(4Z)-3-Methyl-1-phenyl-4-{(phen­yl)[4-(trifluoro­meth­oxy)anilino]methyl­ene}-1H-pyrazol-5(4H)-one

In the title compound, C₂₄H₁₈F₃N₃O₂, the dihedral angles formed by the pyrazolone ring with one benzene and two phenyl rings are 26.18 (6), 74.42 (6) and 46.75 (8)°, respectively. The compound is in an enamine–keto form and its structure is stabilized by three intra­molecular (N—H...O, C—H...O and C—H...F) and two inter­molecular (C—H...O and C—H...F) hydrogen-bond inter­actions.

Key indicators

• Single-crystal X-ray study
• T = 113 K
• Mean [sigma](C-C) = 0.003 Å
• Disorder in main residue
• R factor = 0.049
• wR factor = 0.125
• Data-to-parameter ratio = 14.4

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT029_ALERT_3_C _diffrn_measured_fraction_theta_full Low .......       0.98
PLAT066_ALERT_1_C Predicted and Reported Transmissions Identical .          ?
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       2.67 Ratio
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C24
PLAT301_ALERT_3_C Main Residue  Disorder .........................      11.00 Perc.
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      18.60 Deg.
              C24' -O2   -C24     1.555   1.555   1.555

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   6 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   3 ALERT type 2 Indicator that the structure model may be wrong or deficient
   2 ALERT type 3 Indicator that the structure quality may be low
   0 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

---

Computing details

Data collection: CrystalClear (Rigaku/MSC, 2005); cell refinement: CrystalClear; data reduction: CrystalClear; program(s) used to solve structure: SHELXS97 (Sheldrick, 1990); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: CrystalStructure (Rigaku/MSC, 2004); software used to prepare material for publication: CrystalStructure.

(4Z)-3-Methyl-1-phenyl-4-{(phenyl)[4-(trifluoromethoxy)anilino]methylene}- 1H-pyrazol-5(4H)-one

Crystal data

C24H18F3N3O2	Z = 2
Mr = 437.41	F(000) = 452
Triclinic, P1	Dx = 1.420 Mg m^−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71070 Å
a = 8.0696 (9) Å	Cell parameters from 2686 reflections
b = 11.0945 (12) Å	θ = 1.7–27.9°
c = 13.1253 (14) Å	µ = 0.11 mm^−1
α = 106.698 (4)°	T = 113 K
β = 99.688 (5)°	Platelet, yellow
γ = 108.459 (9)°	0.32 × 0.20 × 0.10 mm
V = 1023.2 (2) Å^3

Data collection

Rigaku Saturn diffractometer	4770 independent reflections
Radiation source: Rotating anode	2854 reflections with I > 2σ(I)
Confocal monochromator	Rint = 0.040
Detector resolution: 7.31 pixels mm^-1	θmax = 27.9°, θmin = 1.7°
ω scans	h = −9→10
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	k = −14→12
Tmin = 0.966, Tmax = 0.989	l = −17→16
9409 measured reflections

Refinement

Refinement on F^2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F^2 > 2σ(F^2)] = 0.049	H atoms treated by a mixture of independent and constrained refinement
wR(F^2) = 0.125	w = 1/[σ^2(Fo^2) + (0.0558P)^2] where P = (Fo^2 + 2Fc^2)/3
S = 0.94	(Δ/σ)max = 0.003
4770 reflections	Δρmax = 0.27 e Å^−3
332 parameters	Δρmin = −0.28 e Å^−3
175 restraints	Extinction correction: SHELXL97 (Sheldrick, 1997), Fc^*=kFc[1+0.001xFc^2λ^3/sin(2θ)]^-1/4
Primary atom site location: structure-invariant direct methods	Extinction coefficient: 0.028 (4)

