Poly[tris­(ethyl­ene-1,2-diammonium) bis­[aqua­(μ-sulfato-κ3O,O′:O′′)(μ-sulfato-κ4O,O′:O′′,O′′′)(sulfato-κO)terbate(III)] tetra­hydrate]

Xu, Z.-W.; Yang, J.-Y.; Fu, Y.-L.; Ng, S.W.

doi:10.1107/S1600536806027322

Poly[tris(ethylene-1,2-diammonium) bis[aqua(μ-sulfato-κ³O,O′:O′′)(μ-sulfato-κ⁴O,O′:O′′,O′′′)(sulfato-κO)terbate(III)] tetrahydrate]

Z.-W. Xu, J.-Y. Yang, Y.-L. Fu and S. W. Ng

The Tb atom in the title compound, {(C₂H₁₀N₂)₃[Tb(SO₄)₃(H₂O)]₂·4H₂O}_n, exists in a nine-coordinate geometry; the anion is linked through sulfate bridges into a three-dimensional network. The counter-ions and water molecules occupy the spaces within the framework and they consolidate the network structure through extensive hydrogen bonds.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806027322/bt2147sup1.cif Contains datablocks global, I
	Structure factor file (CIF format) https://doi.org/10.1107/S1600536806027322/bt2147Isup2.hkl Contains datablock I

CCDC reference: 604762

checkCIF report

Key indicators

Single-crystal X-ray study
T = 291 K
Mean (C-C) = 0.009 Å
R factor = 0.040
wR factor = 0.081
Data-to-parameter ratio = 16.4

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings    Differ ....          ?
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT045_ALERT_1_C Calculated and Reported Z Differ by ............       2.00 Ratio
PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ...          9
PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........         15

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   5 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   3 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   0 ALERT type 2 Indicator that the structure model may be wrong or deficient
   1 ALERT type 3 Indicator that the structure quality may be low
   1 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

Computing details top

Data collection: SMART (Bruker, 2003); cell refinement: SAINT (Bruker, 2003); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97.

Poly[[tris(ethylene-1,2-diammonium) bis[aqua(µ-sulfato-κ³O,O':O'')(µ-sulfato-κ⁴O,O':O'',O''')(sulfato- κO)terbate(III)] tetrahydrate] top

Crystal data top

(C₂H₁₀N₂)₃[Tb(SO₄)₃(H₂O)]₂·4H₂O	F(000) = 1172
M_r = 1188.66	D_x = 2.390 Mg m⁻³
Monoclinic, P2₁/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 3109 reflections
a = 6.5024 (4) Å	θ = 2.3–27.6°
b = 26.392 (2) Å	µ = 4.75 mm⁻¹
c = 9.9070 (7) Å	T = 291 K
β = 103.733 (1)°	Rod, colourless
V = 1651.5 (2) Å³	0.14 × 0.06 × 0.03 mm
Z = 2

Data collection top

Bruker SMART APEX area-detector diffractometer	3763 independent reflections
Radiation source: fine-focus sealed tube	3244 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.050
φ and ω scans	θ_max = 27.5°, θ_min = 1.5°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −8→8
T_min = 0.556, T_max = 0.871	k = −33→34
13711 measured reflections	l = −12→12

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.040	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.081	H-atom parameters constrained
S = 1.11	w = 1/[σ²(F_o²) + (0.0304P)² + 2.0826P] where P = (F_o² + 2F_c²)/3
3763 reflections	(Δ/σ)_max = 0.001
229 parameters	Δρ_max = 1.19 e Å⁻³
0 restraints	Δρ_min = −1.53 e Å⁻³

