Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806025311/ya2019sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536806025311/ya2019Isup2.hkl |
CCDC reference: 618354
Key indicators
- Single-crystal X-ray study
- T = 180 K
- Mean (C-C) = 0.003 Å
- R factor = 0.028
- wR factor = 0.061
- Data-to-parameter ratio = 15.0
checkCIF/PLATON results
No syntax errors found
Alert level C PLAT029_ALERT_3_C _diffrn_measured_fraction_theta_full Low ....... 0.98 PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ? PLAT230_ALERT_2_C Hirshfeld Test Diff for O1 - C4_a .. 6.44 su PLAT244_ALERT_4_C Low 'Solvent' Ueq as Compared to Neighbors for C1S PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........ 3
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 5 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 1 ALERT type 2 Indicator that the structure model may be wrong or deficient 1 ALERT type 3 Indicator that the structure quality may be low 2 ALERT type 4 Improvement, methodology, query or suggestion
Data collection: APEX2 (Bruker Nonius, 2004); cell refinement: SAINT (Bruker, 2003); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2000); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.
[Rh2(C2H3O2)4(C15H15N3O2S)2]·2C2H3N | F(000) = 1148 |
Mr = 1126.82 | Dx = 1.617 Mg m−3 |
Monoclinic, P21/n | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -P 2yn | Cell parameters from 5860 reflections |
a = 8.8710 (9) Å | θ = 2.5–25.8° |
b = 25.256 (3) Å | µ = 0.87 mm−1 |
c = 10.9402 (10) Å | T = 180 K |
β = 109.195 (4)° | Block, red |
V = 2314.8 (4) Å3 | 0.15 × 0.12 × 0.10 mm |
Z = 2 |
Bruker Nonius X8 APEX-II CCD area-detector diffractometer | 4539 independent reflections |
Radiation source: fine-focus sealed tube | 3604 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.042 |
thin–slice ω and φ scans | θmax = 26.4°, θmin = 3.5° |
Absorption correction: multi-scan (SADABS; Sheldrick, 2003) | h = −11→9 |
Tmin = 0.807, Tmax = 0.918 | k = −31→30 |
22091 measured reflections | l = −13→13 |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.028 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.061 | H-atom parameters constrained |
