Acta Cryst. (2006). E62, m2138-m2140  [ doi:10.1107/S1600536806030972 ]

Di--fluoro-bis[(acetonitrile){N,N'-bis[(dimethylamino)(morpholino)methylene]propane-1,3-diamine}copper(II)] bis(hexafluorophosphate): the first di--fluoro-bridged dicopper bisguanidine compound

S. Herres-Pawlis, U. Flörke and G. Henkel

Abstract: The title compound, [Cu₂(C₁₅H₃₁N₆O₂)F₂(CH₃CN)₂](PF₆)₂, has an N₂Cu(-F)₂CuN₂ core as the central element. The Cu₂F₂ ring is planar due to crystallographic inversion symmetry. The N atom from the enclosed acetonitrile solvent molecule serves as the fifth coordinating atom to the Cu centre. The crystal packing exhibits intermolecular hydrogen bonds.

Online 11 August 2006

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