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Tb1	0.45388 (4)	0.321085 (9)	0.54092 (3)	0.01081 (8)
S1	0.5892 (2)	0.43377 (5)	0.7526 (1)	0.0164 (3)
S2	−0.0287 (2)	0.34150 (5)	0.4645 (1)	0.0143 (3)
S3	0.4712 (2)	0.25038 (5)	0.2928 (1)	0.0130 (3)
O1	0.5738 (6)	0.37868 (14)	0.7173 (4)	0.022 (1)
O2	0.4272 (6)	0.44660 (15)	0.8256 (5)	0.028 (1)
O3	0.5622 (7)	0.46343 (15)	0.6231 (4)	0.025 (1)
O4	0.8014 (6)	0.44414 (16)	0.8401 (4)	0.026 (1)
O5	0.0884 (6)	0.29866 (15)	0.4206 (4)	0.021 (1)
O6	0.1358 (6)	0.37160 (15)	0.5603 (4)	0.022 (1)
O7	−0.1825 (6)	0.32203 (14)	0.5397 (4)	0.019 (1)
O8	−0.1350 (6)	0.37155 (16)	0.3449 (5)	0.030 (1)
O9	0.4417 (6)	0.30557 (14)	0.2872 (4)	0.019 (1)
O10	0.5009 (6)	0.23655 (14)	0.4409 (4)	0.017 (1)
O11	0.6507 (6)	0.23435 (14)	0.2365 (4)	0.017 (1)
O12	0.2848 (6)	0.22422 (14)	0.2054 (4)	0.018 (1)
O1w	0.4656 (7)	0.39827 (15)	0.4179 (4)	0.025 (1)
O2w	0.2285 (8)	0.53190 (18)	0.8914 (5)	0.038 (1)
O3w	0.4718 (10)	0.3888 (3)	1.1036 (8)	0.091 (3)
N1	0.1301 (8)	0.37330 (19)	0.8606 (5)	0.026 (1)
N2	−0.0785 (8)	0.29352 (19)	1.1104 (5)	0.027 (1)
N3	−0.0860 (8)	0.52929 (19)	0.6494 (5)	0.027 (1)
C1	0.0537 (10)	0.3277 (2)	0.9195 (7)	0.026 (1)
C2	−0.0138 (11)	0.3404 (2)	1.0496 (7)	0.031 (2)
C3	0.0513 (10)	0.5018 (3)	0.5757 (6)	0.032 (2)
H1w1	0.4784	0.4224	0.4760	0.030*
H1w2	0.5339	0.4051	0.3570	0.030*
H2w1	0.2876	0.5032	0.8892	0.046*
H2w2	0.2259	0.5390	0.9746	0.046*
H3w1	0.5575	0.4133	1.1265	0.110*
H3w2	0.5275	0.3614	1.1394	0.110*
H1n1	0.0372	0.3965	0.8515	0.040*
H1n2	0.1526	0.3662	0.7816	0.040*
H1n3	0.2444	0.3834	0.9147	0.040*
H2n1	−0.1976	0.2837	1.0617	0.041*
H2n2	−0.0888	0.2994	1.1930	0.041*
H2n3	0.0136	0.2706	1.1116	0.041*
H3n1	−0.1190	0.5579	0.6109	0.040*
H3n2	−0.0206	0.5337	0.7337	0.040*
H3n3	−0.1978	0.5122	0.6462	0.040*
H1a	0.1656	0.3025	0.9398	0.032*
H1b	−0.0650	0.3133	0.8520	0.032*
H2a	0.1024	0.3563	1.1157	0.037*
H2b	−0.1313	0.3640	1.0288	0.037*
H3a	0.0789	0.4680	0.6143	0.038*
H3b	0.1857	0.5193	0.5884	0.038*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Tb1	0.0095 (1)	0.0113 (1)	0.0120 (1)	0.0000 (1)	0.0036 (1)	−0.0004 (1)
S1	0.0176 (7)	0.0146 (7)	0.0163 (7)	−0.0019 (5)	0.0028 (5)	−0.0023 (5)
S2	0.0102 (6)	0.0158 (6)	0.0173 (7)	−0.0003 (5)	0.0041 (5)	0.0031 (5)
S3	0.0129 (6)	0.0142 (6)	0.0125 (6)	−0.0007 (5)	0.0041 (5)	−0.0021 (5)
O1	0.030 (2)	0.013 (2)	0.020 (2)	0.002 (2)	−0.002 (2)	0.000 (2)
O2	0.027 (2)	0.026 (2)	0.034 (3)	0.004 (2)	0.013 (2)	−0.005 (2)
O3	0.034 (2)	0.019 (2)	0.021 (2)	−0.003 (2)	0.005 (2)	0.002 (2)
O4	0.020 (2)	0.029 (2)	0.025 (2)	−0.005 (2)	−0.001 (2)	−0.009 (2)
O5	0.015 (2)	0.024 (2)	0.023 (2)	0.001 (2)	0.006 (2)	−0.007 (2)
O6	0.018 (2)	0.020 (2)	0.027 (2)	−0.001 (2)	0.006 (2)	−0.003 (2)
O7	0.011 (2)	0.026 (2)	0.022 (2)	0.000 (2)	0.008 (2)	0.004 (2)
O8	0.019 (2)	0.035 (3)	0.034 (3)	0.002 (2)	0.003 (2)	0.018 (2)
O9	0.024 (2)	0.0162 (19)	0.018 (2)	0.001 (2)	0.010 (2)	−0.001 (2)
O10	0.018 (2)	0.020 (2)	0.012 (2)	−0.001 (2)	0.003 (2)	0.001 (2)
O11	0.016 (2)	0.018 (2)	0.018 (2)	0.001 (2)	0.007 (2)	−0.0032 (16)
O12	0.017 (2)	0.024 (2)	0.014 (2)	−0.002 (2)	0.004 (2)	−0.0055 (16)
O1w	0.044 (3)	0.015 (2)	0.020 (2)	−0.001 (2)	0.015 (2)	0.0005 (17)
O2w	0.048 (3)	0.035 (3)	0.027 (3)	0.006 (2)	−0.003 (2)	−0.012 (2)
O3w	0.063 (4)	0.099 (6)	0.095 (5)	−0.034 (4)	−0.018 (4)	0.060 (5)
N1	0.027 (3)	0.031 (3)	0.026 (3)	−0.001 (2)	0.015 (2)	0.003 (2)
N2	0.030 (3)	0.031 (3)	0.023 (3)	−0.011 (2)	0.008 (2)	0.004 (2)
N3	0.025 (3)	0.024 (3)	0.030 (3)	−0.002 (2)	0.006 (2)	0.001 (2)
C1	0.026 (3)	0.024 (3)	0.034 (4)	−0.003 (3)	0.018 (3)	−0.001 (3)
C2	0.037 (4)	0.024 (3)	0.038 (4)	−0.001 (3)	0.021 (3)	0.004 (3)
C3	0.027 (3)	0.034 (4)	0.032 (4)	0.004 (3)	0.003 (3)	−0.003 (3)

