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Acta Cryst. (2006). E62, m1680-m1682  [ doi:10.1107/S1600536806024019 ]

The tetralithium derivative of the tetrakis(1-naphthylimido)silicate tetraanion

M. C. Copsey, M. S. Balakrishna and T. Chivers

Abstract: The title compound, bis(diethyl ether-[kappa]O)tetra(tetrahydrofuran-[kappa]O)[[mu]4-tetrakis(1-naphthylimido)silane(4-)]tetralithium(I) diethyl ether solvate, [Li4(C40H28N4Si)(C4H8O)4(C4H10O)2]·C4H10O, has been structurally characterized. The compound contains the tetrakis(naphthylimido)silicate tetraanion, which is formally isoelectronic with the orthosilicate anion, [SiO4]4-. The two halves of the molecule are equivalent, related by a crystallographic twofold rotation axis.

Online 28 June 2006


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