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In the title compound, C19H21NO2, the asymmetric unit contains two independent mol­ecules (A and B) linked by a strong N—H...O hydrogen bond. The mol­ecular assembly in the structure is established by N—H...O, C—H...O and C—H...π (arene) inter­actions. Inter­molecular N—H...O hydrogen bonds involving different types of mol­ecules generate an infinite ABAB… chain running parallel to the [001] direction. The combination of N—H...O and C—H...O hydrogen bonds results into a two-dimensional supra­molecular framework of R56(32) rings in the (011) plane.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806033381/ci2140sup1.cif
Contains datablocks org1, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536806033381/ci2140Isup2.hkl
Contains datablock I

CCDC reference: 620757

Key indicators

  • Single-crystal X-ray study
  • T = 153 K
  • Mean [sigma](C-C)= 0.004 Å
  • R factor = 0.058
  • wR factor = 0.137
  • Data-to-parameter ratio = 14.7

checkCIF/PLATON results

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No errors found in this datablock

Computing details top

Data collection: SMART (Bruker, 1998); cell refinement: SAINT (Bruker, 1998); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997) and CAMERON (Watkin et al., 1993); software used to prepare material for publication: SHELXL97, PARST95 (Nardelli, 1995) and PLATON (Spek, 2003).

syn-N-[2-Methyl-1-(4-methyl-phenyl)-3-oxo-3-phenyl-propyl]-acetamide top
Crystal data top
C19H21NO2F(000) = 1264
Mr = 295.37Dx = 1.180 Mg m3
Monoclinic, P21/cMelting point: 392(1) K
Hall symbol: -P 2ybcMo Kα radiation, λ = 0.71073 Å
a = 18.3820 (18) ÅCell parameters from 1457 reflections
b = 11.7845 (12) Åθ = 2.2–20.3°
c = 16.4961 (16) ŵ = 0.08 mm1
β = 111.444 (2)°T = 153 K
V = 3326.1 (6) Å3Block, colourless
Z = 80.35 × 0.12 × 0.10 mm
Data collection top
Bruker SMART CCD area-detector
diffractometer
5844 independent reflections
Radiation source: fine-focus sealed tube4060 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.063
φ and ω scansθmax = 25.0°, θmin = 2.1°
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)
h = 2113
Tmin = 0.984, Tmax = 0.992k = 1412
17160 measured reflectionsl = 1919
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.058Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.137H-atom parameters constrained
S = 1.04 w = 1/[σ2(Fo2) + (0.049P)2 + 0.971P]
where P = (Fo2 + 2Fc2)/3
5844 reflections(Δ/σ)max = 0.001
398 parametersΔρmax = 0.33 e Å3
