The title compound, (C8H20N)[Rh2(C7H6NO)4Cl2]·2CH2Cl2, has the acetamidate-bridged-Rh2 anion on an inversion centre. The tetraethylammonium cation is disordered on another inversion centre. The Rh—Rh bond distance is 2.4265 (13) Å; the metal atom shows octahedral coordination. The chloro ligands both occupy axial stes.
Supporting information
CCDC reference: 621441
Key indicators
- Single-crystal X-ray study
- T = 173 K
- Mean (C-C) = 0.007 Å
- Disorder in solvent or counterion
- R factor = 0.049
- wR factor = 0.101
- Data-to-parameter ratio = 18.6
checkCIF/PLATON results
No syntax errors found
Alert level C
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ?
PLAT244_ALERT_4_C Low 'Solvent' Ueq as Compared to Neighbors for C23
PLAT302_ALERT_4_C Anion/Solvent Disorder ......................... 40.00 Perc.
PLAT420_ALERT_2_C D-H Without Acceptor N1 - H1 ... ?
PLAT420_ALERT_2_C D-H Without Acceptor N2 - H2 ... ?
PLAT432_ALERT_2_C Short Inter X...Y Contact O1 .. C19 .. 3.00 Ang.
0 ALERT level A = In general: serious problem
0 ALERT level B = Potentially serious problem
6 ALERT level C = Check and explain
0 ALERT level G = General alerts; check
1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
3 ALERT type 2 Indicator that the structure model may be wrong or deficient
0 ALERT type 3 Indicator that the structure quality may be low
2 ALERT type 4 Improvement, methodology, query or suggestion
0 ALERT type 5 Informative message, check
Data collection: CrystalClear (Molecular Structure Corporation & Rigaku, 2001); cell refinement: CrystalClear; data reduction: TEXSAN (Rigaku/MSC, 2004); program(s) used to solve structure: SIR97 (Altomare et al., 1999); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97 and TEXSAN.
Tetraethylammonium
dichlorotetra-µ-benzamidato-
κ4N:
O;
κ4O:
N-
dirhodate(II,III)(Rh—Rh) dichloromethane disolvate
top
Crystal data top
(C8H20N)[Rh2(C7H6NO)4Cl2]·2CH2Cl2 | Z = 1 |
Mr = 1057.33 | F(000) = 535 |
Triclinic, P1 | Dx = 1.586 Mg m−3 |
Hall symbol: -P 1 | Mo Kα radiation, λ = 0.71069 Å |
a = 9.649 (5) Å | Cell parameters from 3033 reflections |
b = 10.506 (6) Å | θ = 6.0–55.0° |
c = 12.202 (6) Å | µ = 1.15 mm−1 |
α = 76.571 (16)° | T = 173 K |
β = 66.996 (13)° | Prism, brown |
γ = 83.479 (18)° | 0.10 × 0.10 × 0.10 mm |
V = 1107.1 (10) Å3 | |
Data collection top
Rigaku/MSC Mercury CCD area-detector diffractometer | 4109 reflections with I > 2σ(I) |
Radiation source: fine-focus sealed tube | Rint = 0.032 |
Graphite monochromator | θmax = 27.5°, θmin = 3.0° |
Detector resolution: 14.62 pixels mm-1 | h = −11→12 |
ω scans | k = −13→13 |
9060 measured reflections | l = −9→15 |
5028 independent reflections | |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.049 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.101 | H-atom parameters constrained |
S = 1.07 | w = 1/[σ2(Fo2) + (0.0319P)2 + 2.8887P] where P = (Fo2 + 2Fc2)/3 |
5028 reflections | (Δ/σ)max = 0.001 |
270 parameters | Δρmax = 0.72 e Å−3 |
12 restraints | Δρmin = −0.80 e Å−3 |
Special details top
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor
wR and goodness of fit S are based on F2, conventional
R-factors R are based on F, with F set to zero for
negative F2. The threshold expression of F2 >
σ(F2) is used only for calculating R-factors(gt) etc.
and is not relevant to the choice of reflections for refinement.