S = 1.07 | w = 1/[σ2(Fo2) + (0.0274P)2] where P = (Fo2 + 2Fc2)/3 |
4539 reflections | (Δ/σ)max = 0.002 |
303 parameters | Δρmax = 0.34 e Å−3 |
0 restraints | Δρmin = −0.50 e Å−3 |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. Least-squares planes (x,y,z in crystal coordinates) and deviations from them (* indicates atom used to define plane) 5.7173 (0.0070) x + 11.7939 (0.0230) y - 8.5737 (0.0076) z = 4.8492 (0.0184) * -0.0018 (0.0012) C1 * 0.0000 (0.0013) C2 * -0.0010 (0.0013) C3 * 0.0011 (0.0012) N1 * 0.0017 (0.0013) N2 Rms deviation of fitted atoms = 0.0013 2.7127 (0.0091) x - 2.1030 (0.0541) y + 8.6994 (0.0089) z = 4.6822 (0.0297) Angle to previous plane (with approximate e.s.d.) = 65.42 (0.09) * 0.0045 (0.0007) Rh1 * -0.0022 (0.0004) O1 * -0.0026 (0.0004) O2 * 0.0003 (0.0000) C4 Rms deviation of fitted atoms = 0.0028 |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
Rh1 | 0.47076 (2) | 0.544476 (7) | 0.523569 (16) | 0.01554 (7) | |
S1 | 0.09853 (7) | 0.73740 (2) | 0.51757 (5) | 0.01902 (15) | |
O1 | 0.65992 (19) | 0.56821 (6) | 0.46955 (14) | 0.0206 (4) | |
O2 | 0.28461 (18) | 0.51541 (6) | 0.57378 (14) | 0.0222 (4) | |
O3 | 0.3251 (2) | 0.55113 (6) | 0.33604 (14) | 0.0228 (4) | |
O4 | 0.61765 (19) | 0.53225 (6) | 0.70848 (14) | 0.0198 (4) | |
O5 | −0.02361 (19) | 0.70686 (7) | 0.42744 (14) | 0.0247 (4) | |
O6 | 0.14766 (19) | 0.78571 (6) | 0.47560 (14) | 0.0242 (4) | |
N1 | 0.2579 (2) | 0.69612 (7) | 0.56388 (16) | 0.0157 (4) | |
N2 | 0.4089 (2) | 0.62632 (7) | 0.56846 (17) | 0.0176 (4) | |
N3 | 0.0212 (2) | 0.68135 (8) | 1.07099 (18) | 0.0236 (5) | |
C1 | 0.2725 (3) | 0.64850 (9) | 0.5084 (2) | 0.0180 (5) | |
H1A | 0.1931 | 0.6337 | 0.4356 | 0.022* | |
C2 | 0.3972 (3) | 0.70353 (9) | 0.6671 (2) | 0.0191 (5) | |
H2A | 0.4233 | 0.7328 | 0.7247 | 0.023* | |
C3 | 0.4884 (3) | 0.66046 (9) | 0.6688 (2) | 0.0199 (6) | |
H3A | 0.5916 | 0.6544 | 0.7295 | 0.024* | |
C4 | 0.2623 (3) | 0.46587 (10) | 0.5691 (2) | 0.0212 (6) | |
C5 | 0.1271 (3) | 0.44573 (10) | 0.6120 (3) | 0.0326 (7) | |
H5A | 0.1431 | 0.4080 | 0.6332 | 0.049* | |
H5B | 0.0256 | 0.4507 | 0.5419 | 0.049* | |
H5C | 0.1251 | 0.4655 | 0.6885 | 0.049* | |