Geometric parameters (Å, º) top

Tb1—O1	2.307 (4)	C1—C2	1.495 (8)
Tb1—O5	2.465 (4)	C3—C3ⁱⁱⁱ	1.49 (1)
Tb1—O6	2.506 (4)	O1w—H1w1	0.85
Tb1—O7ⁱ	2.368 (4)	O1w—H1w2	0.85
Tb1—O9	2.530 (4)	O2w—H2w1	0.85
Tb1—O10	2.489 (4)	O2w—H2w2	0.85
Tb1—O11ⁱⁱ	2.521 (4)	O3w—H3w1	0.85
Tb1—O12ⁱⁱ	2.479 (4)	O3w—H3w2	0.85
Tb1—O1w	2.385 (4)	N1—H1n1	0.85
S1—O2	1.452 (4)	N1—H1n2	0.85
S1—O4	1.470 (4)	N1—H1n3	0.85
S1—O3	1.478 (4)	N2—H2n1	0.85
S1—O1	1.493 (4)	N2—H2n2	0.85
S2—O8	1.457 (4)	N2—H2n3	0.85
S2—O7	1.473 (4)	N3—H3n1	0.85
S2—O6	1.481 (4)	N3—H3n2	0.85
S2—O5	1.485 (4)	N3—H3n3	0.85
S3—O9	1.468 (4)	C1—H1a	0.97
S3—O11	1.470 (4)	C1—H1b	0.97
S3—O10	1.480 (4)	C2—H2a	0.97
S3—O12	1.482 (4)	C2—H2b	0.97
N1—C1	1.474 (7)	C3—H3a	0.97
N2—C2	1.480 (8)	C3—H3b	0.97
N3—C3	1.472 (8)