0 restraintsΔρmin = 0.26 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
O10.92272 (10)0.29281 (14)0.75960 (11)0.0284 (4)
O20.89252 (10)0.55527 (14)0.51629 (10)0.0245 (4)
O30.59270 (10)0.46821 (15)0.20451 (12)0.0346 (5)
O40.82350 (10)0.70969 (16)0.22105 (11)0.0331 (5)
N10.86134 (11)0.61008 (16)0.63124 (12)0.0184 (5)
H1A0.85240.66720.65880.022*
N20.82371 (11)0.59357 (16)0.32983 (12)0.0208 (5)
H2A0.85230.55850.37630.025*
C10.89244 (13)0.3571 (2)0.87911 (15)0.0196 (6)
C20.86978 (14)0.4449 (2)0.92152 (16)0.0257 (6)
H20.86400.51810.89900.031*
C30.85588 (15)0.4229 (2)0.99721 (16)0.0290 (6)
H30.84060.48161.02520.035*
C40.86454 (15)0.3149 (2)1.03111 (16)0.0298 (7)
H40.85590.30091.08230.036*
C50.88608 (14)0.2271 (2)0.98907 (16)0.0278 (6)
H50.89120.15391.01150.033*
C60.90010 (13)0.2483 (2)0.91357 (16)0.0236 (6)
H60.91480.18910.88560.028*
C70.90873 (13)0.3745 (2)0.79742 (15)0.0201 (6)
C80.91163 (13)0.4925 (2)0.76189 (15)0.0197 (6)
H80.89270.54700.79450.024*
C90.99618 (14)0.5212 (2)0.77561 (16)0.0267 (6)
H9A0.99880.59690.75540.032*
H9B1.01530.46860.74360.032*
H9C1.02760.51610.83650.032*
C100.85753 (13)0.49703 (19)0.66543 (14)0.0177 (5)
H100.87740.44290.63340.021*
C110.77339 (14)0.4650 (2)0.65028 (15)0.0195 (6)
C120.73356 (14)0.5158 (2)0.69802 (16)0.0262 (6)
H120.75940.56770.74150.031*
C130.65607 (15)0.4902 (2)0.68167 (16)0.0294 (6)
H130.63080.52540.71450.035*
C140.61508 (15)0.4132 (2)0.61753 (17)0.0282 (6)
C150.65518 (15)0.3625 (2)0.57051 (16)0.0264 (6)
H150.62930.31060.52710.032*
C160.73307 (14)0.3874 (2)0.58670 (15)0.0219 (6)
H160.75850.35140.55440.026*
C170.53060 (16)0.3865 (3)0.59915 (19)0.0427 (8)
H17A0.50740.44740.61990.051*
H17B0.52690.31750.62830.051*
H17C0.50360.37770.53750.051*
C180.87772 (13)0.6312 (2)0.56014 (15)0.0194 (5)
C190.87637 (14)0.7538 (2)0.53587 (16)0.0237 (6)
H19A0.83580.76620.48010.028*
H19B0.92590.77440.53300.028*
H19C0.86650.79960.57890.028*
C200.61483 (14)0.3157 (2)0.30375 (16)0.0242 (6)
C250.53540 (15)0.3028 (2)0.28765 (17)0.0324 (7)
H250.49980.35520.25270.039*
C240.50918 (16)0.2128 (3)0.32327 (19)0.0393 (7)
H240.45610.20480.31210.047*
C230.56162 (16)0.1347 (2)0.37538 (18)0.0340 (7)
H230.54370.07400.39900.041*
C220.64029 (16)0.1468 (2)0.39237 (18)0.0315 (7)
H220.67560.09470.42810.038*
C210.66707 (15)0.2362 (2)0.35645 (16)0.0260 (6)
H210.72020.24330.36750.031*
C260.64032 (15)0.4132 (2)0.26224 (16)0.0241 (6)
C270.72715 (14)0.4412 (2)0.29046 (16)0.0215 (6)
H270.75490.40900.34840.026*
C280.75770 (15)0.3859 (2)0.22520 (16)0.0307 (7)