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
O1	0.75299 (16)	0.61087 (13)	0.75314 (11)	0.0270 (3)
N1	1.0507 (2)	0.76483 (16)	0.85706 (12)	0.0234 (4)
N2	1.1526 (2)	0.90516 (16)	0.89128 (13)	0.0260 (4)
N3	0.5576 (2)	0.74522 (17)	0.68609 (13)	0.0255 (4)
C1	0.8722 (2)	0.72936 (19)	0.79899 (15)	0.0230 (4)
C2	0.8595 (2)	0.85739 (19)	0.80125 (15)	0.0231 (4)
C3	1.0399 (2)	0.9593 (2)	0.85964 (15)	0.0248 (4)
C4	1.1115 (3)	1.10967 (19)	0.88521 (17)	0.0315 (5)
H4A	1.2444	1.1481	0.9159	0.047*
H4B	1.0578	1.1523	0.9395	0.047*
H4C	1.0794	1.1272	0.8170	0.047*
C5	1.1405 (2)	0.67718 (19)	0.87229 (15)	0.0225 (4)
C6	1.3272 (2)	0.7184 (2)	0.88455 (15)	0.0264 (4)
H6	1.3951	0.8056	0.8843	0.032*
C7	1.4128 (3)	0.6309 (2)	0.89710 (16)	0.0304 (5)
H7	1.5396	0.6581	0.9045	0.036*
C8	1.3152 (3)	0.5043 (2)	0.89891 (16)	0.0320 (5)
H8	1.3747	0.4448	0.9072	0.038*
C9	1.1305 (3)	0.4651 (2)	0.88854 (16)	0.0330 (5)
H9	1.0634	0.3786	0.8903	0.040*
C10	1.0423 (3)	0.5514 (2)	0.87561 (16)	0.0280 (4)
H10	0.9158	0.5244	0.8691	0.034*
C11	0.7013 (2)	0.86304 (19)	0.74477 (15)	0.0230 (4)
C12	0.6887 (2)	0.99317 (19)	0.74178 (15)	0.0222 (4)
C13	0.6850 (2)	1.0887 (2)	0.83605 (16)	0.0262 (4)
H13	0.6937	1.0727	0.9037	0.031*
C14	0.6686 (2)	1.2076 (2)	0.83042 (16)	0.0284 (5)
H14	0.6647	1.2727	0.8944	0.034*
C15	0.6576 (2)	1.2319 (2)	0.73190 (17)	0.0289 (5)
H15	0.6480	1.3140	0.7288	0.035*
C16	0.6608 (2)	1.1359 (2)	0.63806 (16)	0.0285 (5)
H16	0.6526	1.1521	0.5705	0.034*
C17	0.6759 (2)	1.0167 (2)	0.64273 (16)	0.0259 (4)
H17	0.6775	0.9509	0.5783	0.031*
C18	0.3868 (2)	0.72462 (19)	0.61816 (15)	0.0235 (4)
C19	0.2873 (2)	0.8028 (2)	0.65143 (15)	0.0251 (4)
H19	0.3344	0.8746	0.7220	0.030*
C20	0.1192 (2)	0.7767 (2)	0.58221 (16)	0.0264 (4)
H20	0.0507	0.8299	0.6048	0.032*
C21	0.0539 (2)	0.6720 (2)	0.48025 (15)	0.0254 (4)
C22	0.1491 (2)	0.5916 (2)	0.44563 (16)	0.0259 (4)
H22	0.1007	0.5191	0.3755	0.031*
C23	0.3160 (2)	0.61886 (19)	0.51503 (15)	0.0243 (4)
H23	0.3834	0.5648	0.4921	0.029*
O2	−0.11392 (18)	0.63400 (15)	0.40217 (12)	0.0386 (4)
F1	−0.26439 (18)	0.7258 (2)	0.50398 (12)	0.0570 (6)	0.921 (3)
F2	−0.1170 (2)	0.83808 (19)	0.41867 (18)	0.0663 (7)	0.921 (3)
F3	−0.3549 (3)	0.6536 (3)	0.3282 (2)	0.0758 (9)	0.921 (3)
C24	−0.2077 (3)	0.7120 (3)	0.4127 (2)	0.0391 (7)	0.921 (3)
C24'	−0.187 (2)	0.7195 (14)	0.3866 (15)	0.059 (5)	0.079 (3)
F1'	−0.195 (3)	0.807 (2)	0.4780 (17)	0.075 (5)	0.079 (3)
F2'	−0.081 (3)	0.7895 (19)	0.3384 (17)	0.073 (6)	0.079 (3)
F3'	−0.356 (2)	0.653 (3)	0.318 (2)	0.063 (7)	0.079 (3)
H3	0.581 (3)	0.671 (3)	0.6833 (19)	0.061 (8)*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
