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Acta Cryst. (2006). E62, m1586-m1588  [ doi:10.1107/S1600536806022690 ]

Poly[[mu]-aqua-aqua([mu]4-2-oxidobenzene-1,3-dicarboxylato)([mu]2-2-oxidobenzene-1,3-dicarboxylato)cadmium(II)dicopper(II)]

E Yang, F.-F. Yang and S.-Y. Chen

Abstract: In the molecule of the title compound, [CdCu2(C8H3O5)2(H2O)2]n, each 2-oxidobenzene-1,3-dicarboxylate trianion is bonded to two Cu atoms through O atoms of the carboxylates and the deprononated hydroxy group in chelating mode, forming [Cu2(C8H3O5)2]2- units. A pair of [Cu2(C8H3O5)2]2- units is then coordinated to each Cd atom, forming an infinite chain. The crystal structure is stabilized by intermolecular O-H...O hydrogen bonds.

Online 21 June 2006


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