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In the title compound, [Eu(C8H6NO2)3(H2O)]n, the europium(III) ion is coordinated by eight carboxyl­ate O atoms and one water mol­ecule. The carboxyl­ate ligands bridge pairs of europium(III) ions, forming a zigzag chain along [100]; hydrogen bonds link the chains into sheets parallel to (001).

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806033459/gd2004sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536806033459/gd2004Isup2.hkl
Contains datablock I

CCDC reference: 621315

Key indicators

  • Single-crystal X-ray study
  • T = 291 K
  • Mean [sigma](C-C) = 0.004 Å
  • R factor = 0.023
  • wR factor = 0.048
  • Data-to-parameter ratio = 16.1

checkCIF/PLATON results

No syntax errors found



Datablock: a


Alert level C PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 2.87 Ratio PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for O4 PLAT764_ALERT_4_C Overcomplete CIF Bond List Detected (Rep/Expd) . 1.12 Ratio
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 3 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 2 ALERT type 2 Indicator that the structure model may be wrong or deficient 0 ALERT type 3 Indicator that the structure quality may be low 1 ALERT type 4 Improvement, methodology, query or suggestion 0 ALERT type 5 Informative message, check

Computing details top

Data collection: Bruker SMART; cell refinement: Bruker SMART; data reduction: Bruker SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: Bruker SHELXTL; software used to prepare material for publication: Bruker SHELXTL.

catena-Poly[aquatris{3-(3-pyridyl)acrylato}europium(III)] top
Crystal data top
[Eu(C8H6NO2)3(H2O)]Z = 2
Mr = 614.39F(000) = 608
Triclinic, P1Dx = 1.761 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 6.2459 (6) ÅCell parameters from 5087 reflections
b = 12.7698 (13) Åθ = 2.6–28.2°
c = 15.7220 (16) ŵ = 2.76 mm1
α = 111.771 (1)°T = 291 K
β = 90.320 (1)°Block, colourless
γ = 95.176 (1)°0.15 × 0.09 × 0.08 mm
V = 1158.7 (2) Å3
Data collection top
Bruker SMART CCD area-detector
diffractometer
5207 independent reflections
Radiation source: fine-focus sealed tube4755 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.021
φ and ω scansθmax = 27.5°, θmin = 2.6°
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)
h = 88
Tmin = 0.675, Tmax = 0.799k = 1616
