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Acta Cryst. (2006). E62, m2202-m2204  [ doi:10.1107/S1600536806031680 ]

mer-Bis[2-(6-fluoro-3-methylquinoxalin-2-yl-[kappa]N1)phenyl][3-phenyl-5-(2-pyridyl-[kappa]N)-1,2,4-triazol-1-yl]iridium(III) dichloromethane disolvate

P. G. Jones, S. Ammermann, C. Daniliuc, W.-W. du Mont, W. Kowalsky and H.-H. Johannes

Abstract: The title compound, [Ir(C15H10FN2)2(C13H9N4)]·2CH2Cl2 or C43H29F2IrN8·2CH2Cl2, shows the appreciable trans influence of the C donors; the Ir-N bond lengths trans to C are 2.129 (2) and 2.210 (2) Å, cf. the Ir-N distances trans to N, of 2.055 (2) and 2.070 (2) Å. The three chelating ligands are approximately perpendicular to each other.

Online 16 August 2006


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