R-factors based on F2 are statistically about twice as large
as those based on F, and R- factors based on ALL data will be
even larger. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | Occ. (<1) |
Rh1 | 0.37032 (4) | 0.46648 (3) | 0.55416 (3) | 0.01508 (9) | |
Cl1 | 0.10287 (11) | 0.39089 (10) | 0.64948 (10) | 0.0260 (2) | |
N1 | 0.4363 (4) | 0.3120 (3) | 0.4784 (3) | 0.0191 (7) | |
H1 | 0.3682 | 0.2541 | 0.4946 | 0.023* | |
O1 | 0.6786 (3) | 0.3714 (3) | 0.3713 (3) | 0.0203 (6) | |
N2 | 0.3325 (4) | 0.5725 (3) | 0.4121 (3) | 0.0181 (7) | |
H2 | 0.2398 | 0.5769 | 0.4146 | 0.022* | |
O2 | 0.5742 (3) | 0.6331 (3) | 0.3030 (2) | 0.0189 (6) | |
C1 | 0.5734 (4) | 0.2893 (4) | 0.4061 (4) | 0.0176 (8) | |
C2 | 0.6154 (4) | 0.1646 (4) | 0.3625 (4) | 0.0192 (8) | |
C3 | 0.5124 (5) | 0.0951 (4) | 0.3468 (4) | 0.0277 (10) | |
H3 | 0.4124 | 0.1288 | 0.3624 | 0.033* | |
C4 | 0.5542 (6) | −0.0229 (4) | 0.3084 (4) | 0.0321 (11) | |
H4 | 0.4835 | −0.0689 | 0.2967 | 0.039* | |
C5 | 0.6987 (6) | −0.0732 (4) | 0.2874 (4) | 0.0331 (11) | |
H5 | 0.7275 | −0.1540 | 0.2614 | 0.040* | |
C6 | 0.8008 (6) | −0.0065 (5) | 0.3039 (5) | 0.0405 (12) | |
H6 | 0.8998 | −0.0419 | 0.2903 | 0.049* | |
C7 | 0.7599 (5) | 0.1124 (5) | 0.3403 (5) | 0.0339 (11) | |
H7 | 0.8319 | 0.1586 | 0.3502 | 0.041* | |
C8 | 0.4356 (4) | 0.6374 (4) | 0.3139 (3) | 0.0167 (8) | |
C9 | 0.3963 (5) | 0.7187 (4) | 0.2129 (4) | 0.0203 (8) | |
C10 | 0.5101 (5) | 0.7621 (4) | 0.1015 (4) | 0.0283 (10) | |
H8 | 0.6120 | 0.7408 | 0.0918 | 0.034* | |
C11 | 0.4777 (6) | 0.8359 (5) | 0.0046 (4) | 0.0375 (12) | |
H9 | 0.5567 | 0.8629 | −0.0719 | 0.045* | |
C12 | 0.3299 (6) | 0.8702 (5) | 0.0191 (5) | 0.0376 (12) | |
H10 | 0.3074 | 0.9225 | −0.0469 | 0.045* | |
C13 | 0.2159 (6) | 0.8288 (5) | 0.1289 (5) | 0.0396 (12) | |
H11 | 0.1142 | 0.8517 | 0.1388 | 0.048* | |
C14 | 0.2489 (5) | 0.7537 (5) | 0.2252 (4) | 0.0325 (11) | |
H12 | 0.1693 | 0.7255 | 0.3011 | 0.039* | |
N3 | 0.0000 | 0.5000 | 0.0000 | 0.0356 (14) | |
C15 | 0.0046 (12) | 0.3773 (8) | 0.0946 (9) | 0.057 (4) | 0.50 |
H13 | 0.0772 | 0.3919 | 0.1294 | 0.068* | 0.50 |
H14 | −0.0958 | 0.3691 | 0.1614 | 0.068* | 0.50 |
C16 | 0.046 (2) | 0.2480 (13) | 0.0549 (17) | 0.071 (5)* | 0.50 |
H15 | −0.0296 | 0.2273 | 0.0269 | 0.106* | 0.50 |
H16 | 0.0490 | 0.1792 | 0.1236 | 0.106* | 0.50 |
