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Acta Cryst. (2006). E62, m1501-m1503  [ doi:10.1107/S1600536806021015 ]

trans-Dichlorobis[2-(o-tolyliminomethyl)phenolato-[kappa]O]nickel(II)

X.-H. Liu and J.-H. Zeng

Abstract: In the title compound, [NiCl2(C14H13NO)2], the NiII atom is four-coordinated by two phenolate O atoms from two 2-(o-tolyliminomethyl)phenol ligands and two Cl anions, giving an approximately tetrahedral geometry. The Ni atom lies on a crystallographic twofold rotation axis. A strong intramolecular N-H...O hydrogen bond forms an S(6) ring.

Online 14 June 2006


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