Acta Cryst. (2006). E62, m2041-m2042  [ doi:10.1107/S1600536806029424 ]

Iodo(1,10-phenanthroline)bis(pyrrolidine-1-dithiocarboxylato-²S,S')bismuth(III)

F. Li, H.-D. Yin, J. Zhai and D. Wang

Abstract: The title compound, [Bi(C₄H₈NS₂)₂I(C₁₂H₈N₂)], is monomeric, with the Bi atom chelated by the S atoms of two pyrrolidine-1-dithiocarboxylate ligands and both N atoms of one 1,10-phenanthroline ligand. An iodide ligand completes the coordination, with the seven-coordinate Bi atom adopting a highly distorted capped octahedral geometry.

Online 4 August 2006

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