Acta Cryst. (2006). E62, m2241-m2243  [ doi:10.1107/S160053680603220X ]

Hydronium -chloro-bis[bis(1,10-phenanthroline)copper(I)] hexatungstate monohydrate

P.-T. Ma, F.-X. Hu, M.-X. Li and J.-P. Wang

Abstract: The title compound, (H₃O)[Cu₂Cl(C₁₂H₈N₂)₄][W₆O₁₉]·H₂O, has been synthesized hydrothermally. The structure contains a dicopper(I) complex cation comprising two [Cu(phen)₂]⁺ units bridged by a chloride ion lying on a twofold rotation axis, a Lindquist isopolyanion, [W₆O₁₉]^2-, lying on a centre of inversion, one hydronium cation, and one uncoordinated water molecule per formula unit.

Online 18 August 2006

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