C6 | 0.3139 (3) | 0.51219 (10) | 0.2609 (2) | 0.0201 (5) | |
C7 | 0.2045 (3) | 0.51824 (10) | 0.1234 (2) | 0.0291 (6) | |
H7A | 0.2379 | 0.4939 | 0.0673 | 0.044* | |
H7B | 0.2096 | 0.5547 | 0.0946 | 0.044* | |
H7C | 0.0948 | 0.5100 | 0.1187 | 0.044* | |
C8 | 0.0675 (3) | 0.74735 (9) | 0.6668 (2) | 0.0173 (5) | |
C9 | 0.0978 (3) | 0.79692 (9) | 0.7174 (2) | 0.0217 (6) | |
H9A | 0.1255 | 0.8245 | 0.6696 | 0.026* | |
C10 | 0.0879 (3) | 0.80713 (10) | 0.8406 (2) | 0.0252 (6) | |
H10A | 0.1020 | 0.8421 | 0.8743 | 0.030* | |
C11 | 0.0579 (3) | 0.76654 (9) | 0.9116 (2) | 0.0219 (6) | |
H11A | 0.0554 | 0.7736 | 0.9962 | 0.026* | |
C12 | 0.0305 (3) | 0.71431 (9) | 0.8634 (2) | 0.0182 (5) | |
C13 | −0.0014 (3) | 0.67173 (10) | 0.9391 (2) | 0.0209 (6) | |
C14 | −0.0587 (3) | 0.62473 (10) | 0.8790 (2) | 0.0249 (6) | |
H14A | −0.0883 | 0.5974 | 0.9263 | 0.030* | |
C15 | −0.0743 (3) | 0.61657 (10) | 0.7482 (2) | 0.0281 (6) | |
H15A | −0.1168 | 0.5840 | 0.7082 | 0.034* | |
C16 | −0.0301 (3) | 0.65412 (10) | 0.6773 (2) | 0.0246 (6) | |
H16A | −0.0355 | 0.6468 | 0.5908 | 0.030* | |
C17 | 0.0240 (3) | 0.70419 (9) | 0.7333 (2) | 0.0173 (5) | |
C18 | −0.0549 (3) | 0.64434 (10) | 1.1342 (2) | 0.0276 (6) | |
H18A | −0.1661 | 0.6389 | 1.0798 | 0.041* | |
H18B | −0.0519 | 0.6588 | 1.2182 | 0.041* | |
H18C | 0.0021 | 0.6105 | 1.1473 | 0.041* | |
C19 | 0.1852 (3) | 0.69225 (11) | 1.1522 (2) | 0.0345 (7) | |
H19A | 0.2365 | 0.7151 | 1.1050 | 0.052* | |
H19B | 0.2443 | 0.6589 | 1.1744 | 0.052* | |
H19C | 0.1849 | 0.7101 | 1.2316 | 0.052* | |
N1S | 0.5885 (4) | 0.56774 (13) | 1.0778 (3) | 0.0827 (11) | |
C1S | 0.4868 (4) | 0.57100 (13) | 0.9847 (3) | 0.0474 (8) | |
C2S | 0.3547 (4) | 0.57480 (14) | 0.8656 (3) | 0.0610 (10) | |
H2S1 | 0.2672 | 0.5522 | 0.8707 | 0.091* | |
H2S2 | 0.3890 | 0.5632 | 0.7934 | 0.091* | |
H2S3 | 0.3181 | 0.6116 | 0.8517 | 0.091* |
U11 | U22 | U33 | U12 | U13 | U23 | |
Rh1 | 0.01835 (12) | 0.01179 (12) | 0.01602 (10) | 0.00092 (9) | 0.00504 (8) | −0.00012 (7) |
S1 | 0.0196 (3) | 0.0207 (4) | 0.0165 (3) | 0.0038 (3) | 0.0056 (3) | 0.0012 (2) |
O1 | 0.0253 (10) | 0.0151 (9) | 0.0232 (8) | −0.0005 (8) | 0.0106 (8) | 0.0002 (7) |