H17 | 0.1449 | 0.2535 | −0.0116 | 0.106* | 0.50 |
C17 | −0.0582 (11) | 0.6097 (9) | 0.0699 (10) | 0.060 (4) | 0.50 |
H18 | −0.1630 | 0.5911 | 0.1275 | 0.072* | 0.50 |
H19 | 0.0034 | 0.6100 | 0.1185 | 0.072* | 0.50 |
C18 | −0.0557 (19) | 0.7441 (12) | −0.0086 (15) | 0.065 (5)* | 0.50 |
H20 | 0.0485 | 0.7729 | −0.0512 | 0.097* | 0.50 |
H21 | −0.1147 | 0.8058 | 0.0425 | 0.097* | 0.50 |
H22 | −0.0992 | 0.7410 | −0.0683 | 0.097* | 0.50 |
C19 | 0.1474 (7) | 0.5167 (11) | −0.1080 (6) | 0.034 (2) | 0.50 |
H23 | 0.1365 | 0.5885 | −0.1730 | 0.041* | 0.50 |
H24 | 0.1743 | 0.4353 | −0.1402 | 0.041* | 0.50 |
C20 | 0.2715 (11) | 0.5475 (12) | −0.0728 (11) | 0.035 (3)* | 0.50 |
H25 | 0.2611 | 0.6391 | −0.0648 | 0.053* | 0.50 |
H26 | 0.3695 | 0.5331 | −0.1358 | 0.053* | 0.50 |
H27 | 0.2646 | 0.4903 | 0.0049 | 0.053* | 0.50 |
C21 | −0.1210 (8) | 0.4695 (10) | −0.0417 (7) | 0.033 (2) | 0.50 |
H28 | −0.1350 | 0.5485 | −0.0994 | 0.040* | 0.50 |
H29 | −0.0793 | 0.3994 | −0.0885 | 0.040* | 0.50 |
C22 | −0.2754 (10) | 0.4284 (13) | 0.0501 (11) | 0.042 (3)* | 0.50 |
H30 | −0.2656 | 0.3526 | 0.1110 | 0.063* | 0.50 |
H31 | −0.3347 | 0.4051 | 0.0086 | 0.063* | 0.50 |
H32 | −0.3261 | 0.5009 | 0.0902 | 0.063* | 0.50 |
C23 | 0.1179 (10) | 0.3218 (7) | 0.3713 (7) | 0.078 (2) | |
H33 | 0.1246 | 0.3525 | 0.4398 | 0.094* | |
H34 | 0.0303 | 0.3674 | 0.3547 | 0.094* | |
Cl2 | 0.2822 (3) | 0.36357 (19) | 0.24201 (18) | 0.0765 (6) | |
Cl3 | 0.0889 (3) | 0.1546 (2) | 0.4131 (3) | 0.1161 (10) | |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
Rh1 | 0.01416 (15) | 0.01474 (15) | 0.01295 (15) | −0.00145 (10) | −0.00077 (11) | −0.00366 (11) |
Cl1 | 0.0160 (5) | 0.0292 (6) | 0.0278 (6) | −0.0043 (4) | −0.0028 (4) | −0.0042 (5) |
N1 | 0.0209 (17) | 0.0157 (16) | 0.0199 (18) | −0.0028 (14) | −0.0057 (15) | −0.0044 (14) |
O1 | 0.0196 (14) | 0.0187 (14) | 0.0184 (15) | −0.0026 (11) | −0.0006 (12) | −0.0066 (12) |
N2 | 0.0151 (16) | 0.0203 (17) | 0.0152 (17) | −0.0025 (13) | −0.0026 (14) | −0.0012 (14) |
O2 | 0.0152 (14) | 0.0216 (14) | 0.0156 (15) | −0.0027 (11) | −0.0019 (12) | −0.0019 (12) |
C1 | 0.020 (2) | 0.0168 (19) | 0.0139 (19) | −0.0016 (15) | −0.0043 (16) | −0.0022 (15) |
C2 | 0.021 (2) | 0.0177 (19) | 0.015 (2) | 0.0010 (16) | −0.0036 (17) | −0.0020 (16) |
