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Acta Cryst. (2006). E62, m2290-m2292  [ doi:10.1107/S1600536806032624 ]

Bis{N-(2-hydroxybenzoyl)-N'-[1-(2-pyridyl)ethylidene]hydrazinato}nickel(II)

D.-B. Dang, Y. Bai and C.-Y. Duan

Abstract: The title complex, [Ni(C14H12N3O2)2], consists of two deprotonated 2-acetylpyridine salicylhydrazone ligands coordinated to the nickel as N,N',O-tridentate ligands, forming a neutral complex. The Ni atom lies on a twofold rotation axis. The structure is stabilized by intramolecular O-H...N hydrogen bonding and [pi]-[pi] stacking interactions between the pyridyl and benzene rings, leading to a two-dimensional network in the crystal structure.

Online 23 August 2006


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