10024 measured reflectionsl = 2020
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.023Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.048H-atom parameters constrained
S = 1.04 w = 1/[σ2(Fo2) + (0.0184P)2 + 0.2729P]
where P = (Fo2 + 2Fc2)/3
5207 reflections(Δ/σ)max = 0.002
324 parametersΔρmax = 0.43 e Å3
3 restraintsΔρmin = 0.50 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Eu10.256162 (19)0.527915 (10)0.424404 (9)0.01656 (4)
O10.4225 (3)0.72589 (15)0.48097 (14)0.0303 (5)
O20.5881 (3)0.61313 (14)0.53080 (12)0.0205 (4)
O30.5669 (3)0.49362 (16)0.32821 (12)0.0257 (4)
O40.3039 (3)0.55930 (18)0.27587 (14)0.0362 (5)
O50.0919 (3)0.35461 (16)0.30267 (12)0.0280 (4)
O60.0959 (3)0.40896 (14)0.42706 (11)0.0215 (4)
O70.0410 (3)0.61597 (17)0.39769 (14)0.0258 (4)
N11.0455 (4)1.1950 (2)0.64432 (18)0.0383 (6)
N21.1786 (5)0.3164 (3)0.0103 (2)0.0513 (8)
N30.7910 (4)0.0325 (3)0.1272 (2)0.0581 (9)
C11.2331 (5)1.1776 (3)0.6748 (2)0.0387 (8)
H11.34091.23750.69520.046*
C21.2745 (5)1.0750 (3)0.6775 (2)0.0457 (9)
H21.40621.06640.70070.055*
C31.1166 (5)0.9846 (3)0.6450 (3)0.0458 (9)
H31.14270.91410.64490.055*
C40.9190 (5)0.9996 (2)0.6123 (2)0.0287 (6)
C50.8930 (5)1.1073 (2)0.6137 (2)0.0340 (7)
H50.76211.11910.59210.041*
C60.7472 (4)0.9066 (2)0.5731 (2)0.0286 (6)
H60.62590.92290.54760.034*
C70.7488 (5)0.8023 (2)0.5706 (2)0.0299 (6)
H70.86450.78550.59910.036*
C80.5764 (4)0.7104 (2)0.52467 (18)0.0211 (5)
C91.0899 (6)0.3163 (3)0.0867 (2)0.0528 (10)
H91.16870.29190.13930.063*
C100.8883 (6)0.3498 (3)0.0942 (2)0.0471 (9)
H100.83380.34780.15010.057*
C110.7706 (5)0.3864 (3)0.0165 (2)0.0380 (7)
H110.63360.40840.01920.046*
C120.8590 (5)0.3900 (2)0.06622 (19)0.0283 (6)
C131.0622 (5)0.3522 (3)0.0646 (2)0.0388 (7)
H131.12060.35170.11900.047*
C140.7547 (4)0.4311 (2)0.15433 (19)0.0285 (6)
H140.82400.42200.20330.034*
C150.5721 (5)0.4801 (3)0.17227 (19)0.0312 (7)
H150.50160.49370.12570.037*
C160.4768 (4)0.5138 (2)0.26333 (18)0.0241 (6)
C170.7387 (6)0.0704 (3)0.0735 (3)0.0581 (11)
H170.84970.12490.04190.070*
C180.5319 (5)0.1003 (3)0.0621 (2)0.0497 (9)
H180.50430.17320.02490.060*
C190.3653 (5)0.0186 (3)0.1077 (2)0.0387 (8)
H190.22320.03530.09990.046*
C200.4127 (4)0.0885 (2)0.16509 (19)0.0286 (6)
C210.6275 (5)0.1092 (3)0.1715 (2)0.0446 (9)
H210.65990.18110.20910.054*
C220.2391 (4)0.1756 (2)0.21582 (19)0.0279 (6)
H220.10350.16980.19130.033*
