Acta Cryst. (2006). E62, m2170-m2172  [ doi:10.1107/S1600536806029679 ]

Diazidobis(1,10-phenanthroline)iron(II)

Z.-X. Miao, M. Shao, H.-J. Liu and M.-X. Li

Abstract: The solution reaction of Fe^II with 1,10-phenanthroline and NaN₃ affords the title complex, [Fe(N₃)₂(C₁₂H₈N₂)₂]. In this complex, the central atom adopts a six-coordinate octahedral geometry, with monodentate azide ligands occupying the cis sites and two phenanthroline ligands occupying the other four sites, forming a cis isomer.

Online 16 August 2006

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