O1—Tb1—O5	129.7 (1)	O11—S3—O12	104.9 (2)
O1—Tb1—O6	74.2 (1)	O10—S3—O12	111.1 (2)
O1—Tb1—O7ⁱ	80.7 (1)	S1—O1—Tb1	144.2 (2)
O1—Tb1—O9	141.7 (1)	S2—O5—Tb1	100.3 (2)
O1—Tb1—O10	147.2 (1)	S2—O6—Tb1	98.6 (2)
O1—Tb1—O11ⁱⁱ	77.4 (1)	S2—O7—Tb1^iv	143.6 (2)
O1—Tb1—O12ⁱⁱ	86.7 (1)	S3—O9—Tb1	98.6 (2)
O1—Tb1—O1w	77.2 (1)	S3—O10—Tb1	100.0 (2)
O5—Tb1—O6	56.4 (1)	S3—O11—Tb1^v	98.9 (2)
O5—Tb1—O7ⁱ	148.2 (1)	S3—O12—Tb1^v	100.4 (2)
O5—Tb1—O9	71.4 (1)	N1—C1—C2	110.7 (5)
O5—Tb1—O10	77.8 (1)	N2—C2—C1	109.5 (5)
O5—Tb1—O11ⁱⁱ	119.2 (1)	N3—C3—C3ⁱⁱⁱ	110.5 (6)
O5—Tb1—O12ⁱⁱ	71.0 (1)	Tb1—O1w—H1w1	107.7
O5—Tb1—O1w	95.9 (1)	Tb1—O1w—H1w2	129.1
O6—Tb1—O7ⁱ	147.0 (1)	H1w1—O1w—H1w2	109.8
O6—Tb1—O9	109.3 (1)	H2w1—O2w—H2w2	109.6
O6—Tb1—O10	133.5 (1)	H3w1—O3w—H3w2	110.4
O6—Tb1—O11ⁱⁱ	121.8 (1)	C1—N1—H1n1	109.5
O6—Tb1—O12ⁱⁱ	72.7 (1)	C1—N1—H1n2	109.5
O6—Tb1—O1w	73.3 (1)	H1n1—N1—H1n2	109.5
O7ⁱ—Tb1—O9	78.0 (1)	C1—N1—H1n3	109.5
O7ⁱ—Tb1—O10	77.9 (1)	H1n1—N1—H1n3	109.5
O7ⁱ—Tb1—O11ⁱⁱ	71.6 (1)	H1n2—N1—H1n3	109.5
O7ⁱ—Tb1—O12ⁱⁱ	127.4 (1)	C2—N2—H2n1	109.5
O7ⁱ—Tb1—O1w	80.5 (1)	C2—N2—H2n2	109.5
O9—Tb1—O10	55.8 (1)	H2n1—N2—H2n2	109.5
O9—Tb1—O11ⁱⁱ	124.1 (1)	C2—N2—H2n3	109.5
O9—Tb1—O12ⁱⁱ	131.4 (1)	H2n1—N2—H2n3	109.5
O9—Tb1—O1w	68.1 (1)	H2n2—N2—H2n3	109.5
O10—Tb1—O11ⁱⁱ	72.4 (1)	C3—N3—H3n1	109.5
O10—Tb1—O12ⁱⁱ	86.8 (1)	C3—N3—H3n2	109.5
O10—Tb1—O1w	122.7 (1)	H3n1—N3—H3n2	109.5
O11ⁱⁱ—Tb1—O12ⁱⁱ	55.8 (1)	C3—N3—H3n3	109.5
O11ⁱⁱ—Tb1—O1w	144.8 (1)	H3n1—N3—H3n3	109.5
O12ⁱⁱ—Tb1—O1w	145.2 (1)	H3n2—N3—H3n3	109.5
O2—S1—O4	110.7 (2)	N1—C1—H1a	109.5
O2—S1—O3	111.0 (3)	C2—C1—H1a	109.5
O4—S1—O3	108.4 (2)	N1—C1—H1b	109.5
O2—S1—O1	109.1 (2)	C2—C1—H1b	109.5
O4—S1—O1	108.7 (2)	H1a—C1—H1b	108.1
O3—S1—O1	108.9 (2)	N2—C2—H2a	109.8
O8—S2—O7	110.7 (2)	C1—C2—H2a	109.8
O8—S2—O6	111.1 (3)	N2—C2—H2b	109.8
O7—S2—O6	109.7 (2)	C1—C2—H2b	109.8
O8—S2—O5	110.7 (3)	H2a—C2—H2b	108.2
O7—S2—O5	109.8 (2)	N3—C3—H3a	109.5
O6—S2—O5	104.7 (2)	C3ⁱⁱⁱ—C3—H3a	109.5
O9—S3—O11	112.3 (2)	N3—C3—H3b	109.5
O9—S3—O10	105.5 (2)	C3ⁱⁱⁱ—C3—H3b	109.5
O11—S3—O10	112.1 (2)	H3a—C3—H3b	108.1
O9—S3—O12	111.0 (2)