C230.2608 (4)0.2616 (2)0.29356 (18)0.0234 (6)
H230.39590.26970.31830.028*
C240.0794 (4)0.3451 (2)0.34256 (17)0.0202 (5)
H1W0.154 (4)0.576 (2)0.377 (2)0.038 (10)*
H2W0.037 (5)0.669 (2)0.378 (2)0.061 (12)*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Eu10.01391 (7)0.01709 (7)0.01833 (7)0.00044 (4)0.00006 (4)0.00647 (5)
O10.0282 (11)0.0234 (10)0.0420 (12)0.0022 (8)0.0101 (9)0.0165 (9)
O20.0209 (9)0.0156 (9)0.0245 (10)0.0010 (7)0.0019 (7)0.0078 (7)
O30.0203 (9)0.0357 (11)0.0232 (10)0.0018 (8)0.0024 (8)0.0139 (9)
O40.0276 (11)0.0556 (14)0.0346 (12)0.0166 (10)0.0071 (9)0.0245 (11)
O50.0233 (10)0.0302 (11)0.0226 (10)0.0024 (8)0.0022 (8)0.0019 (8)
O60.0232 (9)0.0210 (9)0.0171 (9)0.0003 (7)0.0001 (7)0.0040 (7)
O70.0178 (10)0.0252 (11)0.0399 (12)0.0023 (8)0.0003 (8)0.0186 (10)
N10.0465 (16)0.0209 (13)0.0462 (16)0.0050 (11)0.0004 (13)0.0130 (12)
N20.0394 (17)0.057 (2)0.0477 (18)0.0121 (14)0.0140 (14)0.0066 (15)
N30.0251 (15)0.0514 (19)0.067 (2)0.0038 (13)0.0032 (14)0.0120 (16)
C10.0437 (19)0.0293 (17)0.0388 (18)0.0125 (14)0.0041 (15)0.0117 (14)
C20.0381 (19)0.042 (2)0.061 (2)0.0091 (15)0.0185 (17)0.0271 (18)
C30.047 (2)0.0285 (17)0.067 (2)0.0066 (15)0.0190 (18)0.0262 (17)
C40.0329 (16)0.0207 (14)0.0336 (16)0.0029 (12)0.0042 (13)0.0125 (12)
C50.0344 (17)0.0245 (15)0.0427 (18)0.0001 (13)0.0033 (14)0.0128 (14)
C60.0254 (15)0.0235 (14)0.0368 (17)0.0000 (11)0.0055 (12)0.0119 (13)
C70.0278 (15)0.0229 (14)0.0384 (17)0.0039 (12)0.0098 (13)0.0124 (13)
C80.0191 (13)0.0200 (13)0.0247 (14)0.0013 (10)0.0023 (10)0.0088 (11)
C90.058 (2)0.053 (2)0.037 (2)0.0021 (19)0.0223 (18)0.0041 (17)
C100.063 (2)0.050 (2)0.0247 (17)0.0021 (18)0.0096 (16)0.0104 (15)
C110.0393 (18)0.0455 (19)0.0301 (17)0.0064 (15)0.0060 (14)0.0146 (15)
C120.0300 (15)0.0266 (15)0.0255 (15)0.0010 (12)0.0059 (12)0.0073 (12)
C130.0327 (17)0.0409 (19)0.0364 (18)0.0052 (14)0.0035 (14)0.0065 (15)
C140.0292 (15)0.0315 (16)0.0270 (15)0.0013 (12)0.0009 (12)0.0139 (13)
C150.0305 (16)0.0428 (18)0.0224 (15)0.0047 (13)0.0011 (12)0.0145 (13)
C160.0230 (14)0.0287 (15)0.0217 (14)0.0020 (11)0.0006 (11)0.0119 (12)
C170.041 (2)0.042 (2)0.062 (3)0.0158 (17)0.0021 (18)0.0096 (18)
C180.043 (2)0.0271 (17)0.058 (2)0.0007 (15)0.0008 (17)0.0082 (16)
C190.0298 (16)0.0308 (17)0.0429 (19)0.0038 (13)0.0005 (14)0.0013 (14)
C200.0249 (14)0.0256 (15)0.0288 (15)0.0011 (12)0.0005 (12)0.0030 (12)
