—C13'	1.542 (8)
C12—C14	1.552 (9)	C12'—C15'	1.543 (8)
C13—H13A	0.9600	C13'—H13D	0.9600
C13—H13B	0.9600	C13'—H13E	0.9600
C13—H13C	0.9600	C13'—H13F	0.9600
C14—H14A	0.9600	C14'—H14D	0.9600
C14—H14B	0.9600	C14'—H14E	0.9600
C14—H14C	0.9600	C14'—H14F	0.9600
C15—C20	1.365 (10)	C15'—C16'	1.352 (9)
C15—C16	1.388 (10)	C15'—C20'	1.385 (9)
C16—C17	1.361 (13)	C16'—C17'	1.387 (11)
C16—H16	0.9300	C16'—H16'	0.9300
C17—C18	1.383 (17)	C17'—C18'	1.331 (14)
C17—H17	0.9300	C17'—H17'	0.9300
C18—C19	1.342 (17)	C18'—C19'	1.342 (15)
C18—H18	0.9300	C18'—H18'	0.9300
C19—C20	1.385 (12)	C19'—C20'	1.397 (12)
C19—H19	0.9300	C19'—H19'	0.9300
C20—H20	0.9300	C20'—H20'	0.9300
C21—C22	1.547 (7)	C21'—C22'	1.543 (7)
C21—H21A	0.9700	C21'—H21C	0.9700
C21—H21B	0.9700	C21'—H21D	0.9700
C22—C25	1.516 (8)	C22'—C25'	1.498 (8)
C22—C23	1.524 (8)	C22'—C23'	1.532 (8)
C22—C24	1.552 (7)	C22'—C24'	1.560 (7)
C23—H23A	0.9600	C23'—H23D	0.9600
C23—H23B	0.9600	C23'—H23E	0.9600
C23—H23C	0.9600	C23'—H23F	0.9600
C24—H24A	0.9600	C24'—H24D	0.9600
C24—H24B	0.9600	C24'—H24E	0.9600
C24—H24C	0.9600	C24'—H24F	0.9600
C25—C30	1.390 (9)	C25'—C26'	1.386 (9)
C25—C26	1.391 (8)	C25'—C30'	1.404 (9)
C26—C27	1.379 (11)	C26'—C27'	1.403 (12)
C26—H26	0.9300	C26'—H26'	0.9300
C27—C28	1.350 (12)	C27'—C28'	1.348 (13)
C27—H27	0.9300	C27'—H27'	0.9300
C28—C29	1.383 (11)	C28'—C29'	1.344 (15)
C28—H28	0.9300	C28'—H28'	0.9300
C29—C30	1.358 (10)	C29'—C30'	1.357 (12)
C29—H29	0.9300	C29'—H29'	0.9300
C30—H30	0.9300	C30'—H30'	0.9300
C31—C32	1.476 (7)	C31'—C32'	1.486 (7)
C32—C33	1.368 (7)	C32'—C33'	1.366 (7)
C32—C37	1.377 (7)	C32'—C37'	1.368 (7)
C33—C34	1.366 (7)	C33'—C34'	1.376 (7)
C33—H33	0.9300	C33'—H33'	0.9300
C34—C35	1.388 (7)	C34'—C35'	1.375 (7)
C34—H34	0.9300	C34'—H34'	0.9300
C35—C36	1.358 (7)	C35'—C36'	1.361 (7)
C36—C37	1.356 (8)	C36'—C37'	1.365 (8)
C36—H36	0.9300	C36'—H36'	0.9300
C37—H37	0.9300	C37'—H37'	0.9300

