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Acta Cryst. (2006). E62, m2357-m2358  [ doi:10.1107/S1600536806033903 ]

[Bis(3-mesitylpyrazol-1-yl)(5-mesitylpyrazol-1-yl)borohydrido]dichloro(5-mesitylpyrazole)titanium(III) toluene solvate

K. Michiue, I. M. Steele and R. F. Jordan

Abstract: In the title TiIII complex, [Ti(C36H40BN6)Cl2(C12H14N2)]·C7H8, the Ti atom is coordinated in a distorted octahedral geometry by three N atoms that are constrained to a facial arrangement by the TpMs* ligand [TpMs* = HB(3-mesitylpyrazolyl)2(5-mesitylpyrazolyl)], by two mutually cis chloride ligands and by an N atom from a 5-mesitylpyrazole ligand.

Online 31 August 2006


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