O1	0.0252 (7)	0.0205 (8)	0.0332 (8)	0.0094 (6)	0.0046 (6)	0.0082 (6)
N1	0.0242 (8)	0.0177 (8)	0.0280 (9)	0.0086 (7)	0.0051 (7)	0.0086 (7)
N2	0.0279 (8)	0.0199 (9)	0.0290 (9)	0.0086 (7)	0.0054 (7)	0.0096 (7)
N3	0.0260 (8)	0.0212 (9)	0.0309 (9)	0.0127 (7)	0.0053 (7)	0.0096 (7)
C1	0.0234 (9)	0.0236 (11)	0.0226 (10)	0.0103 (8)	0.0067 (8)	0.0079 (8)
C2	0.0277 (9)	0.0207 (10)	0.0242 (10)	0.0126 (8)	0.0074 (8)	0.0091 (8)
C3	0.0267 (10)	0.0238 (11)	0.0244 (10)	0.0107 (9)	0.0060 (8)	0.0091 (8)
C4	0.0307 (10)	0.0213 (11)	0.0387 (12)	0.0088 (9)	0.0033 (9)	0.0106 (9)
C5	0.0274 (10)	0.0220 (10)	0.0219 (9)	0.0139 (9)	0.0063 (8)	0.0089 (8)
C6	0.0275 (10)	0.0294 (11)	0.0250 (10)	0.0128 (9)	0.0067 (8)	0.0124 (9)
C7	0.0290 (10)	0.0378 (13)	0.0278 (11)	0.0185 (10)	0.0062 (8)	0.0115 (9)
C8	0.0371 (11)	0.0306 (12)	0.0298 (11)	0.0218 (10)	0.0025 (9)	0.0073 (9)
C9	0.0385 (11)	0.0237 (11)	0.0353 (12)	0.0136 (10)	0.0030 (9)	0.0112 (9)
C10	0.0287 (10)	0.0258 (11)	0.0301 (11)	0.0124 (9)	0.0052 (8)	0.0107 (9)
C11	0.0271 (9)	0.0213 (10)	0.0213 (10)	0.0106 (8)	0.0077 (8)	0.0068 (8)
C12	0.0202 (9)	0.0199 (10)	0.0270 (10)	0.0089 (8)	0.0050 (7)	0.0092 (8)
C13	0.0286 (10)	0.0260 (11)	0.0262 (10)	0.0125 (9)	0.0052 (8)	0.0118 (8)
C14	0.0295 (10)	0.0257 (11)	0.0306 (11)	0.0142 (9)	0.0070 (8)	0.0080 (9)
C15	0.0243 (10)	0.0228 (11)	0.0370 (12)	0.0082 (9)	0.0013 (8)	0.0126 (9)
C16	0.0283 (10)	0.0282 (11)	0.0301 (11)	0.0093 (9)	0.0061 (8)	0.0152 (9)
C17	0.0279 (10)	0.0251 (11)	0.0266 (10)	0.0107 (9)	0.0085 (8)	0.0112 (9)
C18	0.0234 (9)	0.0228 (10)	0.0287 (10)	0.0101 (8)	0.0086 (8)	0.0136 (8)
C19	0.0268 (10)	0.0236 (11)	0.0254 (10)	0.0107 (8)	0.0075 (8)	0.0082 (8)
C20	0.0255 (10)	0.0289 (11)	0.0313 (11)	0.0165 (9)	0.0103 (8)	0.0122 (9)
C21	0.0206 (9)	0.0279 (11)	0.0283 (10)	0.0098 (8)	0.0048 (8)	0.0118 (9)
C22	0.0271 (9)	0.0220 (11)	0.0293 (11)	0.0096 (8)	0.0094 (8)	0.0095 (8)
C23	0.0256 (9)	0.0217 (10)	0.0298 (10)	0.0120 (8)	0.0095 (8)	0.0114 (8)
O2	0.0290 (8)	0.0412 (10)	0.0380 (9)	0.0205 (7)	−0.0019 (6)	0.0027 (7)
F1	0.0301 (8)	0.0714 (14)	0.0512 (10)	0.0182 (8)	0.0166 (7)	−0.0049 (9)
F2	0.0783 (12)	0.0583 (13)	0.0782 (15)	0.0378 (11)	0.0101 (10)	0.0414 (11)
F3	0.0514 (12)	0.1042 (18)	0.0504 (13)	0.0553 (12)	−0.0156 (10)	−0.0128 (12)
C24	0.0320 (12)	0.0495 (16)	0.0340 (14)	0.0264 (12)	0.0034 (10)	0.0043 (12)
C24'	0.056 (6)	0.064 (6)	0.052 (6)	0.029 (5)	0.003 (6)	0.014 (6)
F1'	0.072 (7)	0.073 (7)	0.073 (7)	0.032 (6)	0.003 (6)	0.022 (6)
F2'	0.076 (8)	0.075 (9)	0.060 (8)	0.021 (7)	0.012 (7)	0.029 (7)
F3'	0.059 (9)	0.070 (9)	0.055 (9)	0.041 (7)	0.006 (7)	0.003 (7)