O2—S1—O1—Tb1	101.5 (4)	S3ⁱⁱ—Tb1—O6—S2	−93.0 (2)
O4—S1—O1—Tb1	−137.7 (4)	S3—Tb1—O6—S2	22.0 (2)
O3—S1—O1—Tb1	−19.9 (5)	O8—S2—O7—Tb1^iv	−0.3 (5)
O7ⁱ—Tb1—O1—S1	101.1 (4)	O6—S2—O7—Tb1^iv	122.6 (4)
O1W—Tb1—O1—S1	18.8 (4)	O5—S2—O7—Tb1^iv	−122.8 (4)
O5—Tb1—O1—S1	−68.2 (5)	O11—S3—O9—Tb1	−125.1 (2)
O12ⁱⁱ—Tb1—O1—S1	−130.2 (4)	O10—S3—O9—Tb1	−2.7 (2)
O10—Tb1—O1—S1	150.8 (3)	O12—S3—O9—Tb1	117.8 (2)
O6—Tb1—O1—S1	−57.2 (4)	O1—Tb1—O9—S3	142.9 (2)
O11ⁱⁱ—Tb1—O1—S1	174.2 (4)	O7ⁱ—Tb1—O9—S3	85.3 (2)
O9—Tb1—O1—S1	44.2 (5)	O1W—Tb1—O9—S3	169.7 (2)
S2—Tb1—O1—S1	−61.2 (4)	O5—Tb1—O9—S3	−85.7 (2)
S3ⁱⁱ—Tb1—O1—S1	−157.8 (4)	O12ⁱⁱ—Tb1—O9—S3	−44.6 (3)
S3—Tb1—O1—S1	91.8 (5)	O10—Tb1—O9—S3	1.9 (2)
O8—S2—O5—Tb1	116.9 (2)	O6—Tb1—O9—S3	−128.3 (2)
O7—S2—O5—Tb1	−120.6 (2)	O11ⁱⁱ—Tb1—O9—S3	27.5 (2)
O6—S2—O5—Tb1	−2.9 (2)	S2—Tb1—O9—S3	−107.6 (2)
O1—Tb1—O5—S2	14.8 (3)	S3ⁱⁱ—Tb1—O9—S3	−6.5 (2)
O7ⁱ—Tb1—O5—S2	−144.9 (2)	O9—S3—O10—Tb1	2.7 (2)
O1W—Tb1—O5—S2	−63.4 (2)	O11—S3—O10—Tb1	125.3 (2)
O12ⁱⁱ—Tb1—O5—S2	83.5 (2)	O12—S3—O10—Tb1	−117.7 (2)
O10—Tb1—O5—S2	174.3 (2)	O1—Tb1—O10—S3	−135.9 (2)
O6—Tb1—O5—S2	1.99 (17)	O7ⁱ—Tb1—O10—S3	−85.5 (2)
O11ⁱⁱ—Tb1—O5—S2	112.7 (2)	O1W—Tb1—O10—S3	−15.2 (3)
O9—Tb1—O5—S2	−128.0 (2)	O5—Tb1—O10—S3	73.9 (2)
S3ⁱⁱ—Tb1—O5—S2	97.86 (19)	O12ⁱⁱ—Tb1—O10—S3	145.2 (2)
S3—Tb1—O5—S2	−157.4 (2)	O6—Tb1—O10—S3	82.7 (2)
O8—S2—O6—Tb1	−116.7 (2)	O11ⁱⁱ—Tb1—O10—S3	−159.8 (2)
O7—S2—O6—Tb1	120.6 (2)	O9—Tb1—O10—S3	−1.9 (2)
O5—S2—O6—Tb1	2.8 (2)	S2—Tb1—O10—S3	76.7 (2)
O1—Tb1—O6—S2	−171.8 (2)	S3ⁱⁱ—Tb1—O10—S3	171.9 (2)
O7ⁱ—Tb1—O6—S2	146.1 (2)	O9—S3—O11—Tb1^v	−119.5 (2)
O1W—Tb1—O6—S2	107.2 (2)	O10—S3—O11—Tb1^v	121.9 (2)
O5—Tb1—O6—S2	−2.0 (2)	O12—S3—O11—Tb1^v	1.2 (2)
O12ⁱⁱ—Tb1—O6—S2	−80.3 (2)	O9—S3—O12—Tb1^v	120.3 (2)
O10—Tb1—O6—S2	−12.3 (3)	O11—S3—O12—Tb1^v	−1.2 (2)
O11ⁱⁱ—Tb1—O6—S2	−108.0 (2)	O10—S3—O12—Tb1^v	−122.6 (2)
O9—Tb1—O6—S2	48.3 (2)	N1—C1—C2—N2	−176.9 (5)