O1—Sn1—C11	109.6 (2)	O1'—Sn1'—C21'	93.01 (18)
O1—Sn1—C21	92.33 (18)	O1'—Sn1'—C1'	101.26 (18)
C11—Sn1—C21	115.4 (2)	C21'—Sn1'—C1'	115.9 (2)
O1—Sn1—C1	103.05 (18)	O1'—Sn1'—C11'	110.06 (19)
C11—Sn1—C1	116.8 (2)	C21'—Sn1'—C11'	115.6 (2)
C21—Sn1—C1	115.53 (19)	C1'—Sn1'—C11'	116.8 (2)
C31—O1—Sn1	120.4 (3)	C31'—O1'—Sn1'	122.4 (3)
C35—N1—H1C	120.0	C35'—N1'—H1C'	120.0
C35—N1—H1D	120.0	C35'—N1'—H1D'	120.0
H1C—N1—H1D	120.0	H1C'—N1'—H1D'	120.0
C2—C1—Sn1	121.0 (4)	C2'—C1'—Sn1'	120.4 (4)
C2—C1—H1A	107.1	C2'—C1'—H1A'	107.2
Sn1—C1—H1A	107.1	Sn1'—C1'—H1A'	107.2
C2—C1—H1B	107.1	C2'—C1'—H1B'	107.2
Sn1—C1—H1B	107.1	Sn1'—C1'—H1B'	107.2
H1A—C1—H1B	106.8	H1A'—C1'—H1B'	106.9
C5—C2—C3	112.0 (5)	C5'—C2'—C3'	112.1 (5)
C5—C2—C1	113.1 (4)	C5'—C2'—C4'	107.2 (5)
C3—C2—C1	108.8 (5)	C3'—C2'—C4'	109.6 (5)
C5—C2—C4	108.2 (5)	C5'—C2'—C1'	110.9 (4)
C3—C2—C4	107.5 (5)	C3'—C2'—C1'	109.5 (5)
C1—C2—C4	106.9 (5)	C4'—C2'—C1'	107.3 (5)
C2—C3—H3A	109.5	C2'—C3'—H3D	109.5
C2—C3—H3B	109.5	C2'—C3'—H3E	109.5
H3A—C3—H3B	109.5	H3D—C3'—H3E	109.5
C2—C3—H3C	109.5	C2'—C3'—H3F	109.5
H3A—C3—H3C	109.5	H3D—C3'—H3F	109.5
H3B—C3—H3C	109.5	H3E—C3'—H3F	109.5
C2—C4—H4A	109.5	C2'—C4'—H4D	109.5
C2—C4—H4B	109.5	C2'—C4'—H4E	109.5
H4A—C4—H4B	109.5	H4D—C4'—H4E	109.5
C2—C4—H4C	109.5	C2'—C4'—H4F	109.5
H4A—C4—H4C	109.5	H4D—C4'—H4F	109.5
H4B—C4—H4C	109.5	H4E—C4'—H4F	109.5
C10—C5—C6	117.4 (6)	C6'—C5'—C10'	117.1 (5)
C10—C5—C2	123.0 (5)	C6'—C5'—C2'	122.6 (5)
C6—C5—C2	119.6 (5)	C10'—C5'—C2'	120.3 (5)
C7—C6—C5	121.0 (7)	C5'—C6'—C7'	122.0 (7)
C7—C6—H6	119.5	C5'—C6'—H6'	119.0
C5—C6—H6	119.5	C7'—C6'—H6'	119.0
C8—C7—C6	120.2 (8)	C8'—C7'—C6'	119.8 (7)
C8—C7—H7	119.9	C8'—C7'—H7'	120.1
C6—C7—H7	119.9	C6'—C7'—H7'	120.1
C9—C8—C7	119.9 (8)	C7'—C8'—C9'	119.9 (7)
C9—C8—H8	120.0	C7'—C8'—H8'	120.1
C7—C8—H8	120.0	C9'—C8'—H8'	120.1
C8—C9—C10	120.0 (8)	C8'—C9'—C10'	120.6 (8)
C8—C9—H9	120.0	C8'—C9'—H9'	119.7
C10—C9—H9	120.0	C10'—C9'—H9'	119.7
C5—C10—C9	121.4 (7)	C5'—C10'—C9'	120.7 (7)
C5—C10—H10	119.3	C5'—C10'—H10'	119.7
C9—C10—H10	119.3	C9'—C10'—H10'	119.7
C12—C11—Sn1	119.6 (4)	C12'—C11'—Sn1'	119.0 (4)
C12—C11—H11A	107.4	C12'—C11'—H11C	107.6
Sn1—C11—H11A	107.4	Sn1'—C11'—H11C	107.6
C12—C11—H11B	107.4	C12'—C11'—H11D	107.6
Sn1—C11—H11B	107.4	Sn1'—C11'—H11D	107.6
H11A—C11—H11B	106.9	H11C—C11'—H11D	107.0
C15—C12—C13	112.5 (6)	C14'—C12'—C11'	108.5 (5)
