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Acta Cryst. (2006). E62, m2096-m2098  [ doi:10.1107/S1600536806028261 ]

Bis(2-aminonaphthalene-1-sulfonato-[kappa]O)bis(1,10-phenanthroline)zinc(II)

P.-X. Dai, J.-H. Guo and E.-C. Yang

Abstract: In the title compound, [Zn(C10H8NO3S)2(C12H8N2)2], the ZnII atom lies on a crystallographic twofold axis and is in a distorted octahedral coordination geometry formed by four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from two 2-aminonaphthalene-1-sulfonate ligands. In the crystal structure, intermolecular N-H...O and C-H...O hydrogen bonds link molecules to form a three-dimensional network. In addition, there is a single intramolecular [pi]-[pi] stacking interaction.

Online 9 August 2006


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