H28A0.75200.30500.22670.037*
H28B0.81190.40450.24030.037*
H28C0.72840.41350.16770.037*
C290.73956 (13)0.5696 (2)0.29407 (15)0.0198 (6)
H290.71810.59910.23440.024*
C300.70310 (13)0.6356 (2)0.34910 (14)0.0186 (5)
C310.68545 (14)0.7496 (2)0.33124 (15)0.0225 (6)
H310.69060.78210.28230.027*
C320.66027 (14)0.8155 (2)0.38530 (16)0.0258 (6)
H320.64890.89170.37190.031*
C330.65165 (14)0.7704 (2)0.45909 (16)0.0242 (6)
C340.66784 (14)0.6560 (2)0.47525 (16)0.0248 (6)
H340.66150.62300.52350.030*
C350.69305 (13)0.5896 (2)0.42168 (15)0.0212 (6)
H350.70340.51310.43440.025*
C360.62573 (17)0.8425 (3)0.51910 (18)0.0391 (7)
H36A0.64810.91690.52340.047*
H36B0.64290.80820.57580.047*
H36C0.56980.84820.49630.047*
C370.85815 (15)0.6673 (2)0.29361 (16)0.0223 (6)
C380.94058 (14)0.6983 (2)0.34834 (17)0.0278 (6)
H38A0.96200.64200.39280.033*
H38B0.94120.77090.37490.033*
H38C0.97140.70180.31230.033*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
O10.0350 (11)0.0204 (10)0.0336 (10)0.0032 (8)0.0169 (9)0.0018 (8)
O20.0315 (11)0.0235 (10)0.0225 (9)0.0019 (8)0.0145 (8)0.0028 (8)
O30.0244 (11)0.0314 (11)0.0387 (11)0.0025 (8)0.0004 (9)0.0072 (9)
O40.0361 (12)0.0369 (12)0.0273 (11)0.0036 (9)0.0130 (9)0.0119 (9)
N10.0252 (12)0.0162 (11)0.0178 (11)0.0010 (8)0.0126 (9)0.0016 (9)
N20.0220 (12)0.0208 (12)0.0197 (11)0.0009 (9)0.0077 (9)0.0047 (9)
C10.0155 (13)0.0206 (14)0.0205 (13)0.0017 (10)0.0040 (11)0.0005 (11)
C20.0312 (16)0.0232 (15)0.0233 (14)0.0037 (11)0.0105 (12)0.0026 (12)
C30.0353 (17)0.0273 (16)0.0256 (15)0.0071 (12)0.0123 (13)0.0052 (12)
C40.0328 (17)0.0340 (17)0.0217 (14)0.0158 (12)0.0089 (12)0.0010 (12)
C50.0267 (15)0.0234 (15)0.0270 (15)0.0101 (11)0.0025 (12)0.0058 (12)
C60.0185 (14)0.0224 (15)0.0263 (14)0.0026 (10)0.0041 (11)0.0011 (11)
C70.0153 (13)0.0191 (14)0.0232 (13)0.0015 (10)0.0038 (11)0.0026 (11)
C80.0202 (14)0.0170 (13)0.0212 (13)0.0010 (10)0.0068 (11)0.0008 (10)
C90.0246 (15)0.0223 (15)0.0292 (15)0.0018 (11)0.0051 (12)0.0002 (11)
C100.0229 (14)0.0136 (13)0.0184 (13)0.0004 (10)0.0097 (11)0.0024 (10)
C110.0240 (14)0.0171 (13)0.0180 (13)0.0028 (10)0.0084 (11)0.0057 (10)
C120.0229 (15)0.0343 (16)0.0213 (14)0.0023 (12)0.0077 (11)0.0063 (12)
C130.0247 (16)0.0420 (18)0.0254 (14)0.0014 (12)0.0137 (12)0.0018 (13)
C140.0216 (15)0.0319 (17)0.0302 (15)0.0012 (12)0.0084 (12)0.0078 (12)
C150.0261 (16)0.0210 (15)0.0276 (15)0.0031 (11)0.0043 (12)0.0006 (12)
C160.0269 (15)0.0181 (14)0.0220 (13)0.0027 (11)0.0105 (11)0.0014 (11)
C170.0301 (18)0.053 (2)0.0452 (19)0.0069 (14)0.0141 (14)0.0032 (16)
