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Acta Cryst. (2006). E62, m1567-m1568  [ doi:10.1107/S1600536806019337 ]

Bis{N-(2-hydroxybenzoyl)-N'-[1-(2-pyridyl)ethylidene}hydrazinato]copper(II)

D.-B. Dang, Y. Bai and C.-Y. Duan

Abstract: The title complex, [Cu(C14H12N3O2)2], consists of two deprotonated 2-acetylpyridine salicylhydrazone ligands coordinated to the copper as N,N,O-tridentate ligands, forming a neutral complex. The Cu atom lies on a twofold rotation axis. The structure is stabilized by intramolecular O-H...N hydrogen bonding, and [pi]-[pi] stacking interactions between the pyridyl and benzene rings lead to a two-dimensional network in the crystal structure.

Online 16 June 2006


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