C210.0295 (17)0.0364 (18)0.047 (2)0.0050 (14)0.0050 (15)0.0089 (15)
C220.0215 (14)0.0268 (15)0.0285 (15)0.0002 (11)0.0020 (11)0.0029 (12)
C230.0189 (13)0.0251 (14)0.0239 (14)0.0009 (11)0.0017 (11)0.0072 (11)
C240.0223 (13)0.0176 (13)0.0197 (13)0.0029 (10)0.0026 (10)0.0056 (10)
Geometric parameters (Å, º) top
Eu1—O72.3673 (18)C4—C51.392 (4)
Eu1—O6i2.4251 (17)C4—C61.470 (4)
Eu1—O2ii2.4362 (17)C5—H50.9300
Eu1—O32.4375 (18)C6—C71.319 (4)
Eu1—O52.4576 (18)C6—H60.9300
Eu1—O12.4718 (18)C7—C81.481 (4)
Eu1—O42.527 (2)C7—H70.9300
Eu1—O22.5467 (17)C9—C101.385 (5)
Eu1—O62.5670 (17)C9—H90.9300
Eu1—C162.844 (3)C10—C111.379 (4)
Eu1—C82.884 (3)C10—H100.9300
Eu1—C242.891 (3)C11—C121.393 (4)
O1—C81.250 (3)C11—H110.9300
O2—C81.290 (3)C12—C131.395 (4)
O2—Eu1ii2.4363 (17)C12—C141.467 (4)
O3—C161.280 (3)C13—H130.9300
O4—C161.254 (3)C14—C151.331 (4)
O5—C241.262 (3)C14—H140.9300
O6—C241.286 (3)C15—C161.479 (4)
O6—Eu1i2.4252 (17)C15—H150.9300
O7—H1W0.821 (17)C17—C181.373 (5)
O7—H2W0.840 (17)C17—H170.9300
N1—C11.331 (4)C18—C191.388 (4)
N1—C51.340 (4)C18—H180.9300
N2—C91.319 (5)C19—C201.389 (4)
N2—C131.339 (4)C19—H190.9300
N3—C211.339 (4)C20—C211.388 (4)
N3—C171.343 (4)C20—C221.471 (4)
C1—C21.374 (4)C21—H210.9300
C1—H10.9300C22—C231.323 (4)
C2—C31.385 (4)C22—H220.9300
C2—H20.9300C23—C241.475 (3)
C3—C41.389 (4)C23—H230.9300
C3—H30.9300
O7—Eu1—O6i78.00 (6)N1—C1—C2122.9 (3)
O7—Eu1—O2ii151.98 (6)N1—C1—H1118.5
O6i—Eu1—O2ii86.83 (6)C2—C1—H1118.5
O7—Eu1—O3123.43 (7)C1—C2—C3118.8 (3)
O6i—Eu1—O3151.83 (6)C1—C2—H2120.6
O2ii—Eu1—O379.62 (6)C3—C2—H2120.6
O7—Eu1—O586.21 (7)C2—C3—C4119.9 (3)
O6i—Eu1—O5118.67 (6)C2—C3—H3120.1
O2ii—Eu1—O580.56 (6)C4—C3—H3120.1
O3—Eu1—O583.49 (6)C3—C4—C5116.7 (3)
O7—Eu1—O181.22 (7)C3—C4—C6122.9 (3)
O6i—Eu1—O182.68 (6)C5—C4—C6120.3 (3)
O2ii—Eu1—O1120.38 (6)N1—C5—C4123.9 (3)
O3—Eu1—O183.09 (6)N1—C5—H5118.1
O5—Eu1—O1152.35 (7)C4—C5—H5118.1
O7—Eu1—O471.20 (6)C7—C6—C4126.2 (3)
O6i—Eu1—O4146.02 (6)C7—C6—H6116.9
O2ii—Eu1—O4127.14 (6)C4—C6—H6116.9
O3—Eu1—O452.49 (6)C6—C7—C8123.5 (3)
O5—Eu1—O473.82 (7)C6—C7—H7118.2
O1—Eu1—O478.83 (7)C8—C7—H7118.2
O7—Eu1—O2129.83 (6)O1—C8—O2120.3 (2)
O6i—Eu1—O278.85 (6)O1—C8—C7121.3 (2)
O2ii—Eu1—O268.32 (6)O2—C8—C7118.3 (2)
O3—Eu1—O273.23 (6)O1—C8—Eu158.49 (13)
O5—Eu1—O2143.72 (6)O2—C8—Eu161.99 (13)
O1—Eu1—O252.06 (6)C7—C8—Eu1176.22 (19)
O4—Eu1—O2110.35 (6)N2—C9—C10124.8 (3)
O7—Eu1—O670.13 (6)N2—C9—H9117.6
O6i—Eu1—O667.03 (6)C10—C9—H9117.6