C180.0156 (13)0.0216 (14)0.0197 (13)0.0011 (10)0.0049 (11)0.0010 (11)
C190.0261 (15)0.0235 (14)0.0230 (14)0.0011 (11)0.0106 (11)0.0001 (11)
C200.0217 (15)0.0219 (15)0.0262 (14)0.0024 (11)0.0054 (11)0.0054 (11)
C250.0203 (16)0.0345 (17)0.0369 (16)0.0025 (12)0.0038 (12)0.0026 (13)
C240.0216 (16)0.048 (2)0.0469 (18)0.0104 (13)0.0104 (14)0.0032 (15)
C230.0309 (17)0.0303 (17)0.0394 (17)0.0119 (13)0.0113 (13)0.0002 (13)
C220.0300 (17)0.0201 (15)0.0402 (17)0.0031 (12)0.0077 (13)0.0020 (13)
C210.0210 (14)0.0211 (15)0.0342 (15)0.0039 (11)0.0080 (12)0.0035 (12)
C260.0228 (15)0.0202 (14)0.0246 (14)0.0021 (11)0.0031 (12)0.0056 (11)
C270.0194 (14)0.0210 (14)0.0227 (13)0.0032 (10)0.0058 (11)0.0038 (11)
C280.0282 (16)0.0306 (16)0.0306 (15)0.0052 (12)0.0078 (12)0.0016 (13)
C290.0185 (14)0.0208 (14)0.0181 (13)0.0013 (10)0.0045 (11)0.0049 (11)
C300.0114 (13)0.0240 (14)0.0175 (13)0.0029 (10)0.0016 (10)0.0004 (11)
C310.0254 (15)0.0196 (14)0.0220 (13)0.0021 (11)0.0080 (11)0.0053 (11)
C320.0264 (15)0.0161 (14)0.0316 (15)0.0027 (11)0.0066 (12)0.0004 (11)
C330.0197 (14)0.0290 (15)0.0229 (14)0.0006 (11)0.0065 (11)0.0026 (12)
C340.0213 (15)0.0314 (16)0.0218 (14)0.0016 (11)0.0079 (11)0.0048 (12)
C350.0181 (14)0.0186 (14)0.0260 (14)0.0009 (10)0.0069 (11)0.0046 (11)
C360.0430 (19)0.0395 (18)0.0377 (17)0.0049 (14)0.0184 (15)0.0031 (14)
C370.0288 (15)0.0184 (14)0.0257 (14)0.0007 (11)0.0172 (12)0.0014 (11)
C380.0279 (16)0.0264 (16)0.0347 (15)0.0071 (12)0.0180 (13)0.0004 (12)
Geometric parameters (Å, º) top
O1—C71.224 (3)C18—O21.242 (3)
O2—C181.242 (3)C18—C191.497 (3)
O3—C261.218 (3)C19—H19A0.96
O4—C371.237 (3)C19—H19B0.96
N1—C181.337 (3)C19—H19C0.96
N1—C101.458 (3)C20—C251.393 (3)
N1—H1A0.86C20—C211.395 (3)
N2—C371.338 (3)C20—C261.498 (3)
N2—C291.468 (3)C25—C241.382 (4)
N2—H2A0.86C25—H250.93
C1—C61.388 (3)C24—C231.382 (4)
C1—C21.395 (3)C24—H240.93
C1—C71.498 (3)C23—C221.376 (4)
C2—C31.387 (3)C23—H230.93
C2—H20.93C22—C211.385 (4)
C3—C41.376 (4)C22—H220.93
C3—H30.93C21—H210.93
C4—C51.381 (4)C26—C271.526 (3)
C4—H40.93C27—C291.528 (3)
C5—C61.384 (3)C27—C281.530 (3)
C5—H50.93C27—H270.98
C6—H60.93C28—H28A0.96
C7—C81.517 (3)C28—H28B0.96
C8—C91.525 (3)C28—H28C0.96
C8—C101.538 (3)C29—C301.524 (3)
C8—H80.98C29—H290.98
C9—H9A0.96C30—C351.387 (3)
C9—H9B0.96C30—C311.388 (3)
C9—H9C0.96C31—C321.384 (3)
C10—C111.521 (3)C31—H310.93
C10—H100.98C32—C331.389 (3)
C11—C161.385 (3)C32—H320.93
C11—C121.391 (3)C33—C341.386 (3)
C12—C131.383 (3)C33—C361.507 (3)
C12—H120.93C34—C351.381 (3)
C13—C141.388 (4)C34—H340.93