Geometric parameters (Å, º)

O1—C1	1.251 (2)	C13—C14	1.388 (3)
N1—C1	1.382 (2)	C13—H13	0.9500
N1—N2	1.402 (2)	C14—C15	1.389 (3)
N1—C5	1.421 (2)	C14—H14	0.9500
N2—C3	1.313 (2)	C15—C16	1.388 (3)
N3—C11	1.344 (2)	C15—H15	0.9500
N3—C18	1.420 (2)	C16—C17	1.383 (3)
N3—H3	0.90 (2)	C16—H16	0.9500
C1—C2	1.448 (2)	C17—H17	0.9500
C2—C11	1.394 (2)	C18—C19	1.389 (2)
C2—C3	1.438 (3)	C18—C23	1.392 (2)
C3—C4	1.494 (3)	C19—C20	1.391 (2)
C4—H4A	0.9800	C19—H19	0.9500
C4—H4B	0.9800	C20—C21	1.378 (2)
C4—H4C	0.9800	C20—H20	0.9500
C5—C10	1.387 (3)	C21—C22	1.382 (2)
C5—C6	1.394 (2)	C21—O2	1.409 (2)
C6—C7	1.388 (3)	C22—C23	1.381 (2)
C6—H6	0.9500	C22—H22	0.9500
C7—C8	1.384 (3)	C23—H23	0.9500
C7—H7	0.9500	O2—C24'	1.308 (6)
C8—C9	1.384 (3)	O2—C24	1.312 (2)
C8—H8	0.9500	F1—C24	1.338 (3)
C9—C10	1.392 (3)	F2—C24	1.330 (3)
C9—H9	0.9500	F3—C24	1.311 (3)
C10—H10	0.9500	C24'—F2'	1.333 (10)
C11—C12	1.490 (2)	C24'—F1'	1.334 (10)
C12—C13	1.390 (2)	C24'—F3'	1.337 (10)
C12—C17	1.392 (3)
C1—N1—N2	111.85 (14)	C14—C13—H13	120.3
C1—N1—C5	128.24 (16)	C12—C13—H13	120.3
N2—N1—C5	119.42 (14)	C13—C14—C15	120.45 (18)
C3—N2—N1	106.66 (15)	C13—C14—H14	119.8
C11—N3—C18	128.61 (17)	C15—C14—H14	119.8
C11—N3—H3	113.5 (15)	C16—C15—C14	119.82 (18)
C18—N3—H3	117.3 (15)	C16—C15—H15	120.1
O1—C1—N1	126.04 (17)	C14—C15—H15	120.1
O1—C1—C2	129.19 (16)	C17—C16—C15	120.11 (18)
N1—C1—C2	104.74 (15)	C17—C16—H16	119.9
C11—C2—C3	132.47 (18)	C15—C16—H16	119.9
C11—C2—C1	122.00 (17)	C16—C17—C12	119.99 (18)
C3—C2—C1	105.20 (15)	C16—C17—H17	120.0
N2—C3—C2	111.48 (17)	C12—C17—H17	120.0
N2—C3—C4	118.65 (17)	C19—C18—C23	119.37 (16)
C2—C3—C4	129.85 (16)	C19—C18—N3	122.90 (17)
C3—C4—H4A	109.5	C23—C18—N3	117.71 (16)