C3 | 0.031 (2) | 0.022 (2) | 0.032 (3) | 0.0037 (18) | −0.011 (2) | −0.0107 (19) |
C4 | 0.048 (3) | 0.021 (2) | 0.029 (3) | −0.004 (2) | −0.015 (2) | −0.0092 (19) |
C5 | 0.053 (3) | 0.018 (2) | 0.021 (2) | 0.002 (2) | −0.005 (2) | −0.0065 (18) |
C6 | 0.035 (3) | 0.029 (3) | 0.051 (3) | 0.011 (2) | −0.007 (3) | −0.017 (2) |
C7 | 0.028 (2) | 0.030 (2) | 0.041 (3) | −0.002 (2) | −0.005 (2) | −0.016 (2) |
C8 | 0.019 (2) | 0.0171 (18) | 0.0121 (19) | 0.0006 (15) | −0.0024 (16) | −0.0069 (15) |
C9 | 0.025 (2) | 0.0164 (19) | 0.021 (2) | −0.0033 (16) | −0.0096 (18) | −0.0034 (16) |
C10 | 0.023 (2) | 0.032 (2) | 0.021 (2) | 0.0027 (19) | −0.0039 (19) | 0.0023 (19) |
C11 | 0.040 (3) | 0.041 (3) | 0.019 (2) | 0.000 (2) | −0.005 (2) | 0.005 (2) |
C12 | 0.046 (3) | 0.040 (3) | 0.027 (3) | −0.006 (2) | −0.021 (2) | 0.010 (2) |
C13 | 0.027 (3) | 0.053 (3) | 0.033 (3) | −0.002 (2) | −0.014 (2) | 0.006 (2) |
C14 | 0.023 (2) | 0.043 (3) | 0.024 (2) | −0.005 (2) | −0.007 (2) | 0.006 (2) |
N3 | 0.027 (3) | 0.068 (4) | 0.012 (3) | 0.000 (3) | −0.007 (2) | −0.011 (3) |
C15 | 0.038 (6) | 0.098 (10) | 0.028 (6) | −0.029 (7) | −0.014 (5) | 0.011 (6) |
C17 | 0.027 (6) | 0.112 (11) | 0.046 (7) | −0.012 (6) | 0.006 (5) | −0.058 (8) |
C19 | 0.031 (5) | 0.053 (6) | 0.012 (4) | −0.005 (5) | −0.002 (4) | −0.004 (4) |
C21 | 0.031 (5) | 0.051 (6) | 0.016 (5) | −0.006 (4) | −0.012 (4) | 0.003 (4) |
C23 | 0.125 (7) | 0.065 (4) | 0.075 (5) | 0.047 (5) | −0.074 (5) | −0.033 (4) |
Cl2 | 0.1125 (16) | 0.0715 (12) | 0.0735 (13) | 0.0110 (11) | −0.0680 (13) | −0.0158 (10) |
Cl3 | 0.0816 (15) | 0.0817 (15) | 0.212 (3) | −0.0076 (12) | −0.0950 (19) | −0.0082 (17) |
Geometric parameters (Å, º) top
Rh1—Rh1i | 2.4266 (13) | C13—H11 | 0.9500 |
Rh1—Cl1 | 2.5167 (16) | C14—H12 | 0.9500 |
Rh1—O1i | 2.038 (3) | N3—C19 | 1.508 (6) |
Rh1—O2i | 2.043 (3) | N3—C17 | 1.519 (6) |
Rh1—N1 | 1.975 (3) | N3—C15 | 1.527 (6) |
Rh1—N2 | 1.970 (3) | N3—C21 | 1.533 (5) |
N1—C1 | 1.303 (5) | C15—C16 | 1.507 (8) |
N1—H1 | 0.8800 | C15—H13 | 0.9900 |
O1—C1 | 1.283 (4) | C15—H14 | 0.9900 |
N2—C8 | 1.317 (5) | C16—H15 | 0.9800 |
N2—H2 | 0.8800 | C16—H16 | 0.9800 |
O2—C8 | 1.288 (5) | C16—H17 | 0.9800 |
C1—C2 | 1.483 (5) | C17—C18 | 1.508 (8) |
C2—C7 | 1.385 (6) | C17—H18 | 0.9900 |
C2—C3 | 1.391 (6) | C17—H19 | 0.9900 |
C3—C4 | 1.388 (6) | C18—H20 | 0.9800 |
C3—H3 | 0.9500 | C18—H21 | 0.9800 |