Symmetry codes: (i) x+1, y, z; (ii) x, −y+1/2, z+1/2; (iii) −x, −y+1, −z+1; (iv) x−1, y, z; (v) x, −y+1/2, z−1/2.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
O1w—H1w1···O3	0.85	1.79	2.623 (6)	165
O1w—H1w2···O8ⁱ	0.85	2.36	2.942 (6)	127
O2w—H2w1···O2	0.85	1.93	2.750 (6)	161
O2w—H2w2···O4^vi	0.85	1.94	2.785 (6)	176
O3w—H3w1···O2w^vi	0.85	2.04	2.852 (8)	159
O3w—H3w2···O9^vii	0.85	2.24	2.888 (7)	133
N1—H1n1···O4^iv	0.85	1.97	2.811 (6)	173
N1—H1n2···O6	0.85	2.17	2.984 (6)	159
N1—H1n3···O3w	0.85	2.10	2.891 (8)	156
N2—H2n1···O10^viii	0.85	2.11	2.958 (6)	177
N2—H2n2···O5^vii	0.85	2.28	3.009 (6)	145
N2—H2n3···O12^vii	0.85	2.17	2.959 (7)	155
N3—H3n1···O6ⁱⁱⁱ	0.85	2.50	3.308 (6)	159
N3—H3n2···O2w	0.85	1.97	2.758 (7)	155
N3—H3n3···O3^iv	0.85	1.99	2.835 (6)	171

Symmetry codes: (i) x+1, y, z; (iii) −x, −y+1, −z+1; (iv) x−1, y, z; (vi) −x+1, −y+1, −z+2; (vii) x, y, z+1; (viii) x−1, −y+1/2, z+1/2.

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Format		BIBTeX
		EndNote
		RefMan
		Refer
		Medline
		CIF
		SGML
		Text
		Plain Text

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Poly[tris­(ethyl­ene-1,2-diammonium) bis­[aqua­(μ-sulfato-κ3O,O′:O′′)(μ-sulfato-κ4O,O′:O′′,O′′′)(sulfato-κO)terbate(III)] tetra­hydrate]

Supporting information

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checkCIF/PLATON results

Poly[tris(ethylene-1,2-diammonium) bis[aqua(μ-sulfato-κ³O,O′:O′′)(μ-sulfato-κ⁴O,O′:O′′,O′′′)(sulfato-κO)terbate(III)] tetrahydrate]