C3—C4—H4B	109.5	C18—C19—C20	120.48 (17)
H4A—C4—H4B	109.5	C18—C19—H19	119.8
C3—C4—H4C	109.5	C20—C19—H19	119.8
H4A—C4—H4C	109.5	C21—C20—C19	118.65 (16)
H4B—C4—H4C	109.5	C21—C20—H20	120.7
C10—C5—C6	120.29 (17)	C19—C20—H20	120.7
C10—C5—N1	119.86 (16)	C20—C21—C22	122.06 (16)
C6—C5—N1	119.85 (17)	C20—C21—O2	124.74 (16)
C7—C6—C5	119.35 (19)	C22—C21—O2	113.20 (16)
C7—C6—H6	120.3	C23—C22—C21	118.70 (18)
C5—C6—H6	120.3	C23—C22—H22	120.6
C8—C7—C6	120.71 (18)	C21—C22—H22	120.6
C8—C7—H7	119.6	C22—C23—C18	120.73 (16)
C6—C7—H7	119.6	C22—C23—H23	119.6
C9—C8—C7	119.56 (18)	C18—C23—H23	119.6
C9—C8—H8	120.2	C24'—O2—C24	18.6 (8)
C7—C8—H8	120.2	C24'—O2—C21	124.4 (8)
C8—C9—C10	120.5 (2)	C24—O2—C21	121.31 (17)
C8—C9—H9	119.7	F3—C24—O2	108.4 (2)
C10—C9—H9	119.7	F3—C24—F2	109.2 (2)
C5—C10—C9	119.55 (18)	O2—C24—F2	114.4 (2)
C5—C10—H10	120.2	F3—C24—F1	106.4 (2)
C9—C10—H10	120.2	O2—C24—F1	112.3 (2)
N3—C11—C2	118.34 (17)	F2—C24—F1	105.9 (2)
N3—C11—C12	118.86 (15)	O2—C24'—F2'	104.5 (10)
C2—C11—C12	122.71 (16)	O2—C24'—F1'	115.7 (11)
C13—C12—C17	120.22 (17)	F2'—C24'—F1'	109.1 (11)
C13—C12—C11	120.49 (16)	O2—C24'—F3'	110.8 (13)
C17—C12—C11	119.27 (16)	F2'—C24'—F3'	108.9 (12)
C14—C13—C12	119.40 (17)	F1'—C24'—F3'	107.6 (12)
C1—N1—N2—C3	2.4 (2)	C2—C11—C12—C17	110.3 (2)
C5—N1—N2—C3	175.02 (15)	C17—C12—C13—C14	0.0 (3)
N2—N1—C1—O1	175.70 (17)	C11—C12—C13—C14	−178.38 (16)
C5—N1—C1—O1	3.9 (3)	C12—C13—C14—C15	−0.6 (3)
N2—N1—C1—C2	−2.61 (19)	C13—C14—C15—C16	0.8 (3)
C5—N1—C1—C2	−174.40 (16)	C14—C15—C16—C17	−0.4 (3)
O1—C1—C2—C11	−2.3 (3)	C15—C16—C17—C12	−0.3 (3)
N1—C1—C2—C11	175.93 (16)	C13—C12—C17—C16	0.5 (3)
O1—C1—C2—C3	−176.45 (18)	C11—C12—C17—C16	178.86 (16)