C4—C5 | 1.381 (7) | C18—H22 | 0.9800 |
C4—H4 | 0.9500 | C19—C20 | 1.509 (8) |
C5—C6 | 1.370 (7) | C19—H23 | 0.9900 |
C5—H5 | 0.9500 | C19—H24 | 0.9900 |
C6—C7 | 1.387 (6) | C20—H25 | 0.9800 |
C6—H6 | 0.9500 | C20—H26 | 0.9800 |
C7—H7 | 0.9500 | C20—H27 | 0.9800 |
C8—C9 | 1.481 (6) | C21—C22 | 1.509 (8) |
C9—C10 | 1.385 (6) | C21—H28 | 0.9900 |
C9—C14 | 1.386 (6) | C21—H29 | 0.9900 |
C10—C11 | 1.381 (6) | C22—H30 | 0.9800 |
C10—H8 | 0.9500 | C22—H31 | 0.9800 |
C11—C12 | 1.382 (7) | C22—H32 | 0.9800 |
C11—H9 | 0.9500 | C23—Cl3 | 1.735 (7) |
C12—C13 | 1.372 (7) | C23—Cl2 | 1.754 (9) |
C12—H10 | 0.9500 | C23—H33 | 0.9900 |
C13—C14 | 1.381 (6) | C23—H34 | 0.9900 |
| | | |
N2—Rh1—N1 | 92.59 (14) | C10—C11—H9 | 120.1 |
N2—Rh1—O1i | 88.52 (13) | C12—C11—H9 | 120.1 |
N1—Rh1—O1i | 175.04 (13) | C13—C12—C11 | 119.9 (5) |
N2—Rh1—O2i | 174.83 (12) | C13—C12—H10 | 120.0 |
N1—Rh1—O2i | 89.13 (13) | C11—C12—H10 | 120.0 |
O1i—Rh1—O2i | 89.36 (12) | C12—C13—C14 | 120.0 (5) |
N2—Rh1—Rh1i | 86.19 (10) | C12—C13—H11 | 120.0 |
N1—Rh1—Rh1i | 85.50 (10) | C14—C13—H11 | 120.0 |
O1i—Rh1—Rh1i | 89.76 (8) | C13—C14—C9 | 121.0 (4) |
O2i—Rh1—Rh1i | 89.09 (8) | C13—C14—H12 | 119.5 |
N2—Rh1—Cl1 | 90.58 (10) | C9—C14—H12 | 119.5 |
N1—Rh1—Cl1 | 90.66 (10) | C19—N3—C17 | 118.7 (6) |
O1i—Rh1—Cl1 | 94.16 (8) | C19—N3—C15 | 111.1 (6) |
O2i—Rh1—Cl1 | 94.28 (8) | C17—N3—C15 | 105.5 (6) |
Rh1i—Rh1—Cl1 | 174.86 (3) | C19—N3—C21 | 108.3 (5) |
C1—N1—Rh1 | 124.8 (3) | C17—N3—C21 | 109.0 (6) |
C1—N1—H1 | 117.6 | C15—N3—C21 | 103.0 (5) |
Rh1—N1—H1 | 117.6 | C16—C15—N3 | 118.4 (10) |
C1—O1—Rh1i | 117.5 (3) | C16—C15—H13 | 107.7 |
C8—N2—Rh1 | 124.9 (3) | N3—C15—H13 | 107.7 |
C8—N2—H2 | 117.5 | C16—C15—H14 | 107.7 |
Rh1—N2—H2 | 117.5 | N3—C15—H14 | 107.7 |
C8—O2—Rh1i | 118.8 (2) | H13—C15—H14 | 107.1 |
O1—C1—N1 | 122.3 (3) | C18—C17—N3 | 114.5 (9) |
O1—C1—C2 | 116.8 (3) | C18—C17—H18 | 108.6 |
N1—C1—C2 | 120.9 (3) | N3—C17—H18 | 108.6 |
C7—C2—C3 | 118.4 (4) | C18—C17—H19 | 108.6 |
C7—C2—C1 | 119.5 (4) | N3—C17—H19 | 108.6 |
C3—C2—C1 | 122.1 (4) | H18—C17—H19 | 107.6 |
C4—C3—C2 | 120.7 (4) | C17—C18—H20 | 109.5 |
C4—C3—H3 | 119.6 | C17—C18—H21 | 109.5 |
C2—C3—H3 | 119.6 | H20—C18—H21 | 109.5 |
C5—C4—C3 | 119.8 (4) | C17—C18—H22 | 109.5 |
C5—C4—H4 | 120.1 | H20—C18—H22 | 109.5 |
C3—C4—H4 | 120.1 | H21—C18—H22 | 109.5 |