O2ii—Eu1—O682.32 (6)C11—C10—C9118.0 (3)
O3—Eu1—O6134.06 (6)C11—C10—H10121.0
O5—Eu1—O651.92 (6)C9—C10—H10121.0
O1—Eu1—O6141.58 (6)C10—C11—C12119.3 (3)
O4—Eu1—O6113.56 (6)C10—C11—H11120.3
O2—Eu1—O6135.93 (5)C12—C11—H11120.3
O7—Eu1—C1697.34 (7)C11—C12—C13117.2 (3)
O6i—Eu1—C16165.37 (7)C11—C12—C14124.8 (3)
O2ii—Eu1—C16102.64 (7)C13—C12—C14118.0 (3)
O3—Eu1—C1626.66 (7)N2—C13—C12124.2 (3)
O5—Eu1—C1674.37 (7)N2—C13—H13117.9
O1—Eu1—C1682.90 (7)C12—C13—H13117.9
O4—Eu1—C1626.15 (7)C15—C14—C12127.4 (3)
O2—Eu1—C1694.17 (7)C15—C14—H14116.3
O6—Eu1—C16124.78 (7)C12—C14—H14116.3
O7—Eu1—C8105.64 (7)C14—C15—C16122.7 (3)
O6i—Eu1—C880.82 (6)C14—C15—H15118.7
O2ii—Eu1—C894.85 (7)C16—C15—H15118.7
O3—Eu1—C875.91 (7)O4—C16—O3120.2 (2)
O5—Eu1—C8159.39 (7)O4—C16—C15119.7 (2)
O1—Eu1—C825.54 (6)O3—C16—C15120.1 (2)
O4—Eu1—C893.76 (7)O4—C16—Eu162.64 (14)
O2—Eu1—C826.55 (6)O3—C16—Eu158.67 (13)
O6—Eu1—C8147.82 (6)C15—C16—Eu1167.40 (19)
C16—Eu1—C887.22 (7)N3—C17—C18124.3 (3)
O7—Eu1—C2474.91 (7)N3—C17—H17117.9
O6i—Eu1—C2493.43 (7)C18—C17—H17117.9
O2ii—Eu1—C2482.74 (6)C17—C18—C19118.1 (3)
O3—Eu1—C24109.02 (7)C17—C18—H18121.0
O5—Eu1—C2425.70 (6)C19—C18—H18121.0
O1—Eu1—C24156.09 (7)C18—C19—C20119.4 (3)
O4—Eu1—C2492.15 (7)C18—C19—H19120.3
O2—Eu1—C24150.28 (6)C20—C19—H19120.3
O6—Eu1—C2426.40 (6)C21—C20—C19117.5 (3)
C16—Eu1—C2498.76 (7)C21—C20—C22122.1 (3)
C8—Eu1—C24173.90 (7)C19—C20—C22120.4 (3)
C8—O1—Eu195.97 (15)N3—C21—C20124.3 (3)
C8—O2—Eu1ii156.71 (16)N3—C21—H21117.9
C8—O2—Eu191.45 (14)C20—C21—H21117.9
Eu1ii—O2—Eu1111.68 (6)C23—C22—C20125.1 (3)
C16—O3—Eu194.68 (15)C23—C22—H22117.4
C16—O4—Eu191.21 (16)C20—C22—H22117.4
C24—O5—Eu196.71 (15)C22—C23—C24122.7 (3)
C24—O6—Eu1i156.01 (17)C22—C23—H23118.6
C24—O6—Eu191.00 (15)C24—C23—H23118.6
Eu1i—O6—Eu1112.97 (6)O5—C24—O6119.5 (2)
Eu1—O7—H1W118 (2)O5—C24—C23120.9 (2)
Eu1—O7—H2W127 (2)O6—C24—C23119.6 (2)
H1W—O7—H2W106 (2)O5—C24—Eu157.59 (13)
C1—N1—C5117.9 (3)O6—C24—Eu162.59 (13)
C9—N2—C13116.4 (3)C23—C24—Eu1171.82 (18)
C21—N3—C17116.4 (3)
O7—Eu1—O1—C8162.92 (17)O2ii—Eu1—C8—O1178.22 (16)
O6i—Eu1—O1—C884.01 (16)O3—Eu1—C8—O1103.76 (16)
O2ii—Eu1—O1—C82.05 (18)O5—Eu1—C8—O1105.8 (2)
O3—Eu1—O1—C871.61 (16)O4—Eu1—C8—O153.98 (16)
O5—Eu1—O1—C8133.12 (17)O2—Eu1—C8—O1175.6 (3)
O4—Eu1—O1—C8124.65 (17)O6—Eu1—C8—O194.95 (19)
O2—Eu1—O1—C82.48 (14)C16—Eu1—C8—O179.31 (16)
O6—Eu1—O1—C8121.36 (16)O7—Eu1—C8—O2158.09 (13)
C16—Eu1—O1—C898.47 (17)O6i—Eu1—C8—O283.39 (14)