O2 | 0.0221 (10) | 0.0188 (10) | 0.0281 (9) | −0.0002 (8) | 0.0116 (8) | −0.0003 (7) |
O3 | 0.0259 (10) | 0.0176 (10) | 0.0199 (8) | 0.0048 (8) | 0.0008 (8) | −0.0012 (7) |
O4 | 0.0243 (10) | 0.0152 (10) | 0.0182 (8) | 0.0003 (8) | 0.0047 (8) | −0.0011 (7) |
O5 | 0.0205 (10) | 0.0323 (11) | 0.0181 (8) | 0.0016 (8) | 0.0020 (7) | −0.0022 (7) |
O6 | 0.0313 (11) | 0.0192 (10) | 0.0233 (9) | 0.0039 (8) | 0.0104 (8) | 0.0061 (7) |
N1 | 0.0147 (11) | 0.0166 (11) | 0.0150 (9) | 0.0029 (9) | 0.0039 (9) | −0.0021 (8) |
N2 | 0.0221 (12) | 0.0149 (11) | 0.0159 (9) | 0.0007 (10) | 0.0066 (9) | 0.0002 (8) |
N3 | 0.0228 (12) | 0.0303 (13) | 0.0194 (10) | −0.0050 (10) | 0.0090 (9) | −0.0015 (9) |
C1 | 0.0221 (15) | 0.0153 (14) | 0.0183 (11) | −0.0024 (11) | 0.0091 (11) | −0.0019 (10) |
C2 | 0.0220 (15) | 0.0182 (14) | 0.0152 (11) | −0.0020 (12) | 0.0037 (11) | −0.0043 (10) |
C3 | 0.0198 (14) | 0.0202 (15) | 0.0179 (12) | 0.0020 (12) | 0.0039 (11) | 0.0005 (10) |
C4 | 0.0210 (15) | 0.0242 (16) | 0.0150 (11) | −0.0044 (12) | 0.0014 (11) | 0.0009 (10) |
C5 | 0.0306 (17) | 0.0318 (17) | 0.0397 (15) | −0.0064 (13) | 0.0173 (14) | 0.0009 (12) |
C6 | 0.0177 (14) | 0.0203 (15) | 0.0230 (12) | −0.0037 (12) | 0.0076 (11) | 0.0022 (11) |
C7 | 0.0350 (17) | 0.0273 (16) | 0.0185 (12) | 0.0031 (13) | 0.0000 (12) | 0.0003 (11) |
C8 | 0.0144 (13) | 0.0185 (14) | 0.0192 (12) | 0.0042 (11) | 0.0060 (10) | −0.0023 (10) |
C9 | 0.0193 (14) | 0.0203 (15) | 0.0277 (13) | 0.0006 (11) | 0.0106 (11) | −0.0001 (11) |
C10 | 0.0237 (15) | 0.0215 (15) | 0.0323 (14) | −0.0009 (12) | 0.0116 (12) | −0.0091 (11) |
C11 | 0.0194 (14) | 0.0252 (15) | 0.0241 (12) | −0.0028 (12) | 0.0112 (11) | −0.0076 (11) |
C12 | 0.0124 (13) | 0.0208 (14) | 0.0227 (12) | −0.0020 (11) | 0.0075 (11) | −0.0025 (10) |
C13 | 0.0159 (14) | 0.0261 (15) | 0.0217 (12) | 0.0020 (11) | 0.0073 (11) | −0.0010 (11) |
C14 | 0.0273 (15) | 0.0218 (15) | 0.0264 (13) | −0.0041 (12) | 0.0099 (12) | 0.0020 (11) |
C15 | 0.0349 (17) | 0.0195 (15) | 0.0282 (14) | −0.0092 (13) | 0.0079 (13) | −0.0063 (11) |
C16 | 0.0300 (16) | 0.0236 (15) | 0.0213 (12) | −0.0042 (12) | 0.0097 (12) | −0.0053 (11) |
C17 | 0.0138 (13) | 0.0190 (14) | 0.0186 (11) | 0.0009 (11) | 0.0048 (10) | −0.0024 (10) |