C15—C12—C11	111.4 (5)	C14'—C12'—C13'	109.1 (6)
C13—C12—C11	108.6 (6)	C11'—C12'—C13'	108.0 (5)
C15—C12—C14	108.1 (6)	C14'—C12'—C15'	113.1 (6)
C13—C12—C14	107.0 (6)	C11'—C12'—C15'	110.4 (4)
C11—C12—C14	109.2 (6)	C13'—C12'—C15'	107.7 (5)
C12—C13—H13A	109.5	C12'—C13'—H13D	109.5
C12—C13—H13B	109.5	C12'—C13'—H13E	109.5
H13A—C13—H13B	109.5	H13D—C13'—H13E	109.5
C12—C13—H13C	109.5	C12'—C13'—H13F	109.5
H13A—C13—H13C	109.5	H13D—C13'—H13F	109.5
H13B—C13—H13C	109.5	H13E—C13'—H13F	109.5
C12—C14—H14A	109.5	C12'—C14'—H14D	109.5
C12—C14—H14B	109.5	C12'—C14'—H14E	109.5
H14A—C14—H14B	109.5	H14D—C14'—H14E	109.5
C12—C14—H14C	109.5	C12'—C14'—H14F	109.5
H14A—C14—H14C	109.5	H14D—C14'—H14F	109.5
H14B—C14—H14C	109.5	H14E—C14'—H14F	109.5
C20—C15—C16	116.2 (8)	C16'—C15'—C20'	118.2 (7)
C20—C15—C12	120.5 (7)	C16'—C15'—C12'	120.4 (6)
C16—C15—C12	123.4 (7)	C20'—C15'—C12'	121.4 (6)
C17—C16—C15	122.9 (10)	C15'—C16'—C17'	120.0 (8)
C17—C16—H16	118.6	C15'—C16'—H16'	120.0
C15—C16—H16	118.6	C17'—C16'—H16'	120.0
C16—C17—C18	117.5 (12)	C18'—C17'—C16'	121.6 (10)
C16—C17—H17	121.2	C18'—C17'—H17'	119.2
C18—C17—H17	121.2	C16'—C17'—H17'	119.2
C19—C18—C17	122.6 (12)	C17'—C18'—C19'	120.3 (10)
C19—C18—H18	118.7	C17'—C18'—H18'	119.9
C17—C18—H18	118.7	C19'—C18'—H18'	119.9
C18—C19—C20	117.6 (13)	C18'—C19'—C20'	119.4 (10)
C18—C19—H19	121.2	C18'—C19'—H19'	120.3
C20—C19—H19	121.2	C20'—C19'—H19'	120.3
C15—C20—C19	123.2 (10)	C15'—C20'—C19'	120.5 (9)
C15—C20—H20	118.4	C15'—C20'—H20'	119.7
C19—C20—H20	118.4	C19'—C20'—H20'	119.7
C22—C21—Sn1	119.8 (3)	C22'—C21'—Sn1'	119.4 (4)
C22—C21—H21A	107.4	C22'—C21'—H21C	107.5
Sn1—C21—H21A	107.4	Sn1'—C21'—H21C	107.5
C22—C21—H21B	107.4	C22'—C21'—H21D	107.5
Sn1—C21—H21B	107.4	Sn1'—C21'—H21D	107.5
H21A—C21—H21B	106.9	H21C—C21'—H21D	107.0
C25—C22—C23	114.0 (5)	C25'—C22'—C23'	114.2 (5)
C25—C22—C21	109.9 (4)	C25'—C22'—C21'	110.7 (5)
C23—C22—C21	109.0 (5)	C23'—C22'—C21'	108.4 (5)
C25—C22—C24	107.6 (5)	C25'—C22'—C24'	108.6 (5)
C23—C22—C24	108.8 (5)	C23'—C22'—C24'	107.2 (5)
C21—C22—C24	107.3 (4)	C21'—C22'—C24'	107.5 (5)
C22—C23—H23A	109.5	C22'—C23'—H23D	109.5
C22—C23—H23B	109.5	C22'—C23'—H23E	109.5
H23A—C23—H23B	109.5	H23D—C23'—H23E	109.5
C22—C23—H23C	109.5	C22'—C23'—H23F	109.5
H23A—C23—H23C	109.5	H23D—C23'—H23F	109.5
H23B—C23—H23C	109.5	H23E—C23'—H23F	109.5
C22—C24—H24A	109.5	C22'—C24'—H24D	109.5