C24—Eu1—O1—C8165.92 (17)O2ii—Eu1—C8—O22.60 (16)
O7—Eu1—O2—C827.90 (17)O3—Eu1—C8—O280.61 (14)
O6i—Eu1—O2—C891.77 (14)O5—Eu1—C8—O278.6 (2)
O2ii—Eu1—O2—C8177.22 (18)O1—Eu1—C8—O2175.6 (3)
O3—Eu1—O2—C891.96 (14)O4—Eu1—C8—O2130.39 (14)
O5—Eu1—O2—C8144.32 (14)O6—Eu1—C8—O280.67 (18)
O1—Eu1—O2—C82.39 (14)C16—Eu1—C8—O2105.06 (14)
O4—Eu1—O2—C854.15 (15)C13—N2—C9—C100.1 (6)
O6—Eu1—O2—C8130.92 (14)N2—C9—C10—C110.1 (6)
C16—Eu1—O2—C875.26 (15)C9—C10—C11—C121.0 (5)
C24—Eu1—O2—C8168.92 (15)C10—C11—C12—C132.1 (5)
O7—Eu1—O2—Eu1ii154.88 (7)C10—C11—C12—C14177.5 (3)
O6i—Eu1—O2—Eu1ii91.01 (7)C9—N2—C13—C121.1 (5)
O2ii—Eu1—O2—Eu1ii0.002 (1)C11—C12—C13—N22.2 (5)
O3—Eu1—O2—Eu1ii85.26 (7)C14—C12—C13—N2177.5 (3)
O5—Eu1—O2—Eu1ii32.89 (13)C11—C12—C14—C156.3 (5)
O1—Eu1—O2—Eu1ii179.61 (11)C13—C12—C14—C15173.3 (3)
O4—Eu1—O2—Eu1ii123.06 (7)C12—C14—C15—C16177.2 (3)
O6—Eu1—O2—Eu1ii51.86 (10)Eu1—O4—C16—O312.0 (3)
C16—Eu1—O2—Eu1ii101.96 (8)Eu1—O4—C16—C15165.9 (2)
C8—Eu1—O2—Eu1ii177.22 (18)Eu1—O3—C16—O412.5 (3)
C24—Eu1—O2—Eu1ii13.86 (16)Eu1—O3—C16—C15165.4 (2)
O7—Eu1—O3—C1613.24 (18)C14—C15—C16—O4179.8 (3)
O6i—Eu1—O3—C16148.06 (15)C14—C15—C16—O31.8 (4)
O2ii—Eu1—O3—C16149.39 (16)C14—C15—C16—Eu182.7 (9)
O5—Eu1—O3—C1667.84 (16)O7—Eu1—C16—O41.06 (17)
O1—Eu1—O3—C1687.92 (16)O6i—Eu1—C16—O469.3 (3)
O4—Eu1—O3—C166.73 (15)O2ii—Eu1—C16—O4161.29 (16)
O2—Eu1—O3—C16140.30 (16)O3—Eu1—C16—O4167.8 (3)
O6—Eu1—O3—C1680.88 (17)O5—Eu1—C16—O485.02 (17)
C8—Eu1—O3—C16112.87 (16)O1—Eu1—C16—O479.08 (17)
C24—Eu1—O3—C1670.87 (16)O2—Eu1—C16—O4130.01 (16)
O7—Eu1—O4—C16178.89 (18)O6—Eu1—C16—O471.93 (18)
O6i—Eu1—O4—C16155.00 (15)C8—Eu1—C16—O4104.36 (17)
O2ii—Eu1—O4—C1623.12 (19)C24—Eu1—C16—O476.83 (17)
O3—Eu1—O4—C166.85 (15)O7—Eu1—C16—O3168.89 (15)
O5—Eu1—O4—C1687.40 (17)O6i—Eu1—C16—O398.5 (3)
O1—Eu1—O4—C1696.69 (17)O2ii—Eu1—C16—O330.88 (16)
O2—Eu1—O4—C1654.57 (18)O5—Eu1—C16—O3107.16 (16)
O6—Eu1—O4—C16121.58 (16)O1—Eu1—C16—O388.74 (15)
C8—Eu1—O4—C1675.86 (17)O4—Eu1—C16—O3167.8 (3)
C24—Eu1—O4—C16105.63 (17)O2—Eu1—C16—O337.82 (16)
O7—Eu1—O5—C2462.35 (15)O6—Eu1—C16—O3120.25 (15)
O6i—Eu1—O5—C2411.76 (17)C8—Eu1—C16—O363.47 (16)
O2ii—Eu1—O5—C2492.86 (15)C24—Eu1—C16—O3115.34 (15)
O3—Eu1—O5—C24173.37 (16)O7—Eu1—C16—C15102.7 (9)
O1—Eu1—O5—C24125.21 (17)O6i—Eu1—C16—C15173.1 (8)
O4—Eu1—O5—C24133.86 (16)O2ii—Eu1—C16—C1557.5 (9)
O2—Eu1—O5—C24123.63 (15)O3—Eu1—C16—C1588.4 (9)
