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Acta Cryst. (2006). E62, m1524-m1526  [ doi:10.1107/S1600536806020460 ]

(2,4,6-Trimethyldithiobenzoato-[kappa]2S,S')bis(triphenylphosphine-[kappa]P)gold(I)

D. Davis, F. R. Fronczek, J. A. Schuerman, J. Selbin and S. F. Watkins

Abstract: The asymmetric unit of the title compound, [Au(C10H8S2)(C18H15P)2], consists of two independent molecules. The Au coordination environment can be described as a highly distorted tetrahedral arrangement (S2AuP2), but is more accurately described as a flattened trigonal pyramid defined by three normal covalent bonds (SAuP2), with a second S atom more distantly bonded to the Au atom.

Online 14 June 2006


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