C13—H130.93C35—H350.93
C14—C151.386 (4)C36—H36A0.96
C14—C171.503 (4)C36—H36B0.96
C15—C161.388 (3)C36—H36C0.96
C15—H150.93C37—C381.498 (3)
C16—H160.93C38—H38A0.96
C17—H17A0.96C38—H38B0.96
C17—H17B0.96C38—H38C0.96
C17—H17C0.96
C18—N1—C10124.58 (19)H19A—C19—H19B109.5
C18—N1—H1A117.7C18—C19—H19C109.5
C10—N1—H1A117.7H19A—C19—H19C109.5
C37—N2—C29123.2 (2)H19B—C19—H19C109.5
C37—N2—H2A118.4C25—C20—C21118.7 (2)
C29—N2—H2A118.4C25—C20—C26118.5 (2)
C6—C1—C2118.9 (2)C21—C20—C26122.7 (2)
C6—C1—C7118.1 (2)C24—C25—C20120.4 (3)
C2—C1—C7123.0 (2)C24—C25—H25119.8
C3—C2—C1120.0 (2)C20—C25—H25119.8
C3—C2—H2120.0C25—C24—C23120.2 (3)
C1—C2—H2120.0C25—C24—H24119.9
C4—C3—C2120.4 (3)C23—C24—H24119.9
C4—C3—H3119.8C22—C23—C24120.0 (3)
C2—C3—H3119.8C22—C23—H23120.0
C3—C4—C5120.0 (2)C24—C23—H23120.0
C3—C4—H4120.0C23—C22—C21120.2 (3)
C5—C4—H4120.0C23—C22—H22119.9
C4—C5—C6119.9 (2)C21—C22—H22119.9
C4—C5—H5120.0C22—C21—C20120.4 (2)
C6—C5—H5120.0C22—C21—H21119.8
C5—C6—C1120.7 (2)C20—C21—H21119.8
C5—C6—H6119.6O3—C26—C20120.7 (2)
C1—C6—H6119.6O3—C26—C27119.7 (2)
O1—C7—C1119.9 (2)C20—C26—C27119.6 (2)
O1—C7—C8118.7 (2)C26—C27—C29110.51 (19)
C1—C7—C8121.3 (2)C26—C27—C28107.8 (2)
C7—C8—C9108.89 (19)C29—C27—C28111.2 (2)
C7—C8—C10109.32 (19)C26—C27—H27109.1
C9—C8—C10112.59 (19)C29—C27—H27109.1
C7—C8—H8108.7C28—C27—H27109.1
C9—C8—H8108.7C27—C28—H28A109.5
C10—C8—H8108.7C27—C28—H28B109.5
C8—C9—H9A109.5H28A—C28—H28B109.5
C8—C9—H9B109.5C27—C28—H28C109.5
H9A—C9—H9B109.5H28A—C28—H28C109.5
C8—C9—H9C109.5H28B—C28—H28C109.5
H9A—C9—H9C109.5N2—C29—C30106.90 (18)
H9B—C9—H9C109.5N2—C29—C27109.07 (18)
N1—C10—C11110.65 (18)C30—C29—C27115.91 (19)
N1—C10—C8109.12 (18)N2—C29—H29108.2
C11—C10—C8113.27 (19)C30—C29—H29108.2
N1—C10—H10107.9C27—C29—H29108.2
C11—C10—H10107.9C35—C30—C31117.8 (2)
C8—C10—H10107.9C35—C30—C29122.8 (2)
C16—C11—C12117.8 (2)C31—C30—C29119.2 (2)
C16—C11—C10121.2 (2)C32—C31—C30120.9 (2)
C12—C11—C10120.9 (2)C32—C31—H31119.5
C13—C12—C11120.9 (2)C30—C31—H31119.5
C13—C12—H12119.6C31—C32—C33121.5 (2)
C11—C12—H12119.6C31—C32—H32119.3
C12—C13—C14121.7 (2)C33—C32—H32119.3
C12—C13—H13119.2C34—C33—C32117.1 (2)
C14—C13—H13119.2C34—C33—C36121.3 (2)
C15—C14—C13117.2 (2)C32—C33—C36121.7 (2)
C15—C14—C17121.2 (3)C35—C34—C33121.8 (2)
C13—C14—C17121.6 (2)C35—C34—H34119.1
C14—C15—C16121.6 (2)C33—C34—H34119.1
C14—C15—H15119.2C34—C35—C30120.9 (2)
C16—C15—H15119.2C34—C35—H35119.6
C11—C16—C15120.9 (2)C30—C35—H35119.6
C11—C16—H16119.5C33—C36—H36A109.5
C15—C16—H16119.5C33—C36—H36B109.5
C14—C17—H17A109.5H36A—C36—H36B109.5