C18 | 0.0322 (16) | 0.0281 (16) | 0.0256 (13) | 0.0035 (13) | 0.0136 (12) | 0.0024 (11) |
C19 | 0.0281 (17) | 0.0463 (19) | 0.0266 (14) | −0.0050 (14) | 0.0056 (13) | −0.0027 (12) |
N1S | 0.070 (3) | 0.065 (2) | 0.095 (3) | −0.018 (2) | 0.003 (2) | −0.010 (2) |
C1S | 0.049 (2) | 0.035 (2) | 0.060 (2) | −0.0073 (18) | 0.021 (2) | −0.0056 (17) |
C2S | 0.068 (3) | 0.075 (3) | 0.048 (2) | 0.002 (2) | 0.030 (2) | 0.0084 (18) |
Rh1—Rh1i | 2.3997 (4) | C7—H7A | 0.980 |
Rh1—O1 | 2.0436 (16) | C7—H7B | 0.980 |
Rh1—O2 | 2.0406 (15) | C7—H7C | 0.980 |
Rh1—O3 | 2.0406 (15) | C8—C9 | 1.360 (3) |
Rh1—O4 | 2.0378 (15) | C8—C17 | 1.432 (3) |
Rh1—N2 | 2.2343 (18) | C9—C10 | 1.403 (3) |
S1—O6 | 1.4217 (16) | C9—H9A | 0.950 |
S1—O5 | 1.4277 (17) | C10—C11 | 1.365 (3) |
S1—N1 | 1.6948 (19) | C10—H10A | 0.950 |
S1—C8 | 1.761 (2) | C11—C12 | 1.412 (3) |
O1—C4i | 1.260 (3) | C11—H11A | 0.950 |
O2—C4 | 1.265 (3) | C12—C17 | 1.429 (3) |
O3—C6 | 1.265 (3) | C12—C13 | 1.441 (3) |
O4—C6i | 1.267 (3) | C13—C14 | 1.371 (3) |
N1—C1 | 1.372 (3) | C14—C15 | 1.408 (3) |
N1—C2 | 1.385 (3) | C14—H14A | 0.950 |
N2—C1 | 1.299 (3) | C15—C16 | 1.362 (3) |
N2—C3 | 1.391 (3) | C15—H15A | 0.950 |
N3—C13 | 1.411 (3) | C16—C17 | 1.418 (3) |
N3—C18 | 1.454 (3) | C16—H16A | 0.950 |
N3—C19 | 1.460 (3) | C18—H18A | 0.980 |
C1—H1A | 0.950 | C18—H18B | 0.980 |
C2—C3 | 1.352 (3) | C18—H18C | 0.980 |
C2—H2A | 0.950 | C19—H19A | 0.980 |
C3—H3A | 0.950 | C19—H19B | 0.980 |
C4—O1i | 1.260 (3) | C19—H19C | 0.980 |
C4—C5 | 1.512 (3) | N1S—C1S | 1.119 (4) |
C5—H5A | 0.980 | C1S—C2S | 1.441 (4) |
C5—H5B | 0.980 | C2S—H2S1 | 0.980 |
C5—H5C | 0.980 | C2S—H2S2 | 0.980 |
C6—O4i | 1.268 (3) | C2S—H2S3 | 0.980 |
C6—C7 | 1.506 (3) | ||
O4—Rh1—O2 | 89.32 (6) | C6—C7—H7A | 109.5 |
O4—Rh1—O3 | 175.93 (6) | C6—C7—H7B | 109.5 |
O2—Rh1—O3 | 89.95 (6) | H7A—C7—H7B | 109.5 |
O4—Rh1—O1 | 90.79 (6) | C6—C7—H7C | 109.5 |
O2—Rh1—O1 | 175.91 (6) | H7A—C7—H7C | 109.5 |
O3—Rh1—O1 | 89.65 (6) | H7B—C7—H7C | 109.5 |
O4—Rh1—N2 | 92.58 (6) | C9—C8—C17 | 123.0 (2) |
O2—Rh1—N2 | 89.70 (7) | C9—C8—S1 | 116.03 (17) |
O3—Rh1—N2 | 91.41 (6) | C17—C8—S1 | 120.84 (17) |
O1—Rh1—N2 | 94.39 (7) | C8—C9—C10 | 119.6 (2) |