C6—C5—C4 | 120.1 (4) | N3—C19—C20 | 110.9 (7) |
C6—C5—H5 | 120.0 | N3—C19—H23 | 109.5 |
C4—C5—H5 | 120.0 | C20—C19—H23 | 109.5 |
C5—C6—C7 | 120.2 (5) | N3—C19—H24 | 109.5 |
C5—C6—H6 | 119.9 | C20—C19—H24 | 109.5 |
C7—C6—H6 | 119.9 | H23—C19—H24 | 108.0 |
C2—C7—C6 | 120.8 (4) | C22—C21—N3 | 120.5 (7) |
C2—C7—H7 | 119.6 | C22—C21—H28 | 107.2 |
C6—C7—H7 | 119.6 | N3—C21—H28 | 107.2 |
O2—C8—N2 | 120.9 (4) | C22—C21—H29 | 107.2 |
O2—C8—C9 | 117.7 (3) | N3—C21—H29 | 107.2 |
N2—C8—C9 | 121.4 (4) | H28—C21—H29 | 106.8 |
C10—C9—C14 | 118.2 (4) | Cl3—C23—Cl2 | 112.5 (4) |
C10—C9—C8 | 119.4 (4) | Cl3—C23—H33 | 109.1 |
C14—C9—C8 | 122.4 (4) | Cl2—C23—H33 | 109.1 |
C11—C10—C9 | 121.1 (4) | Cl3—C23—H34 | 109.1 |
C11—C10—H8 | 119.5 | Cl2—C23—H34 | 109.1 |
C9—C10—H8 | 119.5 | H33—C23—H34 | 107.8 |
C10—C11—C12 | 119.8 (5) | | |
| | | |
N2—Rh1—N1—C1 | 86.7 (3) | Rh1—N2—C8—O2 | 1.5 (5) |
O2i—Rh1—N1—C1 | −88.4 (3) | Rh1—N2—C8—C9 | −177.8 (3) |
Rh1i—Rh1—N1—C1 | 0.7 (3) | O2—C8—C9—C10 | 14.5 (5) |
Cl1—Rh1—N1—C1 | 177.3 (3) | N2—C8—C9—C10 | −166.2 (4) |
N1—Rh1—N2—C8 | −84.1 (3) | O2—C8—C9—C14 | −165.5 (4) |
O1i—Rh1—N2—C8 | 91.0 (3) | N2—C8—C9—C14 | 13.9 (6) |
Rh1i—Rh1—N2—C8 | 1.2 (3) | C14—C9—C10—C11 | −1.3 (7) |
Cl1—Rh1—N2—C8 | −174.8 (3) | C8—C9—C10—C11 | 178.7 (4) |
Rh1i—O1—C1—N1 | 5.7 (5) | C9—C10—C11—C12 | 1.7 (7) |
Rh1i—O1—C1—C2 | −172.9 (3) | C10—C11—C12—C13 | −1.3 (8) |
Rh1—N1—C1—O1 | −4.2 (6) | C11—C12—C13—C14 | 0.6 (8) |
Rh1—N1—C1—C2 | 174.3 (3) | C12—C13—C14—C9 | −0.2 (8) |
O1—C1—C2—C7 | 30.6 (6) | C10—C9—C14—C13 | 0.6 (7) |
N1—C1—C2—C7 | −148.1 (4) | C8—C9—C14—C13 | −179.5 (4) |
O1—C1—C2—C3 | −151.6 (4) | C19—N3—C15—C16 | −55.1 (12) |
N1—C1—C2—C3 | 29.8 (6) | C17—N3—C15—C16 | 174.9 (10) |
C7—C2—C3—C4 | −0.7 (7) | C21—N3—C15—C16 | 60.7 (11) |
C1—C2—C3—C4 | −178.5 (4) | C19—N3—C17—C18 | 48.2 (11) |
C2—C3—C4—C5 | 1.0 (7) | C15—N3—C17—C18 | 173.6 (10) |
C3—C4—C5—C6 | −0.2 (7) | C21—N3—C17—C18 | −76.4 (10) |
C4—C5—C6—C7 | −0.8 (8) | C17—N3—C19—C20 | 54.9 (10) |
C3—C2—C7—C6 | −0.3 (7) | C15—N3—C19—C20 | −67.7 (10) |
C1—C2—C7—C6 | 177.6 (4) | C21—N3—C19—C20 | 179.8 (8) |
C5—C6—C7—C2 | 1.1 (8) | C19—N3—C21—C22 | 171.0 (9) |
Rh1i—O2—C8—N2 | −4.0 (5) | C17—N3—C21—C22 | −58.5 (11) |
Rh1i—O2—C8—C9 | 175.3 (2) | C15—N3—C21—C22 | 53.2 (11) |
Symmetry code: (i) −x+1, −y+1, −z+1. |