N1—C1—C2—C3	1.80 (19)	C11—N3—C18—C19	−46.2 (3)
N1—N2—C3—C2	−1.1 (2)	C11—N3—C18—C23	135.4 (2)
N1—N2—C3—C4	−179.99 (16)	C23—C18—C19—C20	−0.5 (3)
C11—C2—C3—N2	−173.66 (19)	N3—C18—C19—C20	−178.93 (18)
C1—C2—C3—N2	−0.4 (2)	C18—C19—C20—C21	−0.1 (3)
C11—C2—C3—C4	5.0 (3)	C19—C20—C21—C22	0.8 (3)
C1—C2—C3—C4	178.27 (19)	C19—C20—C21—O2	179.75 (18)
C1—N1—C5—C10	−30.8 (3)	C20—C21—C22—C23	−1.0 (3)
N2—N1—C5—C10	157.91 (17)	O2—C21—C22—C23	179.99 (17)
C1—N1—C5—C6	149.57 (18)	C21—C22—C23—C18	0.4 (3)
N2—N1—C5—C6	−21.7 (2)	C19—C18—C23—C22	0.4 (3)
C10—C5—C6—C7	1.7 (3)	N3—C18—C23—C22	178.86 (17)
N1—C5—C6—C7	−178.69 (16)	C20—C21—O2—C24'	34.3 (10)
C5—C6—C7—C8	−0.8 (3)	C22—C21—O2—C24'	−146.7 (10)
C6—C7—C8—C9	−0.3 (3)	C20—C21—O2—C24	12.4 (3)
C7—C8—C9—C10	0.4 (3)	C22—C21—O2—C24	−168.6 (2)
C6—C5—C10—C9	−1.6 (3)	C24'—O2—C24—F3	73 (2)
N1—C5—C10—C9	178.85 (16)	C21—O2—C24—F3	178.8 (2)
C8—C9—C10—C5	0.5 (3)	C24'—O2—C24—F2	−49 (2)
C18—N3—C11—C2	−176.67 (17)	C21—O2—C24—F2	56.7 (3)
C18—N3—C11—C12	0.0 (3)	C24'—O2—C24—F1	−169 (3)
C3—C2—C11—N3	171.82 (18)	C21—O2—C24—F1	−63.9 (3)
C1—C2—C11—N3	−0.5 (3)	C24—O2—C24'—F2'	157 (3)
C3—C2—C11—C12	−4.7 (3)	C21—O2—C24'—F2'	70.6 (14)
C1—C2—C11—C12	−177.03 (16)	C24—O2—C24'—F1'	37 (2)
N3—C11—C12—C13	112.2 (2)	C21—O2—C24'—F1'	−49.4 (16)
C2—C11—C12—C13	−71.3 (2)	C24—O2—C24'—F3'	−86 (3)
N3—C11—C12—C17	−66.2 (2)	C21—O2—C24'—F3'	−172.2 (14)

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
N3—H3···O1	0.90 (2)	1.92 (2)	2.6938 (19)	143 (2)
C20—H20···F1	0.95	2.38	2.906 (2)	114
C10—H10···O1	0.95	2.43	2.965 (2)	115
C15—H15···F3^i	0.95	2.53	3.178 (2)	126
C22—H22···O1^ii	0.95	2.58	3.306 (2)	133

Symmetry codes: (i) −x, −y+2, −z+1; (ii) −x+1, −y+1, −z+1.