O6—Eu1—O5—C245.27 (14)O5—Eu1—C16—C1518.8 (9)
C16—Eu1—O5—C24161.07 (17)O1—Eu1—C16—C15177.1 (9)
C8—Eu1—O5—C24171.41 (18)O4—Eu1—C16—C15103.8 (9)
O7—Eu1—O6—C2496.04 (15)O2—Eu1—C16—C15126.2 (9)
O6i—Eu1—O6—C24178.94 (18)O6—Eu1—C16—C1531.9 (9)
O2ii—Eu1—O6—C2489.14 (14)C8—Eu1—C16—C15151.8 (9)
O3—Eu1—O6—C2421.69 (17)C24—Eu1—C16—C1527.0 (9)
O5—Eu1—O6—C245.13 (13)C21—N3—C17—C180.1 (7)
O1—Eu1—O6—C24140.24 (14)N3—C17—C18—C191.1 (7)
O4—Eu1—O6—C2438.15 (15)C17—C18—C19—C202.0 (6)
O2—Eu1—O6—C24136.66 (14)C18—C19—C20—C212.0 (5)
C16—Eu1—O6—C2410.95 (17)C18—C19—C20—C22178.6 (3)
C8—Eu1—O6—C24176.03 (15)C17—N3—C21—C200.1 (6)
O7—Eu1—O6—Eu1i85.01 (8)C19—C20—C21—N31.0 (6)
O6i—Eu1—O6—Eu1i0.0C22—C20—C21—N3179.5 (3)
O2ii—Eu1—O6—Eu1i89.80 (7)C21—C20—C22—C2326.2 (5)
O3—Eu1—O6—Eu1i157.25 (7)C19—C20—C22—C23154.4 (3)
O5—Eu1—O6—Eu1i173.81 (11)C20—C22—C23—C24178.6 (3)
O1—Eu1—O6—Eu1i40.82 (12)Eu1—O5—C24—O69.5 (2)
O4—Eu1—O6—Eu1i142.91 (7)Eu1—O5—C24—C23170.6 (2)
O2—Eu1—O6—Eu1i42.28 (11)Eu1i—O6—C24—O5168.5 (3)
C16—Eu1—O6—Eu1i170.11 (7)Eu1—O6—C24—O59.1 (2)
C8—Eu1—O6—Eu1i2.92 (15)Eu1i—O6—C24—C2311.4 (5)
C24—Eu1—O6—Eu1i178.94 (18)Eu1—O6—C24—C23171.0 (2)
C5—N1—C1—C21.1 (5)Eu1i—O6—C24—Eu1177.6 (4)
N1—C1—C2—C31.7 (5)C22—C23—C24—O516.9 (4)
C1—C2—C3—C41.4 (6)C22—C23—C24—O6163.0 (3)
C2—C3—C4—C50.6 (5)O7—Eu1—C24—O5113.73 (16)
C2—C3—C4—C6177.3 (3)O6i—Eu1—C24—O5169.68 (15)
C1—N1—C5—C40.3 (5)O2ii—Eu1—C24—O583.32 (15)
C3—C4—C5—N10.1 (5)O3—Eu1—C24—O56.97 (17)
C6—C4—C5—N1176.8 (3)O1—Eu1—C24—O5110.7 (2)
C3—C4—C6—C76.0 (5)O4—Eu1—C24—O543.86 (15)
C5—C4—C6—C7177.5 (3)O2—Eu1—C24—O596.29 (18)
C4—C6—C7—C8175.9 (3)O6—Eu1—C24—O5170.7 (2)
Eu1—O1—C8—O24.5 (3)C16—Eu1—C24—O518.43 (16)
Eu1—O1—C8—C7175.6 (2)O7—Eu1—C24—O675.62 (14)
Eu1ii—O2—C8—O1177.8 (3)O6i—Eu1—C24—O60.98 (17)
Eu1—O2—C8—O14.3 (2)O2ii—Eu1—C24—O687.34 (14)
Eu1ii—O2—C8—C72.3 (6)O3—Eu1—C24—O6163.69 (13)
Eu1—O2—C8—C7175.7 (2)O5—Eu1—C24—O6170.7 (2)
Eu1ii—O2—C8—Eu1173.5 (4)O1—Eu1—C24—O678.7 (2)
C6—C7—C8—O13.8 (5)O4—Eu1—C24—O6145.49 (14)
C6—C7—C8—O2176.2 (3)O2—Eu1—C24—O674.36 (19)
O7—Eu1—C8—O117.54 (17)C16—Eu1—C24—O6170.92 (14)
O6i—Eu1—C8—O192.23 (16)
Symmetry codes: (i) x, y+1, z+1; (ii) x+1, y+1, z+1.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O7—H1W···O3iii0.82 (2)1.95 (2)2.765 (3)175 (3)
O7—H2W···N1iv0.84 (2)1.90 (2)2.731 (3)170 (4)
Symmetry codes: (iii) x1, y, z; (iv) x+1, y+2, z+1.
 

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