C22—C24—H24B	109.5	C22'—C24'—H24E	109.5
H24A—C24—H24B	109.5	H24D—C24'—H24E	109.5
C22—C24—H24C	109.5	C22'—C24'—H24F	109.5
H24A—C24—H24C	109.5	H24D—C24'—H24F	109.5
H24B—C24—H24C	109.5	H24E—C24'—H24F	109.5
C30—C25—C26	113.9 (7)	C26'—C25'—C30'	115.2 (7)
C30—C25—C22	122.0 (5)	C26'—C25'—C22'	120.6 (5)
C26—C25—C22	124.1 (6)	C30'—C25'—C22'	124.2 (6)
C27—C26—C25	122.6 (8)	C25'—C26'—C27'	121.6 (7)
C27—C26—H26	118.7	C25'—C26'—H26'	119.2
C25—C26—H26	118.7	C27'—C26'—H26'	119.2
C28—C27—C26	121.5 (8)	C28'—C27'—C26'	120.2 (10)
C28—C27—H27	119.2	C28'—C27'—H27'	119.9
C26—C27—H27	119.2	C26'—C27'—H27'	119.9
C27—C28—C29	117.7 (9)	C29'—C28'—C27'	119.2 (10)
C27—C28—H28	121.1	C29'—C28'—H28'	120.4
C29—C28—H28	121.1	C27'—C28'—H28'	120.4
C30—C29—C28	120.4 (9)	C28'—C29'—C30'	122.0 (9)
C30—C29—H29	119.8	C28'—C29'—H29'	119.0
C28—C29—H29	119.8	C30'—C29'—H29'	119.0
C29—C30—C25	123.9 (7)	C29'—C30'—C25'	121.7 (8)
C29—C30—H30	118.1	C29'—C30'—H30'	119.1
C25—C30—H30	118.1	C25'—C30'—H30'	119.1
O2—C31—O1	121.7 (5)	O2'—C31'—O1'	122.2 (5)
O2—C31—C32	121.6 (5)	O2'—C31'—C32'	122.2 (4)
O1—C31—C32	116.8 (4)	O1'—C31'—C32'	115.5 (4)
C33—C32—C37	116.5 (5)	C33'—C32'—C37'	116.8 (5)
C33—C32—C31	121.3 (4)	C33'—C32'—C31'	121.3 (4)
C37—C32—C31	122.2 (5)	C37'—C32'—C31'	121.9 (4)
C34—C33—C32	121.4 (5)	C32'—C33'—C34'	120.6 (5)
C34—C33—H33	119.3	C32'—C33'—H33'	119.7
C32—C33—H33	119.3	C34'—C33'—H33'	119.7
C33—C34—C35	121.4 (5)	C35'—C34'—C33'	122.0 (5)
C33—C34—H34	119.3	C35'—C34'—H34'	119.0
C35—C34—H34	119.3	C33'—C34'—H34'	119.0
C36—C35—N1	121.2 (5)	C36'—C35'—N1'	120.2 (5)
C36—C35—C34	116.7 (5)	C36'—C35'—C34'	117.1 (5)
N1—C35—C34	122.0 (5)	N1'—C35'—C34'	122.7 (5)
C37—C36—C35	121.7 (5)	C35'—C36'—C37'	120.7 (5)
C37—C36—H36	119.2	C35'—C36'—H36'	119.7
C35—C36—H36	119.2	C37'—C36'—H36'	119.7
C36—C37—C32	122.2 (5)	C36'—C37'—C32'	122.8 (5)
C36—C37—H37	118.9	C36'—C37'—H37'	118.6
C32—C37—H37	118.9	C32'—C37'—H37'	118.6

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
N1—H1C···O2ⁱ	0.86	2.09	2.932 (6)	168
N1′—H1C′···O2′ⁱⁱ	0.86	2.07	2.921 (7)	173

Symmetry codes: (i) x−1/2, −y+1/2, −z; (ii) −x+1, y+1/2, −z+1/2.

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(4-Amino­benzoato)tris­(2-methyl-2-phenyl­propyl)tin(IV)

Supporting information

Key indicators

checkCIF/PLATON results

(4-Aminobenzoato)tris(2-methyl-2-phenylpropyl)tin(IV)