C14—C17—H17B109.5C33—C36—H36C109.5
H17A—C17—H17B109.5H36A—C36—H36C109.5
C14—C17—H17C109.5H36B—C36—H36C109.5
H17A—C17—H17C109.5O4—C37—N2122.3 (2)
H17B—C17—H17C109.5O4—C37—C38122.3 (2)
O2—C18—N1123.0 (2)N2—C37—C38115.4 (2)
O2—C18—N1123.0 (2)C37—C38—H38A109.5
O2—C18—C19121.7 (2)C37—C38—H38B109.5
O2—C18—C19121.7 (2)H38A—C38—H38B109.5
N1—C18—C19115.3 (2)C37—C38—H38C109.5
C18—C19—H19A109.5H38A—C38—H38C109.5
C18—C19—H19B109.5H38B—C38—H38C109.5
C6—C1—C2—C30.5 (4)C10—N1—C18—C19178.5 (2)
C7—C1—C2—C3179.7 (2)C21—C20—C25—C240.1 (4)
C1—C2—C3—C40.2 (4)C26—C20—C25—C24178.7 (2)
C2—C3—C4—C51.0 (4)C20—C25—C24—C230.1 (4)
C3—C4—C5—C61.0 (4)C25—C24—C23—C220.4 (4)
C4—C5—C6—C10.3 (4)C24—C23—C22—C210.8 (4)
C2—C1—C6—C50.5 (3)C23—C22—C21—C200.9 (4)
C7—C1—C6—C5179.8 (2)C25—C20—C21—C220.4 (4)
C6—C1—C7—O15.2 (3)C26—C20—C21—C22179.2 (2)
C2—C1—C7—O1174.5 (2)C25—C20—C26—O312.4 (4)
C6—C1—C7—C8172.3 (2)C21—C20—C26—O3166.4 (2)
C2—C1—C7—C88.0 (3)C25—C20—C26—C27169.8 (2)
O1—C7—C8—C969.0 (3)C21—C20—C26—C2711.5 (3)
C1—C7—C8—C9108.5 (2)O3—C26—C27—C2940.8 (3)
O1—C7—C8—C1054.4 (3)C20—C26—C27—C29141.3 (2)
C1—C7—C8—C10128.1 (2)O3—C26—C27—C2880.9 (3)
C18—N1—C10—C11108.4 (2)C20—C26—C27—C2897.0 (3)
C18—N1—C10—C8126.3 (2)C37—N2—C29—C30101.4 (2)
C7—C8—C10—N1179.21 (18)C37—N2—C29—C27132.6 (2)
C9—C8—C10—N158.1 (3)C26—C27—C29—N2174.28 (18)
C7—C8—C10—C1157.0 (3)C28—C27—C29—N266.1 (2)
C9—C8—C10—C11178.20 (19)C26—C27—C29—C3053.6 (3)
N1—C10—C11—C16105.7 (2)C28—C27—C29—C30173.3 (2)
C8—C10—C11—C16131.4 (2)N2—C29—C30—C3591.7 (2)
N1—C10—C11—C1272.2 (3)C27—C29—C30—C3530.1 (3)
C8—C10—C11—C1250.7 (3)N2—C29—C30—C3182.3 (2)
C16—C11—C12—C130.6 (4)C27—C29—C30—C31155.9 (2)
C10—C11—C12—C13177.3 (2)C35—C30—C31—C321.4 (3)
C11—C12—C13—C140.1 (4)C29—C30—C31—C32172.9 (2)
C12—C13—C14—C150.3 (4)C30—C31—C32—C330.1 (4)
C12—C13—C14—C17179.3 (2)C31—C32—C33—C341.3 (4)
C13—C14—C15—C160.0 (4)C31—C32—C33—C36178.8 (2)
C17—C14—C15—C16179.5 (2)C32—C33—C34—C351.3 (4)
C12—C11—C16—C150.9 (3)C36—C33—C34—C35178.7 (2)
C10—C11—C16—C15177.0 (2)C33—C34—C35—C300.1 (4)
C14—C15—C16—C110.6 (4)C31—C30—C35—C341.3 (3)
O2—O2—C18—N10.0 (2)C29—C30—C35—C34172.8 (2)
O2—O2—C18—C190.0 (3)C29—N2—C37—O49.8 (4)
C10—N1—C18—O21.0 (4)C29—N2—C37—C38168.1 (2)
C10—N1—C18—O21.0 (4)
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
N2—H2A···O20.862.152.902 (3)145
N1—H1A···O4i0.861.962.818 (3)175
C5—H5···O2ii0.932.473.354 (3)160
C34—H34···Cg1i0.932.753.564 (3)146
Symmetry codes: (i) x, y+3/2, z+1/2; (ii) x, y+1/2, z+1/2.
 

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