O4—Rh1—Rh1i | 87.63 (4) | C8—C9—H9A | 120.2 |
O2—Rh1—Rh1i | 88.41 (5) | C10—C9—H9A | 120.2 |
O3—Rh1—Rh1i | 88.35 (4) | C11—C10—C9 | 119.6 (2) |
O1—Rh1—Rh1i | 87.50 (5) | C11—C10—H10A | 120.2 |
N2—Rh1—Rh1i | 178.10 (5) | C9—C10—H10A | 120.2 |
O6—S1—O5 | 118.96 (10) | C10—C11—C12 | 122.1 (2) |
O6—S1—N1 | 108.07 (10) | C10—C11—H11A | 119.0 |
O5—S1—N1 | 104.09 (10) | C12—C11—H11A | 119.0 |
O6—S1—C8 | 109.57 (10) | C11—C12—C17 | 119.0 (2) |
O5—S1—C8 | 113.76 (10) | C11—C12—C13 | 121.6 (2) |
N1—S1—C8 | 100.38 (10) | C17—C12—C13 | 119.2 (2) |
C4i—O1—Rh1 | 119.28 (15) | C14—C13—N3 | 123.0 (2) |
C4—O2—Rh1 | 118.34 (15) | C14—C13—C12 | 118.9 (2) |
C6—O3—Rh1 | 118.54 (15) | N3—C13—C12 | 118.1 (2) |
C6i—O4—Rh1 | 119.40 (14) | C13—C14—C15 | 120.7 (2) |
C1—N1—C2 | 106.88 (19) | C13—C14—H14A | 119.6 |
C1—N1—S1 | 126.70 (16) | C15—C14—H14A | 119.6 |
C2—N1—S1 | 126.41 (15) | C16—C15—C14 | 121.8 (2) |
C1—N2—C3 | 106.15 (19) | C16—C15—H15A | 119.1 |
C1—N2—Rh1 | 122.89 (15) | C14—C15—H15A | 119.1 |
C3—N2—Rh1 | 130.48 (16) | C15—C16—C17 | 119.7 (2) |
C13—N3—C18 | 116.35 (19) | C15—C16—H16A | 120.2 |
C13—N3—C19 | 115.62 (18) | C17—C16—H16A | 120.2 |
C18—N3—C19 | 110.94 (19) | C16—C17—C12 | 119.1 (2) |
N2—C1—N1 | 111.2 (2) | C16—C17—C8 | 124.67 (19) |
N2—C1—H1A | 124.4 | C12—C17—C8 | 116.1 (2) |
N1—C1—H1A | 124.4 | N3—C18—H18A | 109.5 |
C3—C2—N1 | 105.8 (2) | N3—C18—H18B | 109.5 |
C3—C2—H2A | 127.1 | H18A—C18—H18B | 109.5 |
N1—C2—H2A | 127.1 | N3—C18—H18C | 109.5 |
C2—C3—N2 | 110.0 (2) | H18A—C18—H18C | 109.5 |
C2—C3—H3A | 125.0 | H18B—C18—H18C | 109.5 |
N2—C3—H3A | 125.0 | N3—C19—H19A | 109.5 |
O1i—C4—O2 | 126.4 (2) | N3—C19—H19B | 109.5 |
O1i—C4—C5 | 116.9 (2) | H19A—C19—H19B | 109.5 |
O2—C4—C5 | 116.7 (2) | N3—C19—H19C | 109.5 |
C4—C5—H5A | 109.5 | H19A—C19—H19C | 109.5 |
C4—C5—H5B | 109.5 | H19B—C19—H19C | 109.5 |
H5A—C5—H5B | 109.5 | N1S—C1S—C2S | 179.3 (4) |
C4—C5—H5C | 109.5 | C1S—C2S—H2S1 | 109.5 |
H5A—C5—H5C | 109.5 | C1S—C2S—H2S2 | 109.5 |
H5B—C5—H5C | 109.5 | H2S1—C2S—H2S2 | 109.5 |
O3—C6—O4i | 126.0 (2) | C1S—C2S—H2S3 | 109.5 |
O3—C6—C7 | 117.2 (2) | H2S1—C2S—H2S3 | 109.5 |
O4i—C6—C7 | 116.7 (2) | H2S2—C2S—H2S3 | 109.5 |
O4—Rh1—O1—C4i | 88.74 (16) | Rh1—O2—C4—O1i | −3.4 (3) |
O3—Rh1—O1—C4i | −87.22 (16) | Rh1—O2—C4—C5 | 177.71 (16) |
N2—Rh1—O1—C4i | −178.61 (16) | Rh1—O3—C6—O4i | 2.1 (3) |
Rh1i—Rh1—O1—C4i | 1.15 (16) | Rh1—O3—C6—C7 | 179.56 (15) |
O4—Rh1—O2—C4 | −85.86 (16) | O6—S1—C8—C9 | −1.5 (2) |
O3—Rh1—O2—C4 | 90.14 (16) | O5—S1—C8—C9 | −137.40 (18) |
N2—Rh1—O2—C4 | −178.45 (16) | N1—S1—C8—C9 | 112.04 (19) |
Rh1i—Rh1—O2—C4 | 1.79 (16) | O6—S1—C8—C17 | −177.23 (18) |
O2—Rh1—O3—C6 | −89.91 (16) | O5—S1—C8—C17 | 46.9 (2) |
O1—Rh1—O3—C6 | 86.01 (16) | N1—S1—C8—C17 | −63.7 (2) |
N2—Rh1—O3—C6 | −179.61 (16) | C17—C8—C9—C10 | 0.5 (4) |
Rh1i—Rh1—O3—C6 | −1.50 (16) | S1—C8—C9—C10 | −175.12 (18) |
O2—Rh1—O4—C6i | 88.39 (16) | C8—C9—C10—C11 | 4.1 (4) |
O1—Rh1—O4—C6i | −87.52 (16) | C9—C10—C11—C12 | −2.3 (4) |
N2—Rh1—O4—C6i | 178.06 (16) | C10—C11—C12—C17 | −4.0 (4) |
Rh1i—Rh1—O4—C6i | −0.05 (16) | C10—C11—C12—C13 | −179.9 (2) |
O6—S1—N1—C1 | −116.54 (18) | C18—N3—C13—C14 | −14.6 (3) |
O5—S1—N1—C1 | 10.8 (2) | C19—N3—C13—C14 | 118.2 (3) |
C8—S1—N1—C1 | 128.75 (19) | C18—N3—C13—C12 | 162.4 (2) |
O6—S1—N1—C2 | 65.04 (19) | C19—N3—C13—C12 | −64.8 (3) |
O5—S1—N1—C2 | −167.59 (17) | C11—C12—C13—C14 | 166.8 (2) |
C8—S1—N1—C2 | −49.7 (2) | C17—C12—C13—C14 | −9.0 (3) |
O4—Rh1—N2—C1 | −150.26 (16) | C11—C12—C13—N3 | −10.3 (3) |
O2—Rh1—N2—C1 | −60.95 (16) | C17—C12—C13—N3 | 173.8 (2) |
O3—Rh1—N2—C1 | 28.99 (16) | N3—C13—C14—C15 | −178.0 (2) |
O1—Rh1—N2—C1 | 118.75 (16) | C12—C13—C14—C15 | 5.0 (4) |
O4—Rh1—N2—C3 | 20.62 (19) | C13—C14—C15—C16 | 1.5 (4) |
O2—Rh1—N2—C3 | 109.93 (19) | C14—C15—C16—C17 | −4.0 (4) |
O3—Rh1—N2—C3 | −160.12 (19) | C15—C16—C17—C12 | −0.2 (4) |
O1—Rh1—N2—C3 | −70.36 (19) | C15—C16—C17—C8 | −177.4 (2) |
C3—N2—C1—N1 | 0.3 (2) | C11—C12—C17—C16 | −169.3 (2) |
Rh1—N2—C1—N1 | 173.14 (13) | C13—C12—C17—C16 | 6.6 (3) |
C2—N1—C1—N2 | −0.3 (2) | C11—C12—C17—C8 | 8.1 (3) |
S1—N1—C1—N2 | −178.96 (14) | C13—C12—C17—C8 | −175.9 (2) |
C1—N1—C2—C3 | 0.1 (2) | C9—C8—C17—C16 | 170.7 (2) |
S1—N1—C2—C3 | 178.77 (16) | S1—C8—C17—C16 | −13.9 (3) |
N1—C2—C3—N2 | 0.1 (2) | C9—C8—C17—C12 | −6.6 (3) |
C1—N2—C3—C2 | −0.3 (2) | S1—C8—C17—C12 | 168.83 (17) |
Rh1—N2—C3—C2 | −172.32 (14) |
Symmetry code: (i) −x+1, −y+1, −z+1. |