(IUCr) Crystallography Journals Online

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Acta Cryst. (2006). E62, m2307-m2309 [ doi:10.1107/S1600536806033447 ]

catena-Poly[hemi[diaquacopper(II)]--salicylato-³O:O',O''-[(salicylato-²O,O')titanate(IV)]--salicylato-³O,O':O''-hemi[bis(N,N-dimethylformide-O)copper(II)]]

J.-Y. Yang, Y.-L. Fu, J.-L. Ren and S. W. Ng

Abstract: The octahedral tris(salicylato)titanate entity in polymeric {[Cu(C₃H₇NO)₂]_1/2[Cu(H₂O)₂]_1/2[Ti(C₇H₄O₃)₃]}_n links adjacent bis(N,N-dimethylformamide)copper and diaquacopper units through the carboxylate O atoms to form a chain motif. Hydrogen bonds within the chain further consolidate the structure. The two independent Cu atoms lie on different sites of $\\overline{1}$ symmetry.

Online 25 August 2006

catena-Poly[hemi[diaquacopper(II)]--salicylato-3O:O',O''-[(salicylato-2O,O')titanate(IV)]--salicylato-3O,O':O''-hemi[bis(N,N-dimethylformide-O)copper(II)]]

J.-Y. Yang, Y.-L. Fu, J.-L. Ren and S. W. Ng

catena-Poly[hemi[diaquacopper(II)]--salicylato-³O:O',O''-[(salicylato-²O,O')titanate(IV)]--salicylato-³O,O':O''-hemi[bis(N,N-dimethylformide-O)copper(II)]]