Acta Cryst. (2006). E62, m1498-m1500  [ doi:10.1107/S1600536806017302 ]

{2-[2-(Ethylamino)ethyliminomethyl]phenol}{2-[2-(ethylamino)ethyliminomethyl]phenolato}nickel(II) perchlorate

Z.-L. You and J.-Y. Chi

Abstract: In the title structure, [Ni(C₁₁H₁₅N₂O)(C₁₁H₁₆N₂O)]ClO₄, there are two independent ion pairs in the asymmetric unit. In each cation, the Ni^II atom is six-coordinated in a slightly distorted octahedral geometry by two phenolate O atoms, two imine N atoms and two amine N atoms from two Schiff base ligands, in one of which the phenolate O atom is protonated. In the crystal structure, anions and cations are linked through intermolecular O-HO, N-HO and weak C-HO hydrogen bonds, forming one-dimensional chains containing hydrogen-bonded cation dimers.

Online 9 June 2006

Copyright © International Union of